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1.
Procedia Comput Sci ; 202: 55-60, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35574223

RESUMO

At the beginning of 2020, COVID-19 began to sweep through China, major schools adhering to the concept of "no classrooms instead of classes" and launching online education. The major online education platforms received the "epidemic advantage" and grew. However, on the night of 24 July 2021, when Chinese authorities have introduced a guideline to ease the burdens of excessive homework and off-campus tutoring for students undergoing compulsory education, so that including online education platforms, received a severe blow. As part of the digital economy, the current transformation of the education sector to education informatization, quality education and vocational education may become the vane of the new era.

2.
ACS Appl Mater Interfaces ; 8(45): 30677-30682, 2016 Nov 16.
Artigo em Inglês | MEDLINE | ID: mdl-27802017

RESUMO

A new concept called "full-spectrum lighting" has attracted considerable attention in recent years. Traditional devices are usually combined with ultraviolet-light-emitting diode (LED), red, green, and blue phosphors. However, a cyan cavity exists in the 480-520 nm region. Hence, cyan phosphors are needed to compensate for the cavity. (Sr,Ba)5(PO4)3Cl:Eu2+ phosphors feature an extremely unique and tunable photoluminescence spectrum. Nevertheless, the tuning mechanisms of these phosphors remain unclear. In this study, we elucidate the mechanism of the cation size-controlled activator uneven-occupation and reoxidation in (Sr,Ba)5(PO4)3Cl:Eu2+ phosphors. This mechanism could help tune the optical properties of related apatite families and structures with multiple cation sites and strongly uneven occupation of activators and cations. Finally, the package of the LED device is constructed to show that both color rendering index Ra and R9 are higher than 95. Thus, the device could be a potential candidate for full-spectrum lighting.

3.
Chem Asian J ; 9(2): 494-9, 2014 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-24203579

RESUMO

Sunlight-excitable orange or red persistent oxide phosphors with excellent performance are still in great need. Herein, an intense orange-red Sr3-xBaxSiO5:Eu(2+),Dy(3+) persistent luminescence phosphor was successfully developed by a two-step design strategy. The XRD patterns, photoluminescence excitation and emission spectra, and the thermoluminescence spectra were investigated in detail. By adding non-equivalent trivalent rare earth co-dopants to introduce foreign trapping centers, the persistent luminescence performance of Eu(2+) in Sr3SiO5 was significantly modified. The yellow persistent emission intensity of Eu(2+) was greatly enhanced by a factor of 4.5 in Sr3SiO5:Eu(2+),Nd(3+) compared with the previously reported Sr3SiO5:Eu(2+), Dy(3+). Furthermore, Sr ions were replaced with equivalent Ba to give Sr3-xBaxSiO5 :Eu(2+),Dy(3+) phosphor, which shows yellow-to-orange-red tunable persistent emissions from λ=570 to 591 nm as x is increased from 0 to 0.6. Additionally, the persistent emission intensity of Eu(2+) is significantly improved by a factor of 2.7 in Sr3-xBaxSiO5 :Eu(2+),Dy(3+) (x=0.2) compared with Sr3SiO5 :Eu(2+),Dy(3+). A possible mechanism for enhanced and tunable persistent luminescence behavior of Eu(2+) in Sr3-xBaxSiO5:Eu(2+),RE(3+) (RE=rare earth) is also proposed and discussed.


Assuntos
Európio/química , Metais Terras Raras/química , Silicatos/química , Estrôncio/química , Medições Luminescentes , Difração de Raios X
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