Oriented Tapes of Incompatible Polymers Using a Novel Multiplication Co-Extrusion Process.

Continuous tapes of polypropylene (PP) and high-density polyethylene (HDPE) were produced using a novel multiplication co-extrusion process. The structure of the PP/HDPE tapes consists of co-continuous PP and HDPE domains aligned in the extrusion direction, forming a fiber-like composite structure with individual domain thicknesses of 200-500 nm. This unique structure created a significantly large contact interface between the polymer domains. AFM images suggest strong interfacial interactions between incompatible PP and HDPE domains. Orientation at 130 °C was possible due to the enhanced adhesion arising from epitaxial crystallization and the large interfacial area. The modulus, tensile strength, and orientation factor of the oriented composite tapes increased as the draw ratio increased. The existence of two independent shish kabab-like morphologies in the oriented tapes at different draw ratios was indicated by the appearance of two melting peaks for each material. After one-step orientation at 130 °C to a draw ratio of 25, the moduli of the oriented tapes increased to approximately 10 GPa, and the tensile strength increased to approximately 540 MPa. These oriented tapes are stiffer and stronger than commercial tapes and do not fibrillate during the orientation process indicating some interfacial interaction between the domains.

#funnypoliticians: How Do Political Figures Use Humor on Twitter?

Social media has increased its popularity among politicians. If they wish to succeed in the political arena, politicians need to present themselves to citizens as attractive individuals through these platforms. This study examined how politicians present themselves using humor on Twitter. We analyzed tweets (n = 6,443) from 27 politicians to determine their use of different types of humor and its relationship with age, gender, or political position. We also present changes in humor use in relation to the publication of a political survey in which politicians who were part of this study were evaluated. Results showed politicians' use of humor is relatively low in frequency and primarily aggressive. Politicians who are male, younger, and in the opposition tend to use more aggressive humor. We discuss the results considering the role of aggressive humor in political messages. Based on the analyses of tweets and the publication of the survey, we propose as a hypothesis for future studies that politicians' use of humor on Twitter could be affected by the publication of these kinds of surveys.

Antimicrobial LDPE/EVOH Layered Films Containing Carvacrol Fabricated by Multiplication Extrusion.

This work describes the fabrication of antimicrobial multilayered polymeric films containing carvacrol (used as a model essential oil) by co-extrusion and multiplication technique. The microlayering process was utilized to produce films, with up to 65 alternating layers, of carvacrol-containing low-density polyethylene (LDPE) and ethylene vinyl alcohol copolymer (EVOH). Carvacrol was melt compounded with LDPE or loaded into halloysite nanotubes (HNTs) in a pre-compounding step prior film production. The detailed nanostructure and composition (in terms of carvacrol content) of the films were characterized and correlated to their barrier properties, carvacrol release rate, and antibacterial and antifungal activity. The resulting films exhibit high carvacrol content despite the harsh processing conditions (temperature of 200 °C and long processing time), regardless of the number of layers or the presence of HNTs. The multilayered films exhibit superior oxygen transmission rates and carvacrol diffusivity values that are more than two orders of magnitude lower in comparison to single-layered carvacrol-containing films (i.e., LDPE/carvacrol and LDPE/(HNTs/carvacrol)) produced by conventional cast extrusion. The (LDPE/carvacrol)/EVOH and (LDPE/[HNTs/carvacrol])/EVOH films demonstrated excellent antimicrobial efficacy against E. coli and Alternaria alternata in in vitro micro-atmosphere assays and against A. alternata and Rhizopus in cherry tomatoes, used as the food model. The results presented here suggest that sensitive essential oils, such as carvacrol, can be incorporated into plastic polymers constructed of tailored multiple layers, without losing their antimicrobial efficacy.