High-Temperature-Induced Pore System Evolution of Immature Shale with Different Total Organic Carbon Contents.

The pyrolysis process of source rock, especially organic-rich immature shale, is required for oil and gas extraction, during which the evolution of the pore structure system in the immature shale determines the heat conduction and fluid flow under the heating treatment. Although some sound achievements have been made regarding the pyrolysis of immature shale, the effect of the total organic carbon (TOC) content on the pore structure evolution of immature shale remains unclear. With respect to this issue, in this work, a series of N2 adsorption/desorption and nuclear magnetic resonance (NMR) experiments were conducted, and fractal dimension theory was also introduced to analyze the pore structure evolution of immature shale subjected to heating treatment in a quantitative manner. The results indicate that the adsorption branch of the nitrogen adsorption-desorption isotherm can be divided into three stages. The pore structure of different TOC immature shales does not change significantly, and they are all slit-shaped. In addition, immature shale with a higher organic content has a higher hydrocarbon expulsion strength and a higher pore volume growth rate, which indicate that the pyrolysis of organic matter greatly affects the pore structure of immature shale during heating. This phenomenon shows that the pyrolysis of organic matter greatly influences the pore structure of immature shale during the heating process. The pores of immature shale in the study area have significant fractal characteristics, the fractal dimension is between 2.397 and 2.636, the pore space of the sample is extremely small, the pore structure is extremely complex, and the heterogeneity is strong.

Pore Structure Characteristics and Affecting Factors of Shale in the First Member of the Qingshankou Formation in the Gulong Sag, Songliao Basin.

A major historical breakthrough has been made in the exploration of the GK (the first member of the Qingshankou Formation (K2qn1), Gulong Sag) shale oil of the Songliao Basin. However, few reports have been reported on the pore structure characteristics of this large-scale lacustrine medium-high maturity shale. In addition, the difference between the pore structure characteristics of the GK shale and medium-low maturity marine/continental shale is unknown, and the affecting factors of pore development are still unclear. Therefore, in order to clarify the pore structure characteristics of the GK shale and its affecting factors, this study characterized them experimentally and revealed the law of pore evolution using the mineral composition and geochemical analysis, microscopic observations, and pore quantification techniques. Results indicate that (1) the pore system of GK shale reservoirs is divided into micropores (pore diameter < 10 nm), mesopores (10 nm < pore diameter < 50 nm), and macropores (pore diameter > 50 nm); (2) the pore structure of the GK shale is mainly affected by the clay content, siliceous mineral content, and thermal maturity; and (3) when the content of clay minerals and siliceous minerals in the GK shale reservoir is high, and ∼0.8% < R o < ∼1.4%, the storage capacity and oil content of the GK shale show high values, and it can be considered as a strong candidate for further exploration and development. This research can push the shale oil revolution to a new height and is significant to promote the development of the petroleum industry.