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1.
Polymers (Basel) ; 15(21)2023 Oct 27.
Artigo em Inglês | MEDLINE | ID: mdl-37959919

RESUMO

The condition and health of large oil-immersed power transformers' insulation have a direct impact on the safety and stability of the power grid. Therefore, it is crucial to investigate the aging characteristics of oil-paper insulation in power transformers. In this study, we developed a computational model for reclosing current calculation and multiphysics coupling models for magnetic-circuit-force, electrostatic field, and temperature field simulations. The calculated aging resulted in a mechanical stress of 8.71 MPa, an electric field strength of 2.26 × 106 V/m, and a temperature of 113.7 °C. We conducted combined electrical-thermal-mechanical aging tests on the oil-paper insulation and measured various insulating paper performance parameters at different aging stages. Our study revealed that both the mechanical and electrical properties of the insulating paper deteriorated in both aging groups. However, the changes were more pronounced in the electrical-thermal-mechanical aging group compared to the electrical-thermal aging group, indicating that mechanical stress accelerated the aging process of the insulating paper. In the early stages of aging, the rate of performance changes in the electrical-thermal aging group was similar to that in the electrical-thermal-mechanical aging group. However, as the aging time increased, the degradation of performance induced by mechanical aging became more significant. This suggests that the insulating paper's resistance to mechanical damage, specifically short-circuit resistance, noticeably decreased after prolonged aging.

2.
ACS Appl Mater Interfaces ; 15(46): 53902-53912, 2023 Nov 22.
Artigo em Inglês | MEDLINE | ID: mdl-37935440

RESUMO

The poly(m-phenylene isophthalamide) (PMIA) paper has attracted extensive interests due to its ultrahigh mechanical properties as an ideal protective material for anti-impact damage applications. In the pursuit of additional properties, composites based on the PMIA matrix and various fillers are widely explored. However, additional improvements are frequently obtained at the expense of mechanical properties because of the serious interfacial compatibility brought by different components. In this study, a self-reinforced doping strategy is proposed by combining microscale PMIA fibers as the fillers and nanoscale PMIA fibers as the matrix to form a micronano paper. Without the limitation of the interfacial compatibility issues, the nanofibers are tightly aligned and adhered to the microfibers, enabling the in situ generation of hydrogen bonds at the interfaces. A compact interfacial structure is thus constructed with reduced porosity on the surface. It indicates that the microfibers have a positive impact on the improvement of mechanical properties. In our optimized sample with 5 wt % microfibers, the elastic modulus, tensile strength, and elongation are 1530 MPa, 24.8 MPa, and 5.3%, respectively, which are 142, 49.4, and 65% higher than those of the pristine nano-PMIA paper. In addition, the insulating performance is also improved, facilitating its further application extended to broad fields.

3.
Nanomaterials (Basel) ; 13(11)2023 May 23.
Artigo em Inglês | MEDLINE | ID: mdl-37299608

RESUMO

SF6 gas is an arc extinguishing medium that is widely used in gas insulated switchgear (GIS). When insulation failure occurs in GIS, it leads to the decomposition of SF6 in partial discharge (PD) and other environments. The detection of the main decomposition components of SF6 is an effective method to diagnose the type and degree of discharge fault. In this paper, Mg-MOF-74 is proposed as a gas sensing nanomaterial for detecting the main decomposition components of SF6. The adsorption of SF6, CF4, CS2, H2S, SO2, SO2F2 and SOF2 on Mg-MOF-74 was calculated by Gaussian16 simulation software based on density functional theory. The analysis includes parameters of the adsorption process such as binding energy, charge transfer, and adsorption distance, as well as the change in bond length, bond angle, density of states, and frontier orbital of the gas molecules. The results show that Mg-MOF-74 has different degrees of adsorption for seven gases, and chemical adsorption will lead to changes in the conductivity of the system; therefore, it can be used as a gas sensing material for the preparation of SF6 decomposition component gas sensors.

4.
Polymers (Basel) ; 14(15)2022 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-35956649

RESUMO

The poly-m-phenyleneisophthalamide (PMIA) is widely used in the electrical field due to its numerous favorable characteristics, but its poor thermal conductivity limits its application. In this study, PMIA was modified with nano-silica (SiO2) to improve its thermal and mechanical properties. Using iso-phthalic acid and m-phenylenediamine as monomers, the changes in the thermodynamic properties and microstructure parameters of SiO2-modified PMIA were analyzed using molecular dynamics before and after modification in the temperature range of 250~450 K. It was found that adding SiO2 improves the Young's modulus and Shear modulus of PMIA, and the mechanical properties of PMIA, and SiO2/PMIA composites deteriorate with increasing temperature, but the mechanical properties of SiO2/PMIA composites are always better than those of pure PMIA in the temperature range of electrical equipment. Meanwhile, after doping SiO2 with the radius of 8 Å, the glass transition temperature of PMIA increases by 27.11 K, and its thermal conductivity increases from 0.249 W m-1 K-1 to 0.396 W m-1 K-1. When SiO2 is added to PMIA, the thermal expansion coefficient of PMIA will decrease in both glass and rubber states, and its thermal stability will improve. In terms of microstructure parameters, the free volume distribution of the SiO2/PMIA model is less easily dispersed than that of the PMIA model, indicating that the addition of SiO2 can improve the related properties of PMIA by hindering the movement of molecular chains.

5.
Comput Intell Neurosci ; 2022: 2282870, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35990116

RESUMO

Transformers are an essential part of power production. Insulating paper began to be widely used in transformers in the 1990s. The superior aramid nanofiber as the matrix gives the aramid nano-insulating paper excellent mechanical properties, insulation performance, temperature resistance, and flexibility. At first, the heat resistance and service life of insulating paper should be satisfied for use in electrical equipment. With the continuous development of power equipment, people have put forward higher requirements on the properties of insulating paper, especially heat resistance and electrical properties. Insulation paper made of aramid fibers have better thermal stability and more advantages in electrical and mechanical properties, which can significantly improve the service life and safety of electrical appliances. The purpose of this article is to study the use of aramid nanopaper-based insulating materials in transformers to explore the effect of transformer discharge mechanism on aramid nanopaper-based insulating materials. This paper proposes to design multiple deep learning models to identify the discharge mode of the voltage transformer, find the characteristic signal, and carry out related tests on the discharge signal of different modes, and find the maximum temperature value of the aramid nanopaper-based insulating material for industrial use. The experimental results in this paper show that the aramid nanopaper-based insulating material can be used in transformers discharge detection well, and the safety rate is increased by 20%.

6.
Nanomaterials (Basel) ; 12(5)2022 Feb 23.
Artigo em Inglês | MEDLINE | ID: mdl-35269236

RESUMO

The long-term safe and stable operation of oil-impregnated paper (OIP) bushings is of great significance to the operation of power systems. With the growth of OIP bushing, its internal insulation will gradually decay. Aramid insulation paper has excellent thermal aging characteristics and its insulation performance can be improved by using nano-modification technology. In this paper, the nano-SiO2 particles were used as the modified additives, and the modified aramid insulation paper was prepared through four steps: ultrasonic stirring, fiber dissociation, paper sample copying and superheated calendering. The microscopic physical morphology and chemical components of the insulation specimens before and after modification were analyzed by atomic force microscopy (AFM), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), and an OIP bushing model based on the modified aramid insulation paper was constructed and its electric field distribution was analyzed. The simulation results show that the use of SiO2-modified aramid insulation paper can improve the electric field distribution of OIP bushings and increase the operating life of power transformers.

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