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1.
PLoS One ; 19(6): e0305570, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38905234

RESUMO

A range of field-based tests have been proposed for inclusion in physical performance assessment batteries. However, there are obvious time and human resources constraints in applied settings. The knowledge of potential relationships between tests on performance, asymmetries, as well as maturation-induced changes, may help select the most informative and least time-consuming testing battery. The purposes of this study were: (1) to determine correlations in performance between different field-based tests, in interlimb asymmetry between those unilateral tests, and between asymmetry scores and test performances, and (2) to determine the influence of players' maturity status on test performances and asymmetries. A total of 309 male youth soccer players completed a nine-test battery including y-balance test, drop vertical jump, countermovement jump, single leg countermovement jump, standing long jump, single leg hop for distance, Illinois agility test, 10 m sprint, and 20 m sprint. The results revealed moderate-to-very large relationships between jump, sprint, and agility performances (r = 0.43-0.94), but weak-to-moderate correlations between these tests and balance scores (r ≤ 0.38). No relevant relationship (r ≤ 0.32) for asymmetries detected through different unilateral tests was found, nor between asymmetries and performance scores (r < 0.29). While maturity status clearly influenced players' performance, a limited impact on asymmetries was evident. Despite the mentioned relationships, the low shared variance between tests indicates that they should not be used interchangeably, and coaches should select those with the greatest specificity for the sport. Asymmetries do not influence performance, but their prevalence and unchanging nature with maturation can be seen as an opportunity for the identification of highly asymmetrical players and the application of interventions to improve the weaker limb, irrespective of the athlete's stage of development. To this end, the single leg countermovement jump might be viewed as an appropriate test in male youth soccer.


Assuntos
Desempenho Atlético , Futebol , Humanos , Futebol/fisiologia , Masculino , Adolescente , Desempenho Atlético/fisiologia , Criança , Teste de Esforço/métodos
2.
Ann Med ; 56(1): 2337724, 2024 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-38614120

RESUMO

The objectives of this network meta-analysis were: (a) to estimate and compare the pooled effects of some injury prevention programs (IPPs) whose exercise-based components were categorized using a movement pattern-specific taxonomy on reducing overall and some specific body regions (lower extremity, thigh, knee, and ankle) injury incidences in youth team sport athletes and (b) to explore the individual effects of these components on the injury incidence rates (IIRs) previously mentioned. Searches were performed in PubMed, Web of Science, SPORTDiscus, and Cochrane Library. Eligible criteria were: exercise-based interventions comprised of exercises involving athletic motor skill competencies and evaluated against a control group, overall IIRs were reported, and youth (≤19 years old) team sport players. For the current analysis, a taxonomy based on movement patterns was employed for exercise component identification (upper body pushing and pulling; lower body concentric and eccentric; core; mechanics; acceleration; and lower body stability). Pooled effects were calculated by frequentist random effects pairwise and network meta-analyses. Nineteen studies were included. Most of the IPPs exhibit risk reduction when compared to their control groups on overall, lower extremity, and ankle injuries. Interventions comprised of lower body concentric and eccentric, core, mechanics, and lower body stability exercises were the most effective measures for reducing these injuries. None of the IPPs demonstrated to be effective for reducing thigh injuries, and contradictory results were found for knee injuries. Individual analysis at component level revealed that the lower body (bilateral and unilateral, concentric, and eccentric) component was the only one associated with a significant reduction on overall injuries. Indirect evidence suggests that interventions incorporating lower body concentric and eccentric, core, mechanics, and lower body stability exercises might be the most effective for reducing overall, lower extremity, and ankle injuries in youth team sports.


The categorization of exercise components based on the movement patterns might, a priori, be considered a criterion more closely associated with the injury phenomenon.Lower body concentric and eccentric, core, mechanics, and lower body stability exercises should be incorporated to any training program aimed at minimizing the risk of injury in youth.The ineffectiveness of interventions on the reduction of thigh injuries reveals the need for reconsideration of injury prevention strategies.

3.
J Funct Morphol Kinesiol ; 8(4)2023 Nov 30.
Artigo em Inglês | MEDLINE | ID: mdl-38132719

RESUMO

Calf injuries are common in professional football; thus, the establishment of reliable and time-efficient methods of measuring the peak force capabilities of the plantar flexors with equipment that is accessible to football practitioners is valuable. In this study, we determined the preliminary reliability and feasibility of a new test, termed the kneeling isometric plantar flexion test (KIPFT), for footballers. Twenty-one male youth footballers (age = 17.8 ± 1.1 years, height = 182 ± 5 cm, weight = 77.6 ± 5.9 kg) from English League One football clubs completed three trials of the KIPFT on a wireless force plate at the end (2022-2023) and start (2023-2024) of the season. The within-session reliability of the peak force (relative to body weight) was good-excellent for both limbs and both occasions. On average, performance of the KIPFT took just over 1 min per limb and ~2 min to set up. The peak force values were larger for the non-dominant limbs only at the start versus the end of the season, but there were no between-limb differences. From these results, it was determined that (1) the KIPFT is feasible, (2) a minimum of 32 footballers would be required to establish its between-session reliability with ≥80% statistical power and (3) large-cohort normative data for the KIPFT may be best collected at the start of the football season.

4.
PLoS One ; 18(10): e0292487, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-37812631

RESUMO

Musculoskeletal injuries are a common health problem among sporting populations. Such injuries come with a high financial burden to the involved organisations and can have a detrimental impact on the career attainment of injured individuals. Force plates are now a common tool available to sport and exercise science and medicine professionals to enable them to profile injury risk predisposition and modulate the rehabilitation process within sporting environments. This is because contemporary force plate technology is portable and affordable and often comes with software that enables the automatic and immediate feedback of test variables to key stakeholders. However, to our knowledge, to date, there has been no comprehensive review of the scientific literature pertaining to clinical applications of force plate technology. Therefore, this article presents a protocol and a methodological framework to perform a scoping review to identify and map the available scientific literature in which force plates have been applied to the injury profiling and rehabilitation of athletes. The specific aims of the scoping review are 1) to identify and describe the force plate tests, methodologies, and metrics used to screen for injury risk and guide the return of injured athletes to full-time training and competition, 2) to identify potential trends and/or differences by participants' age, sex, and/or level of performance in tests, methodologies, and metrics selected, and 3) to identify key gaps in the existing evidence base and new questions that should be addressed in future research. The global aim of the scoping review is to improve practitioner decision-making around force plate test and variable selection when applied to the injury prevention and rehabilitation of sporting populations.


Assuntos
Traumatismos em Atletas , Medicina , Esportes , Humanos , Traumatismos em Atletas/reabilitação , Atletas , Previsões , Literatura de Revisão como Assunto
5.
ACS Appl Energy Mater ; 5(8): 10216-10223, 2022 Aug 22.
Artigo em Inglês | MEDLINE | ID: mdl-36034760

RESUMO

Most current thermoelectric materials have important drawbacks, such as toxicity, scarceness, and peak operating temperatures above 300 °C. Herein, we report the thermoelectric properties of different crystalline phases of Sn-based perovskite thin films. The 2D phase, Cs2SnI4, is obtained through vacuum thermal deposition and easily converted into the black ß phase of CsSnI3 (B-ß CsSnI3) by annealing at 150 °C. B-ß CsSnI3 is a p-type semiconductor with a figure of merit (ZT) ranging from 0.021 to 0.033 for temperatures below 100 °C, which makes it a promising candidate to power small electronic devices such as wearable sensors which may be interconnected in the so-called Internet of Things. The B-ß phase is stable in nitrogen, whereas it spontaneously oxidizes to Cs2SnI6 upon exposure to air. Cs2SnI6 shows a negative Seebeck coefficient and an ultralow thermal conductivity. However, the ZT values are 1 order of magnitude lower than for B-ß CsSnI3 due to a considerably lower electrical conductivity.

6.
ACS Photonics ; 9(7): 2483-2488, 2022 Jul 20.
Artigo em Inglês | MEDLINE | ID: mdl-35880074

RESUMO

Metal halide perovskites have emerged as a promising group of materials for optoelectronic applications such as photovoltaics, light emission, and photodetectors. So-far, in particular, the stability of light-emitting devices is limited, which is in part attributed to the intrinsic ionic conductivity of these materials. High-performance devices inevitably contain heterojunctions similar to other optoelectronic devices based on oxide perovskites, II-VI, or III-V group semiconductors. To enable efficient heterojunctions, ion exchange at the interface between different layers should be controlled. Herein, we report a method that enables to control and monitor the extent of anion intermixing between solution-processed lead bromide and vacuum-deposited lead chloride perovskite films. Taking advantage of the ability to fine tune the layer thicknesses of the vacuum-deposited films, we systematically study the effect of film thickness on anionic intermixing. Using these multiple layers, we prepare proof of principle light-emitting devices exhibiting green and blue electroluminescence.

7.
Phys Ther Sport ; 56: 48-59, 2022 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-35816871

RESUMO

OBJECTIVES: To explore the incidence, burden, and pattern of injuries in Spanish male youth soccer players during a 9-month competitive season (from September to May-June). DESIGN: Prospective cohort study. PARTICIPANTS: 314 young (10-19 years) soccer players. MAIN OUTCOME MEASURES: Incidence, burden, location, type, severity, mechanism, and circumstance of injuries, as well as potential differences by tactical position, month of the year, age group, and maturity status. RESULTS: A total of 146 time-loss injuries were sustained by 101 different players. This resulted in an overall injury incidence of 3.1 injuries per 1000 h, a training injury incidence of 1.8 injuries per 1000 h, and a match injury incidence of 11.2 injuries per 1000 h. The probability of injury over the season was 34%. Most of the injuries affected the lower extremity and were classified as muscle/tendon injuries, with hamstring muscle injuries representing the most burdensome diagnosis. The incidence of injuries increased with age and maturation, but a heightened risk of overuse injuries during periods around peak height velocity was also identified. CONCLUSIONS: These findings suggest a need for implementing specific injury prevention measures. Due to the high burden shown, these measures should mainly focus on reducing the number and severity of hamstring muscle injuries.


Assuntos
Traumatismos em Atletas , Transtornos Traumáticos Cumulativos , Traumatismos da Perna , Futebol , Lesões dos Tecidos Moles , Adolescente , Traumatismos em Atletas/epidemiologia , Traumatismos em Atletas/prevenção & controle , Transtornos Traumáticos Cumulativos/epidemiologia , Humanos , Incidência , Masculino , Estudos Prospectivos , Futebol/lesões
8.
ACS Energy Lett ; 7(4): 1355-1363, 2022 Apr 08.
Artigo em Inglês | MEDLINE | ID: mdl-35434366

RESUMO

Vacuum processing of multicomponent perovskites is not straightforward, because the number of precursors is in principle limited by the number of available thermal sources. Herein, we present a process which allows increasing the complexity of the formulation of vacuum-deposited lead halide perovskite films by multisource deposition and premixing both inorganic and organic components. We apply it to the preparation of wide-bandgap CsMAFA triple-cation perovskite solar cells, which are found to be efficient but not thermally stable. With the aim of stabilizing the perovskite phase, we add guanidinium (GA+) to the material formulation and obtained CsMAFAGA quadruple-cation perovskite films with enhanced thermal stability, as observed by X-ray diffraction and rationalized by microstructural analysis. The corresponding solar cells showed similar performance with improved thermal stability. This work paves the way toward the vacuum processing of complex perovskite formulations, with important implications not only for photovoltaics but also for other fields of application.

9.
J Strength Cond Res ; 36(5): 1417-1425, 2022 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-32398630

RESUMO

ABSTRACT: Robles-Palazón, FJ, Ayala, F, Cejudo, A, De Ste Croix, M, Sainz de Baranda, P, and Santonja, F. Effects of age and maturation on lower extremity range of motion in male youth soccer players. J Strength Cond Res 36(5): 1417-1425, 2022-Restricted joint range of motion (ROM) has been considered as a primary risk factor for some sport-related injuries. Consequently, preparticipation assessment of lower extremity joints ROM could help identify youth soccer players at high risk of injury and to aid in the design of tailored age and maturational specific training interventions. The purpose of this study was to analyze and compare the influence of chronological age and maturational stage on several lower extremity ROM measures, as well as to describe the lower extremity ROM profile using a comprehensive approach in youth soccer players. A total of 286 male youth soccer players' ROM were assessed including passive hip (extension [PHE], adduction with hip flexed 90° [PHADHF90°], flexion with knee flexed [PHFKF] and extended [PHFKE], abduction with hip neutral [PHABD] and flexed 90° [PHABDHF90°], external [PHER] and internal [PHIR] rotation), knee (flexion [PKF]) and ankle (dorsiflexion with knee flexed [ADFKF] and extended [ADFKE]) ROMs. Between-group differences were analyzed using a one-way analysis of variance (ANOVA) and magnitude-based decisions. The results only report statistically significant (p < 0.05; d > 0.5) and clinically relevant differences (>8°) for the PKF ROM between U12 vs. U19, and Pre-PHV vs. Post-PHV groups. Furthermore, approximately 40, 35, and 20% of players displayed restrictions in their PHFKE, PKF, and ADFKF ROM values, respectively. These findings emphasize the necessity of prescribing (across all age groups and periods of growth and maturation) compensatory measures in daily soccer training, and these exercises should be equally applied to both limbs with the aim of improving PHFKE, PKF and ADFKF ROM values.


Assuntos
Futebol , Adolescente , Feminino , Humanos , Articulação do Joelho , Extremidade Inferior , Masculino , Amplitude de Movimento Articular , Rotação , Futebol/lesões
10.
J Sport Health Sci ; 11(6): 681-695, 2022 11.
Artigo em Inglês | MEDLINE | ID: mdl-34700052

RESUMO

BACKGROUND: To conduct a systematic review and meta-analysis of epidemiological data of injuries in male and female youth football players. METHODS: Searches were performed in MEDLINE/PubMed, Web of Science, Cochrane Library, and SPORTDiscus databases. Studies were considered if they reported injury incidence rate in male and female youth (≤19 years old) football players. Two reviewers (FJRP and ALV) extracted data and assessed trial quality using the Strengthening the Reporting of Observational Studies in Epidemiology (STROBE) statement and the Newcastle Ottawa Scale. The Grading of Recommendations Assessment, Development, and Evaluation approach determined the quality of evidence. Studies were combined using a Poisson random effects regression model. RESULTS: Forty-three studies were included. The overall incidence rate was 5.70 injuries/1000 h in males and 6.77 injuries/1000 h in females. Match injury incidence (14.43 injuries/1000 h in males and 14.97 injuries/1000 h in females) was significantly higher than training injury incidence (2.77 injuries/1000 h in males and 2.62 injuries/1000 h in females). The lower extremity had the highest incidence rate in both sexes. The most common type of injury was muscle/tendon for males and joint/ligament for females. Minimal injuries were the most common in both sexes. The incidence rate of injuries increased with advances in chronological age in males. Elite male players presented higher match injury incidence than sub-elite players. In females, there was a paucity of data for comparison across age groups and levels of play. CONCLUSION: The high injury incidence rates and sex differences identified for the most common location and type of injury reinforce the need for implementing different targeted injury-risk mitigation strategies in male and female youth football players.


Assuntos
Futebol , Adolescente , Adulto , Feminino , Humanos , Masculino , Adulto Jovem
11.
Chem Mater ; 33(18): 7417-7422, 2021 Sep 28.
Artigo em Inglês | MEDLINE | ID: mdl-34602745

RESUMO

Cs2AgBiBr6 has been proposed as a promising lead-free and stable double perovskite alternative to hybrid and lead-based perovskites. However, the low solubility of precursors during wet synthesis, or the distinct volatility of components during evaporation, results in complex multistep synthesis approaches, hampering the widespread employment of Cs2AgBiBr6 films. Here, we present pulsed laser deposition of Cs2AgBiBr6 films as a dry, single-step and single-source deposition approach for high-quality film formation. Cs2AgBiBr6 powders were prepared by mechanochemical synthesis and pressed into a solid target maintaining phase purity. Controlled laser ablation of the double perovskite target in vacuum and a substrate temperature of 200 °C results in the formation of highly crystalline Cs2AgBiBr6 films. We discuss the importance of deposition pressure to achieve stoichiometric transfer and of substrate temperature during PLD growth to obtain high-quality Cs2AgBiBr6 films with grain sizes > 200 nm. This work demonstrates the potential of PLD, an established technique in the semiconductor industry, to deposit complex halide perovskite materials while being compatible with optoelectronic device fabrication, such as UV and X-ray detectors.

12.
ACS Energy Lett ; 6(2): 827-836, 2021 Feb 12.
Artigo em Inglês | MEDLINE | ID: mdl-34568574

RESUMO

Vacuum deposition methods are increasingly applied to the preparation of perovskite films and devices, in view of the possibility to prepare multilayer structures at low temperature. Vacuum-deposited, wide-bandgap solar cells based on mixed-cation and mixed-anion perovskites have been scarcely reported, due to the challenges associated with the multiple-source processing of perovskite thin films. In this work, we describe a four-source vacuum deposition process to prepare wide-bandgap perovskites of the type FA1-n Cs n Pb(I1-x Br x )3 with a tunable bandgap and controlled morphology, using FAI, CsI, PbI2, and PbBr2 as the precursors. The simultaneous sublimation of PbI2 and PbBr2 allows the relative Br/Cs content to be decoupled and controlled, resulting in homogeneous perovskite films with a bandgap in the 1.7-1.8 eV range and no detectable halide segregation. Solar cells based on 1.75 eV bandgap perovskites show efficiency up to 16.8% and promising stability, maintaining 90% of the initial efficiency after 2 weeks of operation.

13.
Phys Ther Sport ; 50: 206-216, 2021 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-34116405

RESUMO

OBJECTIVES: To determine the inter-rater and intra-rater reliability of frontal and sagittal plane landing kinematic measures during drop jump (DVJ) and tuck jump (TJA) tasks in male youth soccer players, to assess the concurrent validity between DVJ and TJA tests, and to evaluate the ability of both tasks to detect differences between players' stage of maturation. DESIGN: Cross-sectional study. PARTICIPANTS: 223 male youth soccer players. MAIN OUTCOME MEASURES: Frontal plane knee projection angles (FPPA), and hip (HF), knee (KF) and ankle (AF) flexion angles at initial contact (IC) and peak flexion (PF) (i.e., the deepest landing position) in the sagittal plane were assessed. RESULTS: Good-to-excellent inter- and intra-rater reliability (ICC > 0.75; TEMST < 0.3; CVTE < 5%) for the FPPA, HF and KF during DVJ and TJA tasks were found. A low concurrent validity between DVJ and TJA measures was reported. Differences by maturity status (BF10 > 10; error < 10; δ > 0.6) were only identified for the TJA. Pre-PHV group reported higher FPPA, HF-IC, HF-PF, and KF-IC values, as well as lower AF-IC than post-PHV. Pre-PHV also displayed greater HF-IC and KF-IC than circa-PHV group. CONCLUSIONS: Although both tests are reliable, the TJA might be viewed as a more informative tool given it shows greater FPPA and can also detect differences by maturity status.


Assuntos
Teste de Esforço/métodos , Extremidade Inferior/fisiologia , Maturidade Sexual , Futebol/fisiologia , Adolescente , Tornozelo/fisiologia , Fenômenos Biomecânicos , Estudos Transversais , Quadril/fisiologia , Humanos , Joelho/fisiologia , Masculino , Amplitude de Movimento Articular , Reprodutibilidade dos Testes
14.
Inorg Chem ; 60(7): 5212-5216, 2021 Apr 05.
Artigo em Inglês | MEDLINE | ID: mdl-33705124

RESUMO

Zero-dimensional (0D) mixed-halide hybrid organic-inorganic MA4PbX6·2H2O (MA = CH3NH3+; X = Br1 - xIx with 0 < x < 1) has been synthesized by a solvent-free mechanochemical approach. It has been shown that this 0D phase with sharp absorption features in the near-UV is a hydrated structure, which can be reversibly transformed into the three-dimensional perovskite phase MAPbX3 by simple thermal annealing (dehydration) in air. This work reveals a new approach to hybrid organic-inorganic perovskites and related 0D structures, which have so far only been thoroughly studied for the inorganic Cs4PbX6 compounds.

15.
Artigo em Inglês | MEDLINE | ID: mdl-32397351

RESUMO

Limited ranges of motion (ROM) have been considered as a relevant risk factor for team sports injuries. The main purposes of the current study were to describe the lower extremity ROM profile, muscular tightness and asymmetries in elite inline hockey players and to examine sex-related differences. Twenty professional inline hockey players from 2 Spanish National Teams (male and female) were measured of passive hip extension [HE], hip adduction with hip flexed 90° [HAD-HF], hip flexion with the knee flexed [HF-KF] and extended [HF-KE], hip abduction with the hip neutral [HAB] and hip flexed 90° [HAB-HF], hip external [HER] and internal [HIR] rotation, knee flexion [KF], ankle dorsiflexion with the knee flexed [ADF-KF] and extended [ADF-KE] ROMs of the dominant and non-dominant leg ROMs were taken. A paired t-test was carried out to assess asymmetries. ROM values were classified as "normal versus tightness", and "normal versus asymmetry" according to the proposed reference values. The effect size for each variable was analyzed. Male team exhibited asymmetry in HF-KF (133.2° dominant vs. 129.8° non-dominant; p = 0.042; d = 0.7243 [moderate effect sizes]) and female team in ADF-KF (38.8° dominant vs. 41.0 non-dominant; p = 0.001; d = 0.6 [moderate effect sizes]) and HAB ROM (41.2° dominant vs. 38.8 non-dominant; p = 0.005; d = 1.1767 [moderate effect sizes]). Male players reported asymmetry in HAD-HF (n = 5), HER (n = 4) and HE (n = 3), whereas female players presented asymmetries in HER (n = 4), HE (n = 3) and KF (n = 2). Overall, 20-100% of all participants showed limited KF, HF_KE, HIR, HE, ADF_KF, HAD-HF, HF-KF, ADF_KE, HTR and HER ROM. The results of this study reinforce the requirement of prescribing exercises aimed at improving hip, knee and ankle ROM within everyday inline hockey practices. In addition, as some asymmetries were found, unilateral flexibility training should be considered where appropriate.


Assuntos
Articulação do Quadril , Hóquei , Amplitude de Movimento Articular , Feminino , Quadril , Humanos , Articulação do Joelho , Masculino , Maleabilidade , Adulto Jovem
16.
Polymers (Basel) ; 12(4)2020 Apr 17.
Artigo em Inglês | MEDLINE | ID: mdl-32316645

RESUMO

A versatile and straightforward route to produce polymer foams with functional surface through their decoration with gold and palladium nanoparticles is proposed. Melamine foams, used as polymeric porous substrates, are first covered with a uniform coating of polydimethylsiloxane, thin enough to assure the preservation of their original porous structure. The polydimethylsiloxane layer allows the facile in-situ formation of metallic Au and Pd nanoparticles with sizes of tens of nanometers directly on the surface of the struts of the foam by the direct immersion of the foams into gold or palladium precursor solutions. The effect of the gold and palladium precursor concentration, as well as the reaction time with the foams, to the amount and sizes of the nanoparticles synthesized on the foams, was studied and the ideal conditions for an optimized functionalization were defined. Gold and palladium contents of about 1 wt.% were achieved, while the nanoparticles were proven to be stably adhered to the foam, avoiding potential risks related to their accidental release.

17.
Artigo em Inglês | MEDLINE | ID: mdl-32120951

RESUMO

The decision-making process about when an athlete may safely return to training and competition after an injury is a difficult decision. Safe return to training and competition is characterised by physical and psychological readiness to return to the sport. The objectives of this study are (1) to assess the measurement properties of the Psychological Readiness of Injured Athlete to Return to Sport questionnaire (PRIA-RS), and (2) to analyse the effectiveness which the PRIA-RS questionnaire possesses when applied during four consecutive seasons on professional soccer players. One hundred and nine male soccer players from the Albacete Soccer Club (Spain) were involved during four consecutive seasons for the current study: 2012-2013, 2013-2014, 2014-2015 and 2015-2016. Psychometric analysis (validity, reliability, internal consistency and effectiveness) and external psychometric analysis (evaluating measures of patient-reported outcomes (EMPRO)) were confirmed and supported. The main results of the study reveal that the psychometric properties of this questionnaire are optimum for their application in a professional sports context.


Assuntos
Atletas/psicologia , Traumatismos em Atletas/psicologia , Psicometria , Volta ao Esporte/psicologia , Futebol , Adulto , Humanos , Masculino , Reprodutibilidade dos Testes , Espanha , Inquéritos e Questionários , Adulto Jovem
18.
Front Psychol ; 10: 2260, 2019.
Artigo em Inglês | MEDLINE | ID: mdl-31681078

RESUMO

The influence on the psychological well-being of the players and their sports performance seems to be one of the keys to the current sports practice. The purpose of this study was to determine the effectiveness of a psychological intervention program for stress control in youth soccer players. A total sample of 19 male youth soccer players (age: 16.3 ± 0.99 years; years playing soccer: 10.89 ± 1.56 years) completed the current research. The Psychological Characteristics Questionnaire related to Sports Performance (CPRD) was used to assess stress factors related to sports competition. A program based on Cognitive-Behavioral Therapy was implemented during eight sessions of approximately 50 min each. A pre-post design was used and statistical differences between pre- and post-measures were checked through dependent sample t-tests. The results indicated that the post-test scores were higher than the pre-tests in "Influence of the Evaluation of Performance" and "Mental Skills" factors, which supposes a significant improvement of the stress management related to performance evaluation, as well as the use of psychological resources and techniques. In addition, the post-test scores were also higher in the "Stress Control" factor, although in this case the differences were not statistically significant. Practical indications deriving from the findings of this study can help youth soccer players to manage the stress of competition using a psychological training program.

19.
Nanoscale ; 11(40): 18739-18745, 2019 Oct 28.
Artigo em Inglês | MEDLINE | ID: mdl-31591610

RESUMO

We developed a facile synthesis of nanocomposite powders of CsPbX3 nanocrystals (NCs) embedded in silica. The synthesis starts from colloidal Cs4PbX6 NCs that are mixed with tetraethyl orthosilicate in the presence of nitric acid, which triggers the sol-gel reaction yielding the formation of SiOx and the conversion of starting NCs into CsPbX3 ones. The overall reaction delivers CsPbX3 NCs encased in a silica matrix. The resulting CsPbX3/SiOx nano-composite powders exhibited enhanced moisture and thermal stability in air. Also, when mixing different CsPbX3/SiOx samples having diverse anion compositions, no interparticle anion exchange processes were observed, which is a further indication that the silica matrix acts as a robust barrier surrounding the NCs. Finallly, we used these composites as down-converter phosphors on top of a blue light-emitting diode (LED), delivering nearly ideal white light emission with the Commission Internationale de l'Eclairage (CIE) color coordinates (0.32, 0.33).

20.
J Phys Chem Lett ; 10(17): 5167-5172, 2019 Sep 05.
Artigo em Inglês | MEDLINE | ID: mdl-31423783

RESUMO

It is widely accepted that a long photoluminescence (PL) lifetime in metal halide perovskite films is a crucial and favorable factor, as it ensures a large charge diffusion length leading to a high power conversion efficiency (PCE) in solar cells. It has been recently found that vacuum-evaporated CH3NH3PbI3 (eMAPI) films show very short PL lifetimes of several nanoseconds. The corresponding solar cells, however, have high photovoltage (>1.1 V) and PCEs (up to 20%). We rationalize this apparent contradiction and show that eMAPI films are characterized by a very high diffusion coefficient D, estimated from modeling the PL kinetics to exceed 1 cm2/s. Such high D values are favorable for long diffusion length as well as fast transport of carriers to film surfaces, where they recombine nonradiatively with surface recombination velocity S ∼ 104 cm/s. Possible physical origins leading to the high D values are also discussed.

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