1.
Org Lett
; 24(41): 7572-7576, 2022 Oct 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36218290
RESUMO
We describe an enantiocontrolled route to a versatile intermediate for the synthesis of highly functionalized clovane-type terpenoids. The synthetic route commenced with (R)-carvone, a commercially available and enantioenriched building block, and an oxygenative strategy was used to concisely access a clovane scaffold. One example of the versatility of the obtained intermediate was the formal synthesis of rumphellclovane E.