Liquid metal assisted sonocatalytic degradation of organic azo dyes to solid carbon particles.

Room temperature liquid metals are an emerging class of materials for a variety of heterogeneous catalytic reactions. In this work we explore the use of Ga based liquid metals as a sonochemical catalyst for the degradation of organic azo dyes such as methyl orange, congo red and eriochrome black T. Rapid degradation to non toxic solid carbon particles was achieved over a large dye concentration range to produce differently sized particles via both bath and probe sonication which could be repeated multiple times with the same catalyst.

Electrochemical Capture and Storage of CO2 as Calcium Carbonate.

A carbon dioxide capture, conversion, and utilization technology has been developed that can be powered by renewable energy with the potential to mitigate CO2 emissions. This relies on an electrochemical process whereby the dissolution of carbon dioxide into carbonate ions is accelerated by a locally induced pH change at the cathode. The carbonate ions can then complex with metal cations, such as Ca2+ , Sr2+ , or Mn2+ , present in solution to form their respective metal carbonates, which precipitate out of solution. To ensure the cathode is not fouled by deposition of the insulating metal carbonate, the process is operated under hydrogen evolution conditions, thereby alleviating any significant attachment of the solid to the electrode. This process is demonstrated in CO2 -saturated solutions while the possibility of direct air capture is also shown, where the precipitation of CaCO3 from atmospherically dissolved CO2 during electrolysis is observed. The latter process can be significantly enhanced by using 5 vol.% of monoethanolamine (MEA) in the electrochemical cell. Finally, the process is investigated using seawater, which is also successful after the initial precipitation of metal sulfates from solution. In particular, the use of renewable energy to capture CO2 and create CaCO3 while also generating hydrogen may be of particular interest to the cement industry, which has a significant CO2 footprint.

Galvanic replacement of liquid metal galinstan with Pt for the synthesis of electrocatalytically active nanomaterials.

The galvanic replacement reaction is a verstile method for the fabrication of bimetallic nanomaterials which is usually limited to solid precursors. Here we report on the galvanic replacement of liquid metal galinstan with Pt which predominantly results in the formation of a Pt5Ga1 material. During the galvanic replacement process an interesting phenomenon was observed whereby a plume of nanomaterial is ejected upwards from the centre of the liquid metal droplet into solution which is due to surface tension gradients on the liquid metal surface that induces surface convection. It was also found that hydrogen gas was liberated during the process facilitated by the formation of the Pt rich nanomaterial which is a highly effective catalyst for the hydrogen evolution reaction (HER). The material was characterised by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction and dynamic light scattering measurements. It was found that Pt5Ga1 was highly effective for the electrochemical oxidation of methanol and ethanol and outperformed a commercial Pt/C catalyst. Density functional theory calculations confirmed that the increased activity is due to the anti poisoning properties of the surface towards CO upon the incorporation of Ga atoms into a Pt catalyst. The use of liquid metals and galvanic replacement offers a simple approach to fabricating Ga based alloy nanomaterials that may have use in many other types of applications.

Microbial cell immobilization in biohydrogen production: a short overview.

The high dependence on fossil fuels has escalated the challenges of greenhouse gas emissions and energy security. Biohydrogen is projected as a future alternative energy as a result of its non-polluting characteristics, high energy content (122 kJ/g), and economic feasibility. However, its industrial production has been hampered by several constraints such as low process yields and the formation of biohydrogen-competing reactions. This necessitates the search for other novel strategies to overcome this problem. Cell immobilization technology has been in existence for many decades and is widely used in various processes such as wastewater treatment, food technology, and pharmaceutical industry. In recent years, this technology has caught the attention of many researchers within the biohydrogen production field owing to its merits such as enhanced process yields, reduced microbial contamination, and improved homogeneity. In addition, the use of immobilization in biohydrogen production prevents washout of microbes, stabilizes the pH of the medium, and extends microbial activity during continuous processes. In this short review, an insight into the potential of cell immobilization is presented. A few immobilization techniques such as entrapment, adsorption, encapsulation, and synthetic polymers are discussed. In addition, the effects of process conditions on the performance of immobilized microbial cells during biohydrogen production are discussed. Finally, the review concludes with suggestions on improvement of cell immobilization technologies in biohydrogen production.