Hierarchical hollow porous structures of nickel-doped λ-MnO2 anodes for Li-ion energy storage systems.

Metal oxides with hollow porous structures are attractive and promising anode candidates for Li-ion batteries due to their high surface area, high loading capacity, and low density. In this work, hierarchical hollow porous structures of nickel (Ni)-doped λ-MnO2 were prepared via a facile, and cost-effective approach, where different amounts of Ni were introduced into MnO2 structures to tailor their physical and chemical properties. When the prepared Ni-doped MnO2 hollow structures were studied as anode materials for Li-ion batteries, the electrode showed excellent electrochemical properties, such as stable cyclability and admirable rate capability. Moreover, Ni doping significantly enhances the diffusion properties of the active materials. The material was also investigated as an anode in another high power and energy Li-ion storage device, namely, a Li-ion hybrid capacitor, which exhibited excellent comprehensive electrochemical performance in terms of good specific cell capacity of 25 mA h g-1 at a high current density of 5 A g-1 and achieved a maximum power density of 29 W kg-1 (with energy density of 30 W h kg-1) with a long cycle life. These results indicate that the Ni-doped MnO2 is suitable for application as an anode material and give considerable insight into future Li-energy storage applications.

N-doped CNTs wrapped sulfur-loaded hierarchical porous carbon cathode for Li-sulfur battery studies.

Lithium-sulfur (Li-S) batteries are considered promising next-generation energy storage devices due to their low cost and high energy density (2600 W h kg-1). However, the practical applicability of Li-S batteries is hindered by the insulating nature of sulfur cathodes, and the high solubility of polysulfides (Li2Sx, 3 < x ≤ 8) which are formed during the electrochemical process. Integrating sulfur into the carbon host is an effective way to enhance the conductivity of the electrode which hampers the shuttling effect of the polysulfides. Here in this study, hierarchical porous carbon structures (HPC) are prepared from spent coffee waste (SCW) by the KOH activation process and are encapsulated with sulfur (SHPC) which increases the interaction between sulfur and carbon and enhances both the electronic and ionic conductivities. Further wrapping of SHPC with N-doped multi-walled carbon nanotubes (NCNTs) gives a SHPC-NCNT composite, which alleviates the shuttling of polysulfides by trapping them and ensures the required conductivity to the sulfur cathode during the Li+ reactions. When studied as a cathode material for Li-S batteries, the prepared cathode showed 664 and 532 mA h g-1 specific capacities after 150 cycles at 0.2C and 0.5C, respectively. The stable cyclability and rate capability properties of SPHCNCNT suggest that the prepared sulfur composite is suitable as a cathode material for Li+ energy storage applications.

Hollow nanostructured NiO particles as an efficient electrode material for lithium-ion energy storage properties.

This work has developed a straightforward approach to obtaining NiO hollow structures by using Li2O2 as an easily removable template. The easy availability and electrochemically active nature of NiO have attracted researchers' attention as an anode electrode for Li-ion storage applications, including Li-ion secondary batteries (LIBs) and for Li-ion hybrid supercapacitors (LiHSCs; which offer higher power densities than LIBs without compromising energy density). However, NiO usage has been limited to its low reaction reversibility, poor conductivity, and conversion reaction capability. Recently, hollow nanostructured materials have attracted attention as efficient battery materials due to their fascinating structural features. This study presents a modified Li2O2-assisted method to obtain porous open 3D architectures of NiO nanostructures. The resultant hollow structures are electrochemically studied as an anode for a LIB, exhibiting excellent stability over hundreds of cycles. The result is recognized as one of the finest among NiO anodes reported. Also, NiO hollow structures studied as anodes for LiHSC devices fabricated with activated carbon cathodes exhibit an outstanding comprehensive electrochemical performance which is better than the typical LIB and supercapacitors.

Metal (Cu/Fe/Mn)-Doped Silicon/Graphite Composite as a Cost-Effective Anode for Li-Ion Batteries.

Silicon is a worthy substitute anode material for lithium-ion batteries because it offers high theoretical capacity and low working potentials vs. Li+/Li. However, immense volume changes and the low intrinsic conductivity of Si hampers its practical applications. In this study, nano/micro silicon particles are achieved by ball milling silicon mesh powder as a scalable process. Subsequent metal (Cu/Fe/Mn) doping into nano/micro silicon by low-temperature annealing, followed by high-temperature annealing with graphite, gives a metal-doped silicon/graphite composite. The obtained composites were studied as anodes for Li-ion batteries, and they delivered high reversible capacities of more than 1000 mAh g-1 with improved Li+ diffusion properties. The full cells from these composite anodes vs. LiCoO2 cathodes delivered suitable energy densities for Li+ storage applications. The enhanced electrochemical properties are accredited to the synergistic effect of metal doping and graphite addition to silicon and exhibit potential for suitable Li+ energy storage applications.