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1.
Water Sci Technol ; 73(5): 1221-9, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-26942546

RESUMO

This study quantitatively evaluates the antifouling action of the continuous physical treatment with electromagnetic fields (EMFs) of seawater used as heat exchanger fluid in an open rack vaporizer (ORV) pilot plant to reduce the growth of biofouling on external rib-tube surfaces. The results demonstrate that the biofilm adhered on the treated rib-tubes was reduced by 33% in thickness and by 44% in dissolved solids regarding the biofilm adhered on the untreated control rib-tubes. The lower conductivity and Ca(2+) and Mg(2+) ionic content in the effluent of the treated seawater confirmed that the EMFs accelerated the process of ionic calcium nucleation and precipitation as calcium carbonate. The precipitation of ions dissolved affected the inter-molecular interactions among extracellular polymers, thereby weakening the biofouling film matrix and reducing its adhesion capacity. The drag of small particles by the flow of seawater had an erosive action and decreased the biofouling film thickness. Consequently, the antifouling methods treatment with EMFs allowed reduce the negative effect that the biofouling have for the heat transfer equipment used in the regasification process and keep the highest techno-economic operating conditions.


Assuntos
Biofilmes/crescimento & desenvolvimento , Incrustação Biológica , Campos Eletromagnéticos , Carbonato de Cálcio , Precipitação Química , Temperatura Alta , Magnésio/química , Nebulizadores e Vaporizadores , Água do Mar
2.
Biofouling ; 31(6): 527-34, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-26222187

RESUMO

The influence of flow velocity (FV) on the heat transfer process in tubes made from AISI 316L stainless steel in a heat exchanger-condenser cooled by seawater was evaluated based on the characteristics of the resulting biofilm that adhered to the internal surface of the tubes at velocities of 1, 1.2, 1.6, and 3 m s(-1). The results demonstrated that at a higher FV, despite being more compact and consistent, the biofilm was thinner with a lower concentration of solids, and smoother, which favoured the heat transfer process within the equipment. However, higher velocities increase the initial cost of the refrigerating water-pumping equipment and its energy consumption cost to compensate for the greater pressure drops produced in the tube. The velocity of 1.6 m s(-1) represented the equilibrium between the advantages and disadvantages of the variables analysed for the test conditions in this study.


Assuntos
Biofilmes/crescimento & desenvolvimento , Incrustação Biológica/prevenção & controle , Temperatura Alta , Aço Inoxidável , Condutividade Térmica , Movimentos da Água , Pressão , Água do Mar
3.
Biofouling ; 31(1): 19-26, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-25567299

RESUMO

This article discusses the antifouling action of a continuous physical treatment process comprising the application of electromagnetic fields (EMFs) to seawater used as the refrigerant fluid in a heat exchanger-condenser to maintain the initial 'clean tube' condition. The results demonstrated that the EMFs accelerated the ionic nucleation of calcium and precipitation as calcium carbonate, which weakened the growing biofilm and reduced its adhesion capacity. Consequently, EMFs induced an erosive effect that reduced biofilm formation and fouling. This treatment allowed for the maintenance of significantly lower fouling factors in the treated tubes compared to a control group of untreated tubes, thereby leading to a higher heat transfer efficiency.


Assuntos
Biofilmes/crescimento & desenvolvimento , Incrustação Biológica/prevenção & controle , Campos Eletromagnéticos , Água do Mar , Cálcio/química , Carbonato de Cálcio/química , Condutividade Térmica
4.
Biofouling ; 30(1): 95-103, 2014 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-24266611

RESUMO

Electromagnetic field (EMF) treatment is presented as an alternative physical treatment for the mitigation of biofouling adhered to the tubes of a heat exchanger-condenser cooled by seawater. During an experimental phase, a fouling biofilm was allowed to grow until experimental variables indicated that its growth had stabilised. Subsequently, EMF treatment was applied to seawater to eliminate the biofilm and to maintain the achieved cleanliness. The results showed that EMFs precipitated ions dissolved in the seawater. As a consequence of the application of EMFs, erosion altered the intermolecular bonding of extracellular polymers, causing the destruction of the biofilm matrix and its detachment from the inner surface of the heat exchanger-condenser tubes. This detachment led to the partial removal of a mature biofilm and a partial recovery of the efficiency lost in the heat transfer process by using a physical treatment that is harmless to the marine environment.


Assuntos
Incrustação Biológica/prevenção & controle , Campos Eletromagnéticos , Biofilmes , Temperatura Alta , Água do Mar
5.
Biofouling ; 29(9): 1139-51, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-24067104

RESUMO

The effectiveness of two quaternary ammonium compounds (QACs) (non-oxidising biocides) to reduce the growth of biofilm adhering to the tubes of a heat exchanger-condenser cooled by seawater was evaluated. Their effectiveness was compared to that of a conventional oxidising biocide (sodium hypochlorite [NaOCl]) under the same testing conditions. Each biocide was applied intermittently (6 h on, 6 h off) in a first shock stage (1.5 ppm over 8 days) and a second stabilising stage (0.5 ppm over 20 days). The results showed that the antifouling effectiveness of the first of the QACs (fifth generation) was comparable to that shown by the oxidising power of NaOCl. Although the reaction time was longer than that of NaOCl, both the compounds removed the biofilm, and the tube was practically restored to its clean condition. Treatment with the second of the QACs (fourth generation) allowed for the stabilisation of biofilm growth, but not for its removal. Ecotoxicology studies classified the QACs as environmentally harmless under the testing conditions.


Assuntos
Fenômenos Fisiológicos Bacterianos , Biofilmes/efeitos dos fármacos , Incrustação Biológica/prevenção & controle , Desinfetantes/farmacologia , Compostos de Amônio Quaternário/farmacologia , Hipoclorito de Sódio/farmacologia , Temperatura Alta , Centrais Elétricas , Água do Mar/química , Condutividade Térmica
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