RESUMO
Interest in the importance of gas sensing devices has increased significantly due to their critical function in monitoring the environment and controlling pollution, resulting in an increased market demand. The present review explores perovskite La-Fe-O based gas sensors with a special focus on LaFeO3 and evaluates their sensitivity to a diverse range of practical target gases that need to be monitored. An analysis has been conducted to assess different routes not only of synthesizing LaFeO3 material but also of characterization with the targeted use for their gas sensing abilities. Additionally, a comprehensive analysis has been performed to explore the effect of introducing other elements through doping. In view of the LaFeO3 sensing performance, more common gases like acetone, ethanol, methanol, formaldehyde, NO x , and CO2 have been targeted. In addition, a discussion on uncommon gases such as CO, SO2, TEA, C2H5, C6H6, and others is also made to give a complete picture of LaFeO3-based gas sensors. The summary and conclusion section of the study addresses the primary obstacles in the synthesis process, the variables that restrict the sensing capabilities of LaFeO3, and its commercial fulfillment.
RESUMO
Surface area and surface active sites are two important key parameters in enhancing the gas sensing as well as photocatalytic properties of the parent material. With this motivation, herein, we report a facile synthesis of Reduced Graphene Oxide/Tungsten Oxide RGO/WO3 hierarchical nanostructures via simple hydrothermal route, and their validation in accomplishment of improved H2S sensing and highly efficient solar driven photo-degradation of RhB Dye. The self-made RGO using modified Hummer's method, is utilized to develop the RGO/WO3 nanocomposites with 0.15, 0.3 and 0.5 wt% of RGO in WO3 matrix. As-developed nanocomposites were analyzed using various physicochemical techniques such as XRD, FE-SEM, TEM/HRTEM, and EDAX. The creation of hierarchic marigold frameworks culminated in a well affiliated mesoporous system, offering efficient gas delivery networks, leading to a significant increase in sensing response to H2S. The optimized sensor (RGO/WO3 with 0.3 wt% loading) exhibited selective response towards H2S, which is ~ 13 times higher (Ra/Rg = 22.9) than pristine WO3 (Ra/Rg = 1.78) sensor. Looking at bi-directional application, graphene platform boosted the photocatalytic activity (94% degradation of Rhodamine B dye in 210 min) under natural sunlight. The RGO's role in increasing the active surface and surface area is clarified by the H2S gas response analysis and solar-driven photo-degradation of RhB dye solution. The outcome of this study provides the new insights to RGO/WO3 based nanocomposites' research spreadsheet, in view of multidisciplinary applications.
RESUMO
We report on the electromagnetic properties of Co2+ substituted spinel MgCuZn ferrites developed via a facile molten salt synthesis (MSS) route. The choice of synthesis route in combination with cobalt substitution led to strong electromagnetic properties such as high saturation magnetization (i.e., 63 emu/g), high coercivity (17.86 gauss), and high initial permeability (2730), which are beneficial for the multilayer chip inductor (MLCI) application. In a typical process, the planned ferrites were synthesized at 800 °C using sodium chloride as a growth inhibitor, with dense morphology and irregularity in the monolithicity of the grains. The compositional analysis of as-prepared ferrite confirms the presence of desired elements with their proportion. The crystallite size (using X-ray diffraction (XRD) analysis) for different samples varies in the range of 49-51 nm. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analysis showcases the compact morphology of the developed samples, which is typical in the ferrite system. The dielectric properties (dielectric-loss and dielectric-constant) in the frequency range of 100Hz-1MHz suggest normal dielectric distribution according to interfacial polarization from Maxwell-Wagner. From the developed ferrites, upon comparison with a low dielectric loss with high permeability value, Mg-Cu-Zn ferrite with Co = 0.05 substitution proved to be a stronger material for MLCIs with high-performance applications.
RESUMO
A robust synthesis approach to develop CuO/ZnO nanocomposites using microwave-epoxide-assisted hydrothermal synthesis and their proficiency toward H2S gas-sensing application are reported. The low-cost metal salts (Cu and Zn) as precursors in aqueous media and epoxide (propylene oxide) as a proton scavenger/gelation agent are used for the formation of mixed metal hydroxides. The obtained sol was treated using the microwave hydrothermal process to yield the high-surface area (34.71 m2/g) CuO/ZnO nanocomposite. The developed nanocomposites (1.25-10 mol % Cu doping) showcase hexagonal ZnO and monoclinic CuO structures, with an average crystallite size in the range of 18-29 nm wrt Cu doping in the ZnO matrix. The optimized nanocomposite (2.5 mol % Cu doping) showed a lowest crystallite size of 21.64 nm, which reduced further to 18.06 nm upon graphene oxide addition. Morphological analyses (scanning electron microscopy and transmission electron microscopy) exhibited rounded grains along with copious channels typical for sol-gel-based materials . Elemental mapping displayed the good dispersion of Cu in the ZnO matrix. When these materials are employed as a gas sensor, they demonstrated high sensitivity and selectivity toward H2S gas in comparison with the reducing gases and volatile organic compounds under investigation. The systematic doping of Cu in the ZnO matrix exhibited an improved response from 76.66 to 94.28%, with reduction in operating temperature from 300 to 250 °C. The 2.5 mol % doped Cu in ZnO was found to impart a response of 23 s for 25 ppm of H2S. Gas-sensing properties are described using an interplay of epoxide-assisted sol-gel chemistry and structural and morphological properties of the developed material.
RESUMO
We report a facile, green synthesis of graphene/Ag/ZnO nanocomposites and their use as acetone sensors via a medicinal plant extraction assisted precipitation process. The choice of plant extract in combination with metal nitrates led to self-sustaining colloid chemistry. Along with the green synthesis strategy, structural, morphological and gas sensing properties are described.
RESUMO
We report a facile synthesis of Ru-loaded WO3 marigold structures through a hydrothermal route and their bidirectional applications as enhanced H2S gas sensors and efficient sunlight-driven photocatalysts. The developed hierarchical marigold structures provide effective gas diffusion channels via a well-aligned mesoporous framework, resulting in remarkable enhancement in the sensing response to H2S. The temperature and gas concentration dependence on the sensing properties reveals that Ru loading not only improves the sensing response, but also lowers the operating temperature of the sensor from 275 to 200 °C. The 0.5 wt% Ru-loaded WO3 shows selective response towards H2S, which is 45 times higher (142) than that of pristine WO3 (3.16) sensor, whereas the 0.25 wt% Ru-loaded WO3 exhibits the highest photocatalytic activity, as shown by the degradation of rhodamine B (RhB) under natural sunlight. The gas sensing and photocatalytic properties are explained through the role of Ru and the structural and morphological properties of the developed material.
RESUMO
A robust synthesis approach to transparent conducting oxide (TCO) materials using epoxide assisted sol-gel chemistry is reported. The new route utilizes simple tin and antimony chloride precursors in aqueous solution, thus eliminating the need for organometallic precursors. Propylene oxide acts as a proton scavenger and drives metal hydroxide formation and subsequent polycondensation reactions. Thin films of antimony-doped tin oxide (ATO) were prepared by dip-coating of mixed metal oxide sols. After annealing at 600 °C in air, structural, electrical and optical properties of undoped and Sb-doped tin oxide films were characterized. Single layer films with 5 mol % Sb doping exhibited an optical transparency which was virtually identical to that of the plain glass substrate and an electrical resistivity of 2.8 × 10(-2) Ω cm. SEM and AFM analysis confirmed the presence of surface defects and cracks which increased with increasing Sb dopant concentration. Multiple depositions of identical ATO films showed a roughly 1 order of magnitude decrease in the film resistivity after the third layer, with typical values below 5 × 10(-3) Ω cm. This suggests that a second and third deposition fill up residual cracks and defects in the first layer and thus brings out the full performance of the ATO material. The epoxide-assisted sol chemistry is a promising technique for the preparation of mixed oxide thin film materials. Its superiority over conventional alkoxide and metal salt-based methods is explained in the context of a general description of the reaction mechanism.
RESUMO
Superhydrophobic surfaces with water contact angle higher than 150 degrees generated a lot of interest both in academia and in industry because of the self-cleaning properties. Optically transparent superhydrophobic silica films were synthesized at room temperature (27 degrees C) using sol-gel process by a simple dip coating technique. The molar ratio of MTMS:MeOH:H(2)O (5 M NH(4)OH) was kept constant at 1:10.56:4.16, respectively. Emphasis is given to the effect of the surface modifying agents on the hydrophobic behavior of the films. Methyl groups were introduced in the silica film by post-synthesis grafting from two solutions using trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ) silylating agents in hexane solvent, individually. The percentage of silylating agents and silylation period was varied from 2.5 to 7.5% and 1 to 3 h, respectively. The TMCS modified films exhibited a very high water contact angle (166+/-2 degrees) in comparison to the HMDZ (138+/-2 degrees) modified films, indicating the water repellent behavior of the surface. When the TMCS and HMDZ modified films were heated at temperatures higher than 350 degrees C and 335 degrees C, respectively, the films became superhydrophilic; the contact angle for water on the films was smaller than 5 degrees. Further, the humidity study was carried out at a relative humidity of 85% at 30 degrees C temperature over 30 days. The films have been characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FT-IR), % optical transmission, humidity tests and contact angle (CA) measurements.