RESUMO
Ultrasensitive sensors of various physical properties can be based on percolation systems, e.g., insulating media filled with nearly touching conducting particles. Such a system at its percolation threshold featuring the critical particle concentration, changes drastically its response (electrical conduction, light transmission, etc.) when subjected to an external stimulus. Due to the critical nature of this threshold, a given state at the threshold is typically very unstable. However, stability can be restored without significantly sacrificing the structure sensitivity by forming weak connections between the conducting particles. In this work, we employed nano-bridged nanosphere lithography to produce such a weakly connected percolation system. It consists of two coupled quasi-Babinet complementary arrays, one with weakly connected, and the other with disconnected metallic islands. We demonstrate via experiment and simulation that the physics of this plasmonic system is non-trivial, and leads to the extraordinary optical transmission at narrowly defined peaks sensitive to system parameters, with surface plasmons mediating this process. Thus, our system is a potential candidate for percolation effect based sensor applications. Promising detection schemes could be based on these effects.
RESUMO
We develop nano-bridged nanosphere lithography (NB-NSL), a modification to the widely used conventional nanosphere lithography (NSL). Nano-bridges between polystyrene (PS) spheres of a pristine NSL template are controllably formed in a two-step process: (i) spin-coating of a dilute styrene solution on top of the template, followed by (ii) oxygen plasma etching of the template. We show that the nanobridge dimensions can be precisely tuned by controlling the pre-processing conditions and the plasma etching time. The resulting lithography templates feature control over the shape and size of the apertures, which determine the morphology of the final nano-island arrays after material deposition and template removal. The unique advantage of NB-NSL is that PS particle templates based on a single PS particle diameter can be utilized for the fabrication of a variation of nano-island shapes and sizes, whereas conventional NSL yields only bowtie-shaped nano-islands, with their size being predetermined by the PS particle diameter of the template.
RESUMO
Graphene carbon nitride (g-C3N4) was successfully prepared by semi-closed pyrolysis and then incorporated into the ultraviolet (UV)-curing system to synthesize different specimens of g-C3N4-hybridized UV-curing (g-C3N4/UV) coatings. The apparent appearance and dispersity g-C3N4 were characterized through X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). The influence of the curing speed and mechanical properties was also tested. The dispersion level of g-C3N4 can be kept less than 1 µm by mechanical mixing. The pencil hardness of composite coatings could be 6H while the adhesion based on glass could be 1 level. The degree of curing of the coating could be obviously improved by the addition of g-C3N4, leading to a 7 percent increase of the gel content. Additionally, the decomposition of hard segments of polyurethane acrylate could be avoided by the use of g-C3N4 resulting in an increasing stability to heat. We found the gel content in an aerobic environment was lower than that in an anaerobic environment. On this basis, the function and mechanism of g-C3N4 was investigated in detail and methods to eliminate the O2 were proposed.
