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1.
PLoS One ; 16(6): e0252782, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-34086771

RESUMO

In areas of social exclusion, there are greater risks of facing discrimination at school. The teaching-learning processes may contribute toward the perpetuation of this inequality. This research analyzes a literacy event that takes place in a low-income school in Southern Spain. The new literacy studies have come to examine how power relationships and affective bonds work in such literacy practices. An ethnographic method was followed to facilitate a deeper understanding of multimodal literacy. Further, a social semiotics multimodal approach was adopted to analyze the meaning-making social process that takes place in the classroom. The participants comprised two teachers and 17 children, whose ages range from 5 to 7 years. Data were collected in the form of reports, audio recordings, video recordings, and photographs over a two-years period. The results obtained have revealed that the children have been taught writing and reading through a dominant orthodox model that fails to consider the community's and families' cultural capitals. They also show that the literacy process does not grant any affective quality. Neither is there an authentic dialogic space created between the school and the community. This lack of dialogue generates an inequality in the actual acquisition of comprehensive reading and writing skills at school, with instances of groups exclusion, owing to the anti-hegemonic practices of knowledge acquisition.


Assuntos
Alfabetização , Criança , Pré-Escolar , Humanos , Masculino , Leitura , Instituições Acadêmicas , Espanha
2.
J Photochem Photobiol B ; 179: 32-38, 2018 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-29324295

RESUMO

The objective of this work was to ascertain the nature of the components responsible for the reducing and stabilizing properties of Zostera noltii extracts that lead to gold nanoparticle formation using chemical techniques of analysis. In order to achieve this aim, we try the synthesis of AuNPs with three different extracts from plants collected in the Bay of Cádiz (Spain). The n-butanol extract produced the best results. Taking this into account, four fractions were isolated by Sephadex LH-20 column chromatography from this extract and we studied their activity. The chemical study of these fractions led to the isolation of several flavone sulfates and these were identified as the species' responsible for the formation and stabilization of the AuNPs. Flavone sulfates were purified by high performance liquid chromatography and the structures were established by means of spectroscopic methods nuclear magnetic resonance and mass spectroscopy. AuNPs have an average lifetime of about 16weeks. Additionally, the morphology and crystalline phase of the gold nanoparticles were characterized by transmission electron microscopy. The composition of the nanoparticles was evaluated by electron diffraction and energy dispersive X-ray spectroscopy. An 88% of the gold nanoparticles has a diameter in the range 20-35nm, with an average size of 26±2nm.


Assuntos
Ouro/química , Nanopartículas Metálicas/química , Extratos Vegetais/química , Zosteraceae/química , Cromatografia Líquida de Alta Pressão , Flavonoides/química , Flavonoides/isolamento & purificação , Química Verde , Espectroscopia de Ressonância Magnética , Microscopia Eletrônica de Transmissão , Conformação Molecular , Tamanho da Partícula , Espectrometria por Raios X , Zosteraceae/metabolismo
3.
World J Surg Oncol ; 12: 53, 2014 Mar 06.
Artigo em Inglês | MEDLINE | ID: mdl-24597686

RESUMO

BACKGROUND: Multidisciplinary care is a key enabler in the provision of high quality care for cancer patients. Despite compelling evidence supporting their benefit to patients and for providers, multidisciplinary cancer conferences (MCC) are not universally occurring. Team composition of MCC reflects the multidisciplinary nature of the body. Lack of nursing input can have a negative impact on team decision making. The objective of this study was to evaluate multidisciplinary care and adherence to national recommendations at a medium-sized hospital through a clinical audit of cancer conferences and clinical records. METHODS: A total of 77 multidisciplinary cancer conferences were visited and 496 electronic health records were reviewed. The regularity of meetings and multidisciplinary attendance were evaluated. Each electronic health record was checked to verify documented prospective discussion before any treatment was started. RESULTS: Nine multidisciplinary teams meet on a weekly or biweekly basis at the hospital with an average number of ten people and six different specialties represented. Average duration of meetings was 46.8 min. Though most patients (64.5%) were discussed at some point at the relevant cancer conference, only 40% had a documented multidisciplinary team discussion prior to the first treatment. Pathological stage (pTNM) was documented in 53.6% of clinical records. CONCLUSIONS: Nursing representatives should be included as usual attendees at cancer conferences. Prospective discussion of all cancer cases should be encouraged. Use of checklists and systematic collection of key information, specifically cancer staging, could improve clinical documentation in the electronic clinical record.


Assuntos
Auditoria Clínica , Tomada de Decisões , Equipe de Assistência ao Paciente/organização & administração , Padrões de Prática Médica/organização & administração , Qualidade da Assistência à Saúde/normas , Humanos , Prognóstico , Estudos Prospectivos
4.
Mar Drugs ; 12(2): 682-99, 2014 Jan 27.
Artigo em Inglês | MEDLINE | ID: mdl-24473169

RESUMO

Polyunsaturated aldehydes (PUAs) are organic compounds mainly produced by diatoms, after cell wounding. These compounds are increasingly reported as teratogenic for species of grazers and deleterious for phytoplanktonic species, but there is still scarce information regarding concentration ranges and the composition of PUAs in the open ocean. In this study, we analyzed the spatial distribution and the type of aldehydes produced by the large-sized (>10 µm) phytoplankton in the Atlantic Ocean surface. Analyses were conducted on PUAs released after mechanical disruption of the phytoplankton cells, referred to here as potential PUAs (pPUAs). Results show the ubiquitous presence of pPUA in the open ocean, including upwelling areas, as well as oligotrophic gyres. Total pPUA concentrations ranged from zero to 4.18 pmol from cells in 1 L. Identified PUAs were heptadienal, octadienal and decadienal, with heptadienal being the most common (79% of total stations). PUA amount and composition across the Atlantic Ocean was mainly related to the nitrogen:phosphorus ratio, suggesting nutrient-driven mechanisms of PUA production. Extending the range of trophic conditions considered by adding data reported for productive coastal waters, we found a pattern of PUA variation in relation to trophic status.


Assuntos
Aldeídos/isolamento & purificação , Diatomáceas/metabolismo , Fitoplâncton/metabolismo , Aldeídos/química , Oceano Atlântico
5.
Res Vet Sci ; 90(2): 208-11, 2011 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-20579679

RESUMO

Brucella melitensis is a major human and animal pathogen, with a wide host range that includes all domestic ruminant species, although small ruminants are its preferred hosts. Outbreaks in cattle due to B. melitensis have become a worldwide emerging problem particularly difficult to control due to the lack of knowledge on the epidemiology in this host species and of an effective vaccine. However, combination of molecular tools and strict biosecurity measures can help to solve these difficulties and eventually eradicate the disease from infected herds. In the present report, management of an outbreak in Spain involving four farms, more than 2000 cattle and several human cases is described. Application of Multiple Locus VNTR Analysis (MLVA) allowed identifying the most likely source of infection. Stamping out and test-and-slaughter strategies were applied, proving their usefulness to control the outbreak depending on infection level, and without the need of other alternative measures.


Assuntos
Brucella melitensis/isolamento & purificação , Brucelose Bovina/microbiologia , Surtos de Doenças/veterinária , Animais , Brucelose Bovina/epidemiologia , Bovinos , Testes Sorológicos , Espanha/epidemiologia
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