Highly efficient and selective heterogeneous catalytic reduction of 2-nitroaniline by cerium oxide nanocatalyst under microwave irradiation.

Efficient nanocatalyst with incredible performance is highly demanding in a heterogeneous catalysis system. Herein, we report the facile fabrication of uniform and highly stable Cerium Oxide nanoparticles (CeO2 NPs), through chemical precipitation method using sodium hydroxide as reducing agent. The synthesized material is characterized through highly sophisticated techniques including UV-Visible, FT-IR, SEM, AFM, XRD, and Zeta Sizer- Potential to check the particle formation, surface morphology, topography, crystalline nature, size, and surface potential. The heterogeneous catalytic performance of CeO2 NPs has been accomplished for the reduction of 2-nitroaniline from the aqueous media. The CeO2 nanocatalyst displayed excellent reusability, while the reduction in several repetitive catalytic cycles against 2-nitroaniline under optimized conditions. The CeO2 nanocatalyst shows 99.12% efficiency within 60s reaction time under a greener source of microwave radiation.

Fabrication of nickel-tagged magnetic imprinted polymeric network for the selective extraction of Ni(II) from the real aqueous samples.

A new nickel ion, magnetic imprinted polymer was fabricated through the precipitation polymerization process, using amine-functionalized silica-capped iron oxide particles as a core material, and 4-vinyl pyridine as complexing agent methacrylic acid as functional monomer. The resulted magnetic adsorbent was employed to eliminate toxic Ni2+ ions from industrial wastewater. The different parameters were optimized, such as pH, shaking speed, and adsorbent dose, to obtain the maximum adsorption capacity. The synthesized material showed high selectivity coefficient for Ni+2 ions in the presence of other competitive ions and followed pseudo-second-order kinetics and Langmuir isotherm. A good adsorption capacity of 158.73 mg g-1 was obtained at optimized pH 6 in the concentration of 5 mg L-1 nickel ions aqueous solution. The limit of detection, quantification, and the percent relative standard deviation was found to be 0.58, 1.93, and 3.4%. This proves the excellent performance of prepared magnetic Ni(II) ion-imprinted polymer for selective detoxification of Ni2+ ions from real aqueous samples. Due to tunable magnetic properties, the prepared MMIPs are highly selective and sensitive and highly porous in nature; due to excellent magnetic properties, there is no need for centrifugation. Just use external magnetic field, it has good reusability. Showing preparation of Ni (II) imprinted magnetic polymer.

Fabrication of Pt-Pd@ITO grown heterogeneous nanocatalyst as efficient remediator for toxic methyl parathion in aqueous media.

In this study, nano-sized ITO supported Pt-Pd bimetallic catalyst was synthesized for the degradation of methyl parathion pesticide, a common extremely toxic contaminant in aqueous solution. On the characterization with different techniques, a beautiful scenario of honeycomb architecture composed of ultra-small nanoneedles or fine hairs was found. Average size of nanocatalyst also confirmed which was in the range of 3-5 nm. High percent degradation (94%) was obtained in 30 s using 1.5 × 10- 1 mg of synthesized nanocatalyst, 0.5 mM NaBH4, and 110 W microwave radiations power. Recyclability of nanocatalyst was efficient till 4th cycle observed during study of reusability. The supported Pt-Pd bimetallic nanocatalyst on ITO displayed many advantages over conventional methods for degradation of methyl parathion pesticide, such as high percent degradation, short reaction time, small amount of nanocatalyst, and multitime reusability. Graphical abstract Schematic illustration of reaction for degradation of methyl parathion.