Assessment of persistent organic pollutants in surface sediments along Lebanese coastal zone.

The levels of some persistent organic pollutants (POPs) along the Lebanese coastal zone (LCZ) were assessed by collecting15 surface sediments from five hotspot stations. Such stations were influenced by various industrial units, riverine input, and touristic activities. The levels of polycyclic aromatic hydrocarbons (∑16PAHs), their methylated derivatives (∑18Me-PAHs), and polychlorinated biphenyls (∑28PCBs) were in the range of 537-3773 µg∙kg-1 dw, 187-1541 µg∙kg-1 dw, and 143-303 µg∙kg-1 dw respectively. Significant contamination was found at Beirut Port that is surrounded by a densely populated area and is subjected to multidisciplinary activities. Source identification of PAHs was confirmed by using the diagnostic ratio of PAHs with low molecular weight and high molecular weight (LMW/HMW). For PCBs, LCZ is polluted by higher chlorinated congeners with 4 to 9 chlorinated atoms generated from volatilization and combustion processes. Toxicity and biological risks were assessed using toxic equivalent quantity (TEQcarc) and sediment quality guideline quotient (SQGq).

Assessment of trace metals contamination in surficial sediments along Lebanese Coastal Zone.

A Characterization and assessment study was conducted for trace metals pollution in surface sediments at six sites including harbors, bays and river input along Lebanese coast (LCZ). A particular attention was given to Tripoli Port in order to identify the main sources of trace metals pollution inside this harbor. Total metals concentrations were compared with those reported for the shale. The results revealed that trace metals (Cd, Pb, Zn, and Cr) contamination was significantly localized at Beirut Port, which is classified as the most highly polluted site. At Tripoli Port site, metals contamination was classified as moderate; it is affected by shipping, ship maintenance activities and sewage outfall. According to the SQGs guideline, the biological adverse effect of Cd, Pb and Zn were expected to occur frequently at Beirut Port. The results obtained would be helpful in developing more effective harbor management strategies to control and monitor the metal discharges.

Distribution of persistent organic pollutants (PAHs, Me-PAHs, PCBs) in dissolved, particulate and sedimentary phases in freshwater systems.

The occurrence of three groups of hazardous organic contaminants (PCBs, PAHs, Me-PAHs) in fifteen watercourses and rivers located in highly urbanized and industrialized zones was studied. The distribution of 62 organic contaminants was determined in three matrices: in the dissolved phase, associated with suspended solid matter (SSM) and in sediment. Their distributions in the aquatic environment depend strongly on their physicochemical properties. Low molecular weight PAHs were predominant in the dissolved phase while those with high molecular weight accumulated preferentially in SSM and sediments. Among the 28 PCBs congeners, only PCB153 was detected. The results showed that the contamination of these areas originated mainly from combustion processes. The three the most polluted sites identified are surrounded by big cities. Ecotoxicological assessment based on the international Sediment Quality Guidelines (SQGs) showed that the toxic effects of the sediment in these watercourses and rivers occurred due to high levels of hydrocarbons.

Organic pollution in surficial sediments of Tripoli harbour, Lebanon.

Tripoli harbour is among the most important ports on the Mediterranean Sea eastern basin. The persistent organic pollutants (POPs) were monitored (28 PCBs, 16 PAHs and 18 Me-PAHs) in 15 stations of Tripoli harbour basins, which are influenced by anthropogenic activities. Total PAHs concentrations ranged from 243 to 2965 µg kg(-1)dw, total Me-PAH concentrations ranged from 54 to 1638 µg kg(-1)dw, while total PCB levels ranged from 18 to 302 µg kg(-1)dw. PCBs profiles were dominated by four and six-chlorinated congeners while the PAHs were dominated by four and five rings. For identifying pollution emission sources of PAHs, different ratios were used. The results show that the pollution origin was predominated by pyrogenic process related to the deposition of coal dust and the combustion of biomass and coal. Based on Sediments Quality Guidelines the biological adverse effects on aquatic ecosystems were expected rarely to occasionally for PAHs and PCBs contamination.