Life cycle assessment of the use of decommissioned wind blades in second life applications.

53,000 tonnes of blade waste from on-shore wind farms will potentially be generated in Ireland by 2040. The recycling of blades, which are made from composite material, is costly and thus far no high volume recycling solution exists. Repurposing blades into second life structures is an alternative which is gaining in popularity, but has many challenges. Green Public Procurement has the potential to help drive demand for blade products in Irish public works. The Re-Wind project has generated a Design Atlas with 47 blade product concepts and these are screened for their ability to overcome repurposing challenges. Three Irish scenarios are developed based on this ranking, maximal utilization of the blade, and on the end customer. Life Cycle Assessment is used to determine the marginal environmental impacts of the raw material substitution provided by the use of blade material. Focusing on greenhouse gas emissions, an estimated 342 kg CO2 e can be saved for every tonne of blade waste used in these scenarios. Blade substitution of steel products was found to provide the most impact, followed by substitution of concrete products. Although repurposing is unlikely to offer an end-of-life solution for all Irish blade waste, the use of 20% of this material annually would divert 315 tonnes of blade waste from landfill, as well as avoiding emissions of 71,820 kg CO2 e. Green procurement has the potential to create a demand for repurposed blade products, which in turn could create jobs in high unemployment areas. Utilization of repurposed, local material could contribute to creating resiliency in supply chains. Both job creation and supply chain resiliency are essential for a post-Covid recovery in Ireland.

Per- and Polyfluoroalkyl Substances in Ducks and the Relationship with Concentrations in Water, Sediment, and Soil.

The present study examined the occurrence and concentration of per- and polyfluoroalkyl substances (PFAS) measured in game ducks (13 compounds), water, sediment, and soils (33 compounds) in waterways in Victoria, Australia. The study aimed to identify potential ecological and human health risks from measured PFAS concentrations. Four species of duck and samples of water, sediment, and soil were collected from 19 wetlands, which were chosen based on their popularity as hunting locations. The risks posed by 3 PFAS (perfluorooctanoic acid, perfluorohexane sulfonic acid [PFHxS], and perfluorooctane sulfonic acid [PFOS]) to the environment and human health were assessed using available national ecological and human health guidelines. A diverse range of short- and long-chain carboxylic and sulfonic acids were found in the environment and in ducks. Concentrations were generally low and varied between wetlands, duck species, tissue analyzed (breast or liver), and environmental compartment (water, sediment, soil). Higher PFOS concentrations in water and sediments were observed at wetlands near sources of contamination (i.e., a defense base or urban environment). Elevated PFOS and PFOS + PFHxS concentrations in ducks were observed near local point sources but also at wetlands with no known point sources of contamination. There were clear differences in PFAS concentrations detected in duck tissues versus the environment, highlighting complexities of bioaccumulation, movement of animals, and spatiotemporal variation and raising questions about the relevance of using abiotic criteria to assess risk to biota. Human health risk assessment showed that only ducks inhabiting wetlands near local sources of PFAS were likely to pose a risk to consumers. Further studies are required to improve our knowledge of PFAS toxicokinetics and chronic impacts in biota to guide management decisions. Environ Toxicol Chem 2021;40:846-858. © 2020 SETAC.

Emerging and legacy contaminants across land-use gradients and the risk to aquatic ecosystems.

Information on potentially harmful emerging and legacy chemicals is essential to understand the risks to the environment and inform regulatory actions. The objective of this study was to assess the occurrence, concentration, and distribution of emerging and legacy contaminants across a gradient of land-use intensity and determine the risk posed to aquatic ecosystems. The land-use intensity gradient considered was: background/undeveloped < low-intensity agriculture < high-intensity agriculture < urban residential < urban industrial. Twenty-five sites were sampled for surface water, sediment, and soil. A total of 218 chemicals were analyzed: pesticides, per- and poly-fluoroalkyl substances (PFAS), polybrominated biphenyls and polybrominated diphenyl ethers (PBDEs), phthalates, and short-chain chlorinated paraffins (SCCPs). The risk posed by the analyzed chemicals to the aquatic environment was measured using hazard quotients (HQs), which were calculated by dividing the maximum measured environmental concentration by a predicted no-effect concentration for each chemical. A HQ > 1 was considered to indicate a high risk of adverse effects from the given chemical. A total of 68 chemicals were detected: 19 pesticides, 18 PFAS, 28 PBDEs, two phthalates, and SCCPs (as total SCCPs). There were no significant differences in the overall chemical composition between land uses. However, the insecticide bifenthrin, PFAS, PBDEs, and phthalates were more frequently found in samples from residential and/or industrial sites, suggesting urban land uses are hotspots and potential large-scale sources of these chemicals. Nineteen chemicals had a HQ > 1; most had a restricted spatial distribution limited to high-intensity agriculture and industrial sites in Melbourne. Bifenthrin and the perfluorooctanesulfonic acid (PFOS) had the highest HQs in residential and industrial sites, suggesting an increased risk to aquatic ecosystems in urban settings. The results of this study will enhance future research, predictive methods, and effective targeting of monitoring, and will help guide regulatory management actions and mitigation solutions.

Municipal wastewater effluent licensing: A global perspective and recommendations for best practice.

Advances in wastewater treatment have greatly improved the quality of municipal wastewater effluents in many parts of the world, but despite this, treated wastewaters can still pose a risk to the environment. Licensing plays a crucial role in the regulation of municipal wastewater effluents by setting standards or limits designed to protect the economic, environmental and societal values of waterbodies. Traditionally these standards have focused on physical and chemical water quality parameters within the discharge itself, however these approaches do not adequately account for emerging contaminants, potential effects of chemical mixtures, or variations in the sensitivity and resilience of receiving environments. In this review we focus on a number of industrialised countries and their approach to licensing. We consider how we can ensure licensing is effective, particularly when considering the rapid changes in our understanding of the impacts of discharges, the technical advances in our ability to detect chemicals at low concentrations and the progress in wastewater treatment technology. In order to meet the challenges required to protect the values of our waterways, licensing of effluents will need to ensure that there is no disconnect between the core values to be protected and the monitoring system designed to scrutinise performance of the WWTP. In many cases this may mean an expansion in the monitoring approaches used for both the effluent itself and the receiving waterbody.

Identifying heavy metal levels in historical flood water deposits using sediment cores.

When designing mitigation and restoration strategies for aquatic systems affected by heavy metal contamination, we must first understand the sources of these pollutants. In this study, we introduce a methodology that identifies the heavy metal levels in floodplain lake sediments deposited by one source; fluvial floods. This is done by comparing sediment core heavy metal profiles (i.e., historical pollution trends) to physical and chemical properties of sediments in these cores (i.e., historical flooding trends). This methodology is applied to Willsmere and Bolin Billabongs, two urban floodplain lakes (billabongs) of the Yarra River (South-East Australia). Both billabongs are periodically inundated by flooding of the Yarra River and one billabong (Willsmere Billabong) is connected to an urban stormwater drainage network. 1-2-m long sediment cores (containing sediment deposits up to 500 years old) were taken from the billabongs and analysed for heavy metal concentrations (arsenic, chromium, copper, lead, nickel, zinc). In cores from both billabongs, arsenic concentrations are high in the flood-borne sediments. In Bolin Billabong, absolute metal levels are similar in flood and non-flood deposits. In Willsmere Billabong, absolute copper, lead and zinc levels were generally lower in fluvial flood-borne sediments in the core compared to non-fluvial sediments. This suggests that heavy metal concentrations in Bolin Billabong sediments are relatively similar regardless of whether or not fluvial flooding is occurring. However for Willsmere Billabong, heavy metal concentrations are high when overland runoff, direct urban stormwater discharges or atmospheric deposition is occurring. As such, reducing the heavy metal concentrations in these transport pathways will be of great importance when trying to reduce heavy metal concentrations in Willsmere Billabong sediments. This study presents a proof-of-concept that can be applied to other polluted aquatic systems, to understand the importance of river floods in the contamination of the bed sediments of aquatic systems. As a cost effective and less time consuming alternative to extensive field monitoring, our proposed method can be used to identify the key sources of pollution and therefore support the development of effective management strategies.

Using sediment cores to establish targets for the remediation of aquatic environments.

When assigning site-specific restoration targets for deteriorating aquatic systems, it is necessary to have an understanding of the undisturbed or background state of the system. However, the site-specific characteristics of aquatic systems prior to disturbance are mostly unknown, due to the lack of historical water and sediment quality data. This study aims to introduce a method for filling this gap in our understanding, using dated sediment cores from the beds of aquatic environments. We used Bolin Billabong, a floodplain lake of the Yarra River (South-East Australia), as a case study to demonstrate the application of this method. We identified the concentrations of aluminium, cadmium, chromium, copper, iron, lead, manganese, nickel, tin and zinc at 8 cm intervals through the sediment core. This showed that aluminium, chromium, copper, iron, lead, nickel, tin and zinc concentrations in Bolin Billabong sediments significantly increased after European settlement in the river catchment in the mid-19th century. The differences between current Australian sediment quality guidelines trigger values and the background metal concentrations in Bolin Billabong sediments underscore the value of using locally relevant background toxicant concentrations when setting water and sediment quality targets.

Sediment cores as archives of historical changes in floodplain lake hydrology.

Anthropogenic activities are contributing to the changing hydrology of rivers, often resulting in their degradation. Understanding the drivers and nature of these changes is critical for the design and implementation of effective mitigation strategies for these systems. However, this can be hindered by gaps in historical measured flow data. This study therefore aims to use sediment cores to identify historical hydrological changes within a river catchment. Sediment cores from two floodplain lakes (billabongs) in the urbanised Yarra River catchment (Melbourne, South-East Australia) were collected and high resolution images, trends in magnetic susceptibility and trends in elemental composition through the sedimentary records were obtained. These were used to infer historical changes in river hydrology to determine both average trends in hydrology (i.e., coarse temporal resolution) as well as discrete flood layers in the sediment cores (i.e., fine temporal resolution). Through the 20th century, both billabongs became increasingly disconnected from the river, as demonstrated by the decreasing trends in magnetic susceptibility, particle size and inorganic matter in the cores. Additionally the number of discrete flood layers decreased up the cores. These reconstructed trends correlate with measured flow records of the river through the 20th century, which validates the methodology that has been used in this study. Not only does this study provide evidence on how natural catchments can be affected by land-use intensification and urbanisation, but it also introduces a general analytical framework that could be applied to other river systems to assist in the design of hydrological management strategies.

Spatial and Seasonal Variation of dissolved organic carbon (DOC) concentrations in Irish streams: importance of soil and topography characteristics.

Dissolved organic carbon (DOC) concentrations have increased in many sites in Europe and North America in recent decades. High DOC concentrations can damage the structure and functions of aquatic ecosystems by influencing water chemistry. This study investigated the spatial and seasonal variation of DOC concentrations in Irish streams across 55 sites at seven time occasions over 1 year (2006/2007). The DOC concentrations ranged from 0.9 to 25.9 mg/L with a mean value of 6.8 and a median value of 5.7 mg/L and varied significantly over the course of the year. The DOC concentrations from late winter (February: 5.2 ± 3.0 mg/L across 55 sites) and early spring (April: 4.5 ± 3.5 mg/L) had significantly lower DOC concentrations than autumn (October: mean 8.3 ± 5.6 mg/L) and early winter (December: 8.3 ± 5.1 mg/L). The DOC production sources (e.g., litterfall) or the accumulation of DOC over dry periods might be the driving factor of seasonal change in Irish stream DOC concentrations. Analysis of data using stepwise multiple linear regression techniques identified the topographic index (TI, an indication of saturation-excess runoff potential) and soil conditions (organic carbon content and soil drainage characteristics) as key factors in controlling DOC spatial variation in different seasons. The TI and soil carbon content (e.g., soil organic carbon; peat occurrence) are positively related to DOC concentrations, while well-drained soils are negatively related to DOC concentrations. The knowledge of spatial and seasonal variation of DOC concentrations in streams and their drivers are essential for optimum riverine water resources management.

Seasonal exports of phosphorus from intensively fertilised nested grassland catchments.

We carried out a one year (2002) study of phosphorus (P) loss from soil to water in three nested grassland catchments with known P input in chemical fertilizer and animal liquid slurry applications. Chemical fertilizer was applied to the grasslands between March and September and animal slurry was applied over the twelve months. The annual chemical P fertilizer applications for the 17 and 211 ha catchments were 16.4 and 23.7 kg P/ha respectively and the annual slurry applications were 10.7 and 14.0 kg P/ha, respectively. The annual total phosphorus (TP) export in stream-flow was 2.61, 2.48 and 1.61 kg P/ha for the 17, 211 and 1524 ha catchments, respectively, compared with a maximum permissible (by regulation) annual export of ca. 0.35 kg P/ha. The export rate (ratio of P export to P in land applications) was 9.6% and 6.6% from the 17 and 211 ha catchments, respectively. On average, 70% of stream flow and 85% of the P export occurred during the five wet months (October to February) indicating that when precipitation is much greater than evaporation, the hydrological conditions are most favourable for P export. However the soil quality and land use history may vary the results. Particulate P made up 22%, 43% and 37% of the TP export at the 17, 211 and 1524 ha catchment areas, respectively. As the chemical fertilizer was spread during the grass growth months (March to September), it has less immediate impact on stream water quality than the slurry applications. We also show that as the catchment scale increases, the P concentrations and P export decrease, confirming dilution due to increasing rural catchment size. In the longer term, the excess P from fertilizer maintains high soil P levels, an antecedent condition favourable to P loss from soil to water. This study confirms the significant negative water quality impact of excess P applications, particularly liquid animal slurry applications in wet winter months. The findings suggest that restricted P application in wet months can largely reduce the P losses from soil to water.

Maximizing the aesthetic result in panniculectomy after massive weight loss.

BACKGROUND: Plastic surgical consultation for abdominal contouring following massive weight loss is becoming increasingly prevalent, especially with the popularity of surgical weight loss procedures. The authors reviewed their experience with a novel panniculectomy technique that generally combines horizontal and vertical tissue excision to generate the best contour possible while providing effective relief of symptoms related to a dependent abdominal panniculus. METHODS: A retrospective chart review was conducted of 100 consecutive patients who underwent panniculectomy using the authors' technique over a 5-year period. Demographic and procedural data were collected, and outcome measures were analyzed. RESULTS: Eighty-seven women and 13 men with an average weight loss of 133 lb underwent abdominal panniculectomy. A total of 37 ventral hernias were repaired concomitantly. Mean clinical follow-up was 16 months. Hospital length of stay averaged 4 days, and the most common complications were blood transfusion requirement (n = 39), fluid collections (n = 32), tissue necrosis requiring debridement (n = 18), and contour irregularities requiring revision (n = 15). Overall, 56 patients had a completely uncomplicated recovery. Greater amounts of tissue resection were associated with higher rates of transfusion (p < 0.01). CONCLUSIONS: The panniculectomy technique described can be performed safely and reproducibly. It yields an excellent abdominal contour and is effective in alleviating many symptoms of the dependent abdominal panniculus. It also provides exposure for improved evaluation and repair of concomitant ventral hernia defects.

Biologic enhancement of wound healing.

Manipulation of the healing process through wound supplementation with agents that are natural contributors to the healing process is an appealing concept. Early experimental studies evaluating wounds supplemented with inflammatory mediators used materials extracted from cell preparations and generated encouraging results. Recombinant technology has allowed the production of larger volumes of these mediators that can be used more practically and safely in the clinical setting. Several clinical trials involving inflammatory mediators as wound supplements are reviewed, and the results of many of the studies are encouraging. Wound supplements are considered drugs, and therefore, they must be demonstrated to be safe and efficacious before they can receive approval for human use by the FDA. It is extremely expensive to carry out the experimental studies required for FDA approval. Because of the expense involved, Regranex is the only supplement that has been tested thoroughly enough to receive FDA approval for use in humans. It is hoped that additional agents will be demonstrated to be safe and efficacious in human trials so that they might become available in the United States in the near future.