Research progress of catalysts for synthesis of low-carbon alcohols from synthesis gas.

In recent years, the application value of low-carbon alcohols (C1-C6 alcohols) in the fuel, chemical, environmental protection and other fields has become increasingly prominent. Catalytic conversion of synthesis gas to low-carbon alcohol is one of the important ways to realize the industrial production of low-carbon alcohol. Lack of high-performance catalysts is the main reason that restricts the industrial development of producing low-carbon alcohols from synthesis gas. The construction of a dual active-center catalyst with high activity and stability, and the study of its function and catalytic mechanism have become significantly important. In this paper, the characteristics of the reaction process of syngas to low-carbon alcohols, and the catalytic mechanism and preparation methods of different catalyst systems were reviewed, which provide the basis for further research on high performance catalysts.

Effect of Cu-based metal organic framework (Cu-MOF) loaded with TiO2 on the photocatalytic degradation of rhodamine B dye.

Using copper nitrate trihydrate as the copper source, TiO2@Cu-MOF nanocomposites were prepared by a one-step crystallization method, and the effect of the amount of TiO2 loaded on the adsorption of rhodamine B was studied. X-ray diffraction (XRD), scanning electron microscope (SEM), energy spectrometer (EDS), N2 adsorption-desorption (BET), and infrared spectroscopy (FTIR) were used to characterize the microstructure and surface properties of composite materials. The results show that the composite material not only has a good degradability for rhodamine B, the decolorization rate reaches 98.03% after 120 min, but it also maintains a good cycle performance. Fitting the first-order kinetic equation to the reaction process, under the optimal conditions, R2 = 0.98, indicating that the reaction process conforms to the first-order kinetic equation. Therefore, the catalyst has good catalytic degradation and cycle performance.

Renewable Cyclopentanol From Catalytic Hydrogenation-Rearrangement of Biomass Furfural Over Ruthenium-Molybdenum Bimetallic Catalysts.

Biomass furfural-like compounds are chemicals that cannot be extracted from fossil materials, through which a large number of fine chemicals and fuel additives can be opened up, but one big efficiency problem during the transformation is the accumulation of oligomers. Here, we propose a novel and efficient Ru-Mo bimetallic catalyst for selective hydrogenation-rearrangement of furfural-like compounds. The result showed that an unprecedented rearrangement product selectivity of 89.1% to cyclopentanol was achieved under an optimized reaction condition over a 1%Ru-2.5%Mo/CNT catalyst reduced at 600°C. Subsequent characterization suggested that the catalyst presented with weak acidity and strong hydrogenation activity for the reaction, which not only ensures the smooth hydrogenation-rearrangement reaction but also inhibits the accumulation of furan polymers. These findings provide a convenient strategy to tune the catalytic performance of Mo-based catalysts by controlling the reduction and carburization conditions, which appear to be versatile for the rearrangement of furans and similar compounds.