Innovative biopolyelectrolytes-based technologies for wastewater treatment.

Developing eco-friendly, cost-effective, and efficient methods for treating water pollutants has become paramount in recent years. Biopolyelectrolytes (BPEs), comprising natural polymers like chitosan, alginate, and cellulose, have emerged as versatile tools in this pursuit. This review offers a comprehensive exploration of the diverse roles of BPEs in combating water contamination, spanning coagulation-flocculation, adsorption, and filtration membrane techniques. With ionizable functional groups, BPEs exhibit promise in removing heavy metals, dyes, and various pollutants. Studies showcase the efficacy of chitosan, alginate, and pectin in achieving notable removal rates. BPEs efficiently adsorb heavy metal ions, dyes, and pesticides, leveraging robust adsorption capacity and exceptional mechanical properties. Furthermore, BPEs play a pivotal role in filtration membrane techniques, offering efficient separation systems with high removal rates and low energy consumption. Despite challenges related to production costs and property variability, their environmentally friendly, biodegradable, renewable, and recyclable nature positions BPEs as compelling candidates for sustainable water treatment technologies. This review delves deeper into BPEs' modification and integration with other materials; these natural polymers hold substantial promise in revolutionizing the landscape of water treatment technologies, offering eco-conscious solutions to address the pressing global issue of water pollution.

Enhanced bioelectroremediation of heavy metal contaminated groundwater through advancing a self-standing cathode.

Hexavalent chromium (Cr(VI)) contamination in groundwater poses a substantial global challenge due to its high toxicity and extensive industrial applications. While the bioelectroremediation of Cr(VI) has attracted huge attention for its eco-friendly attributes, its practical application remains constrained by the hydrogeochemical conditions of groundwater (mainly pH), low electron transfer efficiency, limitations in electrocatalyst synthesis and electrode fabrication. In this study, we developed and investigated the use of N, S co-doped carbon nanofibers (CNFs) integrated on a graphite felt (GF) as a self-standing cathode (NS/CNF-GF) for the comprehensive reduction of Cr(VI) from real contaminated groundwater. The binder free cathode, prepared through electro-polymerization, was employed in a dual-chamber microbial fuel cell (MFC) for the treatment of Cr (VI)-laden real groundwater (40 mg/L) with a pH of 7.4. The electrochemical characterization of the prepared cathode revealed a distinct electroactive surface area, more wettability, facilitating enhanced adsorption and rapid electron transfer, resulting in a commendable Cr(VI) reduction rate of 0.83 mg/L/h. The MFC equipped with NS/CNF-GF demonstrated the lowest charge transfer resistance (Rct) and generated the highest power density (155 ± 0.3 mW/m2) compared to control systems. The favorable electrokinetics for modified cathode led to swift substrate consumption in the anode, releasing more electrons and protons, thereby accelerating Cr(VI) reduction to achieve the highest cathodic coulombic efficiency (C.Eca)of80 ± 1.3 %. A similar temporal trend observed between Cr(VI) removal efficiency, COD removal efficiency, and C.Eca, underscores the effective performance of the modified electrode. The reusability of the binder free cathode, exemption from catholyte preparation and the absence of pH regulation requirements highlighted the potential scalability and applicability of our findings on a larger scale.

Microplastic particles in river sediments and water of southwestern Nigeria: insights on the occurrence, seasonal distribution, composition, and source apportionment.

Microplastics (MPs) are globally recognized as an emerging environmental threat, particularly in the aquatic environment. This study presents baseline data on the occurrence and distribution of MPs in sediments and surface water of major rivers in southwestern Nigeria. Microplastics were extracted by density separation and polymer identification using Fourier transformed infrared spectroscopy in attenuated total reflectance mode (FTIR-ATR). The abundance of MPs in surface sediment and water samples across all locations ranged from 12.82 to 22.90 particle/kg dw and 6.71 to 17.12 particle/L during the dry season and 5.69 to 14.38 particle/kg dw and 12.41 to 22.73 particle/L during the wet season, respectively. On average, fiber constituted the highest percentage of MP in sediments (71%) and water (67%) while foam accounted for the lowest values of 0.6% and 1.7%, respectively. Polypropylene (PP) and polyethylene (PE) were the main MPs across all locations based on Fourier transform infrared spectroscopy (FTIR). MPs of size < 1 mm were the most abundant (≥ 55%) on average in both water and sediments. The study identified run-off from human activities and industrial wastewater as potential sources of MP exposure based on positive matrix factorization. The study suggests assessing the impact of different land-use activities on MPs occurrence and distribution in addition to quantifying MPs in seafood as a way forward in food safety management systems for further studies. This study confirmed the occurrence and widespread distribution of MPs in surface water and sediments and provides a database on MP pollution in Nigeria.

Sustainable Bifunctional ZnO Composites For Synchronous Adsorption And Reduction Of Cr(VI) to Cr(III).

In decentralized systems, adsorption-based strategies offer inherent advantages for the treatment of drinking water contaminated with oxoanion. However, these strategies only involve phase transfer and not the transformation to an innocuous state. The requirement for an after-treatment procedure to manage the hazardous adsorbent further complicates the process. Here we formulate green bifunctional ZnO composites for the simultaneous adsorption and photoreduction of Cr(VI) to Cr(III). Three non-metal-ZnO composites based on raw charcoal- ZnO, modified charcoal- ZnO charcoal, and chicken feather- ZnO were prepared from the combination of ZnO with non-metal precursors. The composites were characterized and both the adsorption and photocatalyst features were studied, separately, in synthetic feedwater and groundwater contaminated with Cr(VI). The adsorption efficiency of the composites for Cr(VI) at different initial concentrations, under solar illumination without hole scavenger, and in the dark without hole scavenger, were appreciable (between 48 and 71%), and initial concentration dependent. The photoreduction efficiencies (PE%) of all the composites were > 70%, irrespective of the initial Cr(VI) concentration. The occurrence of the transformation of Cr(VI) to Cr(III) during the photoredox reaction was established. Whereas the initial solution pH value, organic load, and ionic strength had no influence on the PE (%) of all the composites, CO32- and NO3- had negative impacts. The PE (%) values of the different ZnO-composites obtained for both the synthetic feedwater and groundwater systems were comparable.

Occurrence and probabilistic risk assessment of polycyclic aromatic hydrocarbons in blood and urine of auto-mechanics in Akure Metro, Nigeria.

This study provides baseline data on the concentration of polycyclic aromatic hydrocarbons (PAHs) in blood and urine samples of auto-mechanics, using Nigeria as a case study. Eighteen auto-mechanics participated in the study excluding two controls. The concentrations for the ΣPAHs across all participants (excluding control) ranged from 1.67 to 3.30 (2.17 ± 0.58) in blood with a significantly higher (P < 0.05) range of 7.61 to 10.76 (8.69 ± 1.00) in urine. The high molecular weight PAHs (4-6 rings) dominated the PAH profile in both blood (≥ 92%) and urine (≥ 87%) across all locations. Dibenz(a)anthracene was the most distributed PAH, while acenaphthene and indeno(1,2,3-cd)pyrene were the least distributed. The dermal route constituted approximately 99% of the total chronic exposure, followed by ingestion, and the least via inhalation. The hazard index (HI) was below the safe thresholds (HI = 1), suggesting non-carcinogenic PAH effects. However, all the participants including control samples had carcinogenic risk (CR) values above the acceptable level of 10-6 in both blood and urine samples. The carcinogenic and mutagenic potencies were higher in urine than in blood. The results suggest less acute toxicity and more potential chronic effects. The computed elimination ratio (> 1) suggests low excretion in urine and a potentially harmful trend. Molecular diagnostic ratios and principal component analysis suggest mixed PAH sources. The study revealed biomonitoring solely dependent on blood analysis may greatly underestimate health risks due to PAH exposure. To the best of our knowledge, this study is the first to provide levels of PAHs in the blood and urine of Nigerian mechanics. Findings herein will support policymakers at all levels in re-focusing attention to the less prioritized professions that pre-disposes people to PAHs and other emerging pollutants in society.

Process variables that defined the phytofiltration efficiency of invasive macrophytes in aquatic system.

Phytofiltration is an eco-friendly and cost-effective approach to the management of pollutants in aquatic system. The present study aimed at elucidating the process variables that defined the phytofiltration efficiency of invasive macrophytes in aquatic system. The invasion of macrophytes, such as Pistia stratiotes, of water bodies is an undesirable experience because of the challenges synonymous with their occurrence. Owing to the unfettered proliferation, high and rich biomass generation, and nutrient uptake capability, these macrophytes outcompete the native vegetation and reduce the distinctiveness of the biological communities at various scales. However, these same intrinsic features positioned them as an ideal phytofiltration species for the decontamination of polluted aqua systems. Herein, we provided an overview of the process of phytofiltration in an aquatic system, and the need to create a balanced ecological system through the exploitation of the potentials of macrophytes as phytoremediators. The translocation factor, type, and concentration of pollutants in the matrix, pH value, type of macrophyte employed are among the factors identified as determinants of the success or failure of invasive macrophytes as pollutant remediators in the aqua system. Therefore, the optimization of these variables, to enhance the phytoremediation potentials of the different macrophytes were critically appraised.

Nutrient recovery from yellow water to soil-crop systems.

The potentials of the nutrient recovered (NRM), via a facile green and sustainable approach from human urine, as a fertilizer in soil-crop system was studied. Nutrient was recovered using a highly decentralized modular reactor, with packed bed of granular gastropod shell. The cultivations of Zea mays (maize) and Solanum lycopersicum (tomato) were the cases studied. The total nutrient composition, the P-speciation, and the safety-risk assessment of the NRM were determined. Using NPK as the standard fertilizer, and a non-fertilized soil as the control, the fertilizing potential of the NRM was evaluated. The influence of the different fertilizer application regimes on the wet and dry biomass nutrient composition, after-harvest soil nutrient composition, and pH values was studied. The NRM contained 106 mg/g of TN and 374.6 mg/g of TP, and the P species identified were Ca2-P (31.66%), Ca8-P (14.99%), and Ca10-P (53.32%). The growth rate of the NRM crops were lower than that of the NPK crops until the 17th day, when the NRM crops grew faster than that of the NPK and control (p < 0.05). The NRM is beneficial to acidic soils and also acts as a slow nutrient releasing fertilizer.

Process enhancing strategies for the reduction of Cr(VI) to Cr(III) via photocatalytic pathway.

This discourse aimed at providing insight into the strategies that can be adopted to boost the process of photoreduction of Cr(VI) to Cr(III). Cr(VI) is amongst the highly detestable pollutants; thus, its removal or reduction to an innocuous and more tolerable Cr(III) has been the focus. The high promise of photocatalysis hinged on the sustainability, low cost, simplicity, and zero sludge generation. Consequently, the present dissertation provided a comprehensive review of the process enhancement procedures that have been reported for the photoreduction of Cr(VI) to Cr(III). Premised on the findings from experimental studies on Cr(VI) reductions, the factors that enhanced the process were identified, dilated, and interrogated. While the salient reaction conditions for the process optimization include the degree of ionization of reacting medium, available photogenerated electrons, reactor ambience, type of semiconductors, surface area of semiconductor, hole scavengers, quantum efficiency, and competing reactions, the relevant process variables are photocatalyst dosage, initial Cr(VI) concentration, interfering ion, and organic load. In addition, the practicability of photoreduction of Cr(VI) to Cr(III) was explored according to the potential for photocatalyst recovery, reactivation, and reuse reaction conditions and the process variables.

Concentrations and Toxic Equivalency of Polycyclic Aromatic Hydrocarbons (PAHs) and Polychlorinated Biphenyl (PCB) Congeners in Groundwater Around Waste Dumpsites in South-West Nigeria.

Polyaromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in groundwater and leachate around selected waste dumpsites from two southwestern states of Nigeria were investigated. Samples were Soxhlet-extracted using hexane/methylene chloride mixture and cleaned-up with preconditioned solid-phase extraction cartridges. The ∑PAHs (PCBs) (all in µg/L) in the boreholes, leachate, and hand-dug well across all locations ranged from below detection limit (BDL) to 0.62 (BDL to 0.067), 1.16 to 9.96 (0.003 to 0.041), and BDL to 0.01 (0.001-0.031), respectively. Low molecular weight-PAHs accounted for ≥61% of ∑PAHs detected across all locations. The highly chlorinated hexa-PCBs [2,2',3,4,4',5'-HeCB(#180), 2,2',3,4',5',6-HeCB(#34) and 2,2',4,4',5,5'-HeCB(#153)] dominated the entire congener profiles. Pyrene and 2,3',4,4',5-PeCB(#118) constituted 56% and 58% of the ∑PAHs and ∑PCBs, respectively. Sampled water is not adequately safe for drinking and may pose cancer risk. This study should be sustained for health risk and sustenance of an enduring ecological integrity.

Bioaccumulation and toxic potencies of polycyclic aromatic hydrocarbons in freshwater biota from the Ogbese River, Nigeria.

Samples of fish and shellfish (periwinkles, mussel, and snail) collected from the rapidly contaminated Ogbese River, Ondo State, Nigeria, were analyzed for their polycyclic aromatic hydrocarbon (PAH) levels by gas chromatography-mass spectrometry after cleanup using solid-phase extraction. The rank order of concentration of ΣPAHs in fish follows: gills >> eggs >>> muscle. The dry weight concentrations (µg/g) of total PAHs ranged from < 0.001 to 2.06, 0.01 to 18.67, 0.01 to 9.56, and 0.01 to 8.28 in fish muscle, periwinkle, snail, and mussel respectively. Accumulation levels of PAHs in the biota were used to calculate biota-sediment (or porewater) accumulation factors (BSAF (BPwAF)) and bioaccumulation factor (BAF). The lower molecular weight PAHs constitute major components (≥ 87% in each case) of PAH congener profiles. Bioaccumulation was greatest for PAHs with log Kow values between 5.0 and 5.6. However, the study did not show a good correlation between log Kow of individual PAH and the corresponding BSAFs/BPwAF for the biota. The study indicates that significantly greater (p < 0.05) BSAFs for ΣPAHs were observed in the three bottom dwellers than in fish muscle which suggests that the sediment-feeding behavior largely affected the extent of PAH bioaccumulation in the aquatic organisms. The calculated potency equivalent concentration (PEC) of total PAHs was above the recommended screening value (SV) in US EPA guidelines, suggesting great concern for human consumption. However, estimated excess cancer risk (ECR) induced by dietary exposure only suggests potential cancer risk. The study suggests urgent remediation of the river to safeguard public health.

Influence of organic carbon and metal oxide phases on sorption of 2,4,6-trichlorobenzoic acid under oxic and anoxic conditions.

Chlorobenzoic acids represent crucial recalcitrant metabolites in the environment; thus, the influence of soil components on the sorption of 2,4,6-trichlorobenzoic acid (TCB) under oxic and anoxic conditions was studied. The surficial physiognomies of untreated and isolated soil samples were studied using FTIR, XRD, specific surface area, and PZC determination. The roles of redox potential, dissolved organic carbon (DOC), and pH, particularly under anoxic condition, were appraised. Batch equilibrium adsorption studies on soils of variable Fe/Mn oxides and organic carbon showed that adsorption was low across all components (log Koc = 0.82-3.10 Lg(-1)). The sorption of 2,4,6-TCB was well described by the pseudo second-order kinetic model. The fluctuation of both redox potential and pH during anoxic experiment had a negative impact on the sorption, partitioning, and the oxidation of organic matter. Linear relationships were observed for Kd with both soil total organic carbon (TOC) and surface area (SA). The results showed the existence of DOC-mediated sorption of 2,4,6-TCB which seems to be enhanced at lower pH. The reductive dissolution, particularly of iron compounds, possibly impeded sorption of 2,4,6-TCB under anoxic condition. It could be inferred that habitats dominated by fluctuating oxygen concentrations are best suited for the development of environmental conditions capable of mineralizing 2,4,6-TCB and similar xenobiotics.