Enhancing pyromorphite formation in lead-contaminated soils by improving soil physical parameters using hydroxyapatite treatment.

During chemical immobilization in soil, enhancement of insoluble phases is required to prevent toxic metal from leaching into the surrounding environment. Understanding the effects of physicochemical parameters of soil on the reaction between lead and hydroxyapatite is important to enhance the formation of the insoluble pyromorphite-lead phase. However, the combined effect of soil physical parameters on pyromorphite formation and compressive strength has not been reported. This study aimed to investigate the relationship between soil texture and pyromorphite formation, as well as unconfined compressive strength in lead-contaminated soils treated with hydroxyapatite under different compaction states and moisture conditions. Our findings showed that in compacted soil, >20% of lead was formed as pyromorphite compared with 10% of lead in uncompacted soil. In particular, low porosity and a high saturation ratio of soil under the unsaturated moisture condition were favorable for pyromorphite formation. Under the saturated moisture condition, the addition of hydroxyapatite enhanced pyromorphite formation compared with that under the unsaturated moisture condition. In addition, the leaching of soluble lead into the surrounding environment could be suppressed to <0.05% of lead in soil. The addition of hydroxyapatite also increased compressive strength of the compacted soil with increased curing period despite the soil texture. Our results suggest that treatments such as compacting and seepage control with hydroxyapatite may simultaneously increase pyromorphite formation and compressive strength. Furthermore, when performing soil recycling with hydroxyapatite at sites in the groundwater zone, the soluble lead in the soil is prevented from leaching to the surrounding environment. Hydroxyapatite could be used to enable the reuse of lead-contaminated soil for lead immobilization and to increase compressive strength.

Formation of a lead-insoluble phase, pyromorphite, by hydroxyapatite during lead migration through the water-unsaturated soils of different lead mobilities.

This study combined the original unsaturated-column-percolation test with X-ray diffraction (XRD) analysis to understand how lead is transformed into lead-insoluble phase and immobilized by hydroxyapatite during lead migration in the water-unsaturated soil of different lead mobilities. The amounts of lead migrated from the soils without hydroxyapatite ranged from 4 to 46%, depending on the lead mobilities of soils. On the other hand, those of soils with hydroxyapatite were greatly suppressed by > 95% as compared with those without hydroxyapatite. The XRD analysis showed that the amounts of lead transformed into pyromorphite were compatible with those of lead migrated from the soil irrespective of the different lead mobilities. To the best of our knowledge, this study provides the first experimental evidence that lead migration can induce lead to transform into pyromorphite in the water-unsaturated soil. In addition, this study quantitatively demonstrates that the amount of lead migrated is almost equal to that of lead formed into pyromorphite. Thus, it was found that even if soluble lead remains after the application of immobilization material, it would be immobilized by the material during the lead migration as long as adequate material is applied to the soil.

Simultaneous lead and antimony immobilization in shooting range soil by a combined application of hydroxyapatite and ferrihydrite.

This study investigated whether a combined application of hydroxyapatite and ferrihydrite could immobilize lead and antimony in shooting range soil in which the level of lead contamination is markedly higher than that of antimony. In addition, we evaluated the stability of lead and antimony immobilized by the combined application with varying soil pH. The levels of water-soluble lead and antimony for the combined application were lower than those of single applications of hydroxyapatite or ferrihydrite, indicating that the combined application could suppress the levels of water-soluble lead and antimony by 99.9% and 95.5%, respectively, as compared with the levels in shooting range soil without immobilization material. The amounts of residual lead and amorphous Fe/Al oxide-bound antimony fractions in sequential extraction increased with a decrease in the exchangeable and carbonate lead fractions as well as in non-specifically bound and specifically bound antimony fractions. The alteration of lead and antimony phases to chemically more stable ones as a result of the combined application would result in the suppression of their mobility. The stability of immobilized lead and antimony in the combined application was equal to that of lead with a single application of hydroxyapatite and that of antimony with a single application of ferrihydrite within neutral to alkaline pH conditions, respectively. Therefore, this study suggests that the combined application of hydroxyapatite and ferrihydrite can simultaneously immobilize lead and antimony in shooting range soil with neutral to alkaline pH.