1.
Chem Commun (Camb)
; 51(6): 1112-5, 2015 Jan 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25461278
RESUMO
3-Aryltetrahydrobenzisoxazoles prepared en route to the coleophomone natural products and analogues, were found to undergo a remarkable base-mediated rearrangement to 2-aryltetrahydrobenzoxazoles. The scope of this unprecedented, facile transformation was probed: a range of analogues was produced, a mechanism proposed, and an application demonstrated by synthesis of a known herbicidal compound.