Advances on sonophotocatalysis as a water and wastewater treatment technique: efficiency, challenges and process optimisation.

Due to water shortage and increased water pollution, various methods are being explored to improve water quality by treating contaminants. Sonophotocatalysis is a combination of two individual water treatment processes i.e., photocatalysis and sonocatalysis. With advantages including shorter reaction times and enhanced activity, this technique shows possible futuristic applications as an efficient water treatment technology. Herein, background insight on sonophotocalysis as a water and wastewater treatment technique as well as the general mechanism of activity is explained. The commonly used catalysts for sonophotocatalytic applications as well as their synthesis pathways are also briefly discussed. Additionally, the utilisation of sonophotocatalysis for the disinfection of various microbial species as well as treatment of wastewater pollutants including organic (dyes, pharmaceuticals and pesticides) and inorganic species (heavy metals) is deliberated. This review also gives a critical analysis of the efficiency, enhancement strategies as well as challenges and outlooks in this field. It is thus intended to give insight to researchers in the context of facilitating future developments in the field of water treatment, and advancing sonophotocatalysis towards large-scale implementation and commercialization.

Fibrous TiO2 Alternatives for Semiconductor-Based Catalysts for Photocatalytic Water Remediation Involving Organic Contaminants.

Water decontamination remains a challenge in several developed and developing countries. Affordable and efficient approaches are needed urgently. In this scenario, heterogeneous photocatalysts appear as one of the most promising alternatives. This justifies the extensive attention that semiconductors, such as TiO2, have gained over the last decades. Several studies have evaluated their efficiency for environmental applications; however, most of these tests rely on the use of powder materials that have minimal to no applicability for large-scale applications. In this work, we investigated three fibrous TiO2 photocatalysts, TiO2 nanofibers (TNF), TiO2 on glass wool (TGW), and TiO2 in glass fiber filters (TGF). All materials have macroscopic structures that can be easily separated from solutions or that can work as fixed beds under flow conditions. We evaluated and compared their ability to bleach a surrogate dye molecule, crocin, under batch and flow conditions. Using black light (UVA/visible), our catalysts were able to bleach a minimum of 80% of the dye in batch experiments. Under continuous flow experiments, all catalysts could decrease dye absorption under shorter irradiation times: TGF, TNF, and TGW could, respectively, bleach 15, 18, and 43% of the dye with irradiation times as short as 35 s. Catalyst comparison was based on the selection of physical and chemical criteria relevant for application on water remediation. Their relative performance was ranked and applied in a radar plot. The features evaluated here had two distinct groups, chemical performance, which related to the dye degradation, and mechanical properties, which described their applicability in different systems. This comparative analysis gives insights into the selection of the right flow-compatible photocatalyst for water remediation.

The antibacterial and antifungal properties of neutral, octacationic and hexadecacationic Zn phthalocyanines when conjugated to silver nanoparticles.

The syntheses and characterization of novel octacationic and hexadecacationic Pcs is reported. With the aim of enhancing singlet oxygen generation efficiencies and hence antimicrobial activities, these Pcs (including their neutral counterpart) are conjugated to Ag nanoparticles (AgNPs). The obtained results show that the conjugate composed of the neutral Pc has a higher loading of Pcs as well as a greater singlet oxygen quantum yield enhancement (in the presence of AgNPs) in DMSO. The antimicrobial efficiencies of the Pcs and their conjugates were evaluated and compared on S. aureus, E. coli and C. albicans. The cationic Pcs possess better activity than the neutral Pc against all the microorganisms with the hexadecacationic Pc being the best. This work therefore demonstrates that increase in the number of cationic charges on the reported Pcs results in enhanced antimicrobial activities, which is maintained even when conjugated to Ag nanoparticles. The high activity and lack of selectivity of the cationic Pcs when conjugated to Ag NPs against different microorganisms make them good candidates for real life antimicrobial treatments.

The improved antibacterial efficiency of a zinc phthalocyanine when embedded on silver nanoparticle modified silica nanofibers.

This work reports on the fabrication and modification of electrospun polymer free silica nanofibers (SiO2 NFs) with the aim of creating heterogeneous antibacterial catalysts. The optical and photophysical properties of the obtained NFs i.e. bare SiO2, Ag-SiO2, Pc-SiO2 and Pc@Ag-SiO2 NFs (Pc = phthalocyanine) were compared and reported. The singlet oxygen quantum yields of the Pc-SiO2 and Pc@Ag-SiO2 NFs were also quantified and found to be 0.08 and 0.12, respectively, in water. All the modified SiO2 NFs were found to possess photoactivity against S. aureus with the most effective being the Pc@Ag-SiO2 NFs due to the synergy between the Pc and Ag nanoparticles. The bare SiO2 NFs do not exhibit any antibacterial activity while the Ag-SiO2 and Pc@Ag-SiO2 NFs were found to also exhibit dark toxicity. The generated photocatalysts are attractive because they are active against bacteria and they are easily retrievable post-application. The nanocatalysts reported herein are therefore feasible candidates for real-life antibacterial applications.

Dual phototransformation of the pollutants methyl orange and Cr (VI) using phthalocyanine-cobalt ferrite based magnetic nanocomposites.

Bifunctional nanocomposites based on zinc phthalocyanines and glutathione capped CoFe2O4 magnetic nanoparticles (GSH-CoFe2O4 MNPs) are applied in a binary system wherein simultaneous photooxidation of methyl orange (MO) and photoreduction of Cr (VI) are conducted. The photoactivity of two zinc Pcs with different functional moieties are compared based on their interactions with GSH-CoFe2O4 MNPs. Conjugation of the Pcs to the GSH-CoFe2O4 MNPs not only enhanced their singlet oxygen production but also their photocatalytic activity in both photooxidation and photoreduction experiments. Using electron paramagnetic resonance (EPR) spectroscopy, the Pc-MNP conjugates reported herein were found to exhibit superparamagnetic behaviour, giving the advantage of easy separation using an external magnetic field post application, an attractive attribute for heterogeneous catalysis. The catalysts reported herein are therefore good candidates as catalysts for real life water purification analyses as they facilitate the treatment of both organic and inorganic water pollutants.