Droplet-Based Direct-Current Electricity Generation Induced by Dynamic Electric Double Layers.

Harvesting energy from water droplets has received tremendous attention due to the pursuit of sustainable and green energy resources. The droplet-based electricity generator (DEG) provides an admirable strategy to harvest energy from droplets into electricity. However, most of the DEGs merely generate electricity of alternating current (AC) output rather than direct current (DC) without the utilization of rectifiers, impeding its practical applications in energy storage and power supply. Here, a direct current droplet-based electricity generator (DC-DEG) is developed by the simple configuration of the electrodes. The DC output originates from the dynamical electric double layer (EDL) formed at two electrodes and droplet interfaces where the charging/discharging process of EDL capacitance occurs. Several experiments are exhibited to demonstrate the rationality of the proposed principle. The influence of some factors on the output is investigated for further insight into the DC-DEG device. This work provides a novel strategy to harvest energy from water droplets directly into DC electricity and may expand the application of DEGs in powering electronic devices without the help of rectifiers.

Hierarchical porous dual-mode thermal management fabrics achieved by regulating solar and body radiations.

Personal thermal management (PTM) of fabrics is vital for human health; the ever-changing location of the human body poses a big challenge for fabrics to maintain a favorable metabolic temperature. Herein, a dual-mode thermal management fabric is designed to achieve both cooling and heating functions by regulating simultaneously solar and body radiations. The cooling or heating mode can be exchanged by flipping the fabric without an external energy supply. The passive cooling side consists of an electrospun polyacrylonitrile (PAN) fabric with a hierarchical porous structure, exhibiting high sunlight reflectance (91.42%) and an ∼14 °C temperature decrease under direct sunlight irradiation. The co-existence of nanoscale and microscale pores is proven to be essential for improved cooling performances. The other heating side, coated with an MXene layer, shows high photothermal conversion efficiency (37.5%) and outstanding heating capability outdoors. Furthermore, the contrary mid-infrared emissivity of the two sides (high emissivity of the cooling side while low emissivity of the heating side) leads to the dual-mode passive regulation of body thermal energy. Besides, this fabric demonstrates satisfactory wearability and excellent stability. Our work proposes an energy-saving and cost-effective approach for PTM fabrics potentially suitable for various scenarios (e.g., indoors/outdoors, summer/winter, low/high latitude areas).

Suppressing the Exacerbated Hydrogen Evolution of Porous Zn Anode with an Artificial Solid-Electrolyte Interphase Layer.

Rechargeable Zn batteries are widely studied as aqueous, safe, and environmentally friendly alternatives to Li-ion batteries. The 3D porous Zn anode has been extensively reported for suppressing Zn dendrite growth and accelerating the electrode kinetics. However, we demonstrate herein that the undesirable hydrogen evolution reaction (HER) is also exacerbated for porous Zn electrode. Therefore, a polytetrafluoroethylene (PTFE) coating is further applied on the porous Zn serving as the artificial solid-electrolyte interphase (SEI), which is demonstrated to effectively inhibit the hydrogen evolution and maintain the Zn plating kinetics. By utilizing the synergistic effects of the porous morphology and artificial SEI layer, better performances are obtained over porous Zn or bare Zn foil, including dendrite-free Zn plating/stripping up to 2000 h at 2 mA cm-2 and extended cycling in the Zn||V2O5 cell. This work suggests two complementary strategies for achieving simultaneously dendrite-free and side-reaction-suppressed Zn batteries.

Electricity Generation and Self-Powered Sensing Enabled by Dynamic Electric Double Layer at Hydrogel-Dielectric Elastomer Interfaces.

The electric double layer (EDL) at liquid-solid interfaces is fundamental to many research areas ranging from electrochemistry and microfluidics to colloidal chemistry. Here, we demonstrate the electricity generation by mechanically modulating the EDL at the hydrogel-dielectric polymer interfaces. It is found that contact electrification between the hydrogel and the dielectric polymer could charge the dielectric polymer surface at first; the mechanical deformation of the pyramid-shaped hydrogel results in the periodic variation of the EDL area and capacitance, which then induces an alternative current in the external circuits. This mechano-to-electrical energy conversion mechanism is then utilized to construct soft stretchable self-powered pressure sensors by designing dynamic EDL at hydrogel-dielectric elastomer interfaces. The sensitivity is optimized to 1.40 kPa-1 in the low-pressure range of 31-300 Pa by increasing the elastomer roughness. Its antifreeze performance is also improved by adding ethylene glycol into the hydrogel. The capability in detecting subtle human activities is further demonstrated. This mechano-electrical energy conversion and the corresponding self-powered sensor can be widely applied in future soft electronics.

Textile Triboelectric Nanogenerators Simultaneously Harvesting Multiple "High-Entropy" Kinetic Energies.

Distributed renewable kinetic energies are ubiquitous but with irregular amplitudes and frequencies, which, as one category of "high-entropy" energies, are crucial for next-generation self-powered electronics. Herein, we present a flexible waterproof dual-mode textile triboelectric nanogenerator (TENG), which can simultaneously scavenge multiple "high-entropy" kinetic energies, including human motions, raindrops, and winds. A freestanding-mode textile TENG (F-TENG) and a contact-separation-mode textile TENG (CS-TENG) are integrated together. The structure parameters of the textile TENG are optimized to improve the output performances. The raindrop can generate a voltage of up to ∼4.3 V and a current of about ∼6 µA, while human motion can generate a voltage of over 120 V and a peak power density of ∼500 mW m-2. The scavenged electrical energies can be stored in capacitors for powering small electronics. Therefore, we demonstrated a facile preparation of a TENG-based energy textile that is highly promising for kinetic energy harvesting and self-powered electronics.

Triboelectric-optical responsive cholesteric liquid crystals for self-powered smart window, E-paper display and optical switch.

Intelligent responsive devices are crucial for a variety of applications ranging from smart electronics to robotics. Electro-responsive cholesteric liquid crystals (CLC) have been widely applied in display panels, smart windows, and so on. In this work, we realize the mechanical stimuli-triggered optical responses of the CLC by integrating it with a triboelectric nanogenerator (TENG), which converts the mechanical motion into alternating current electricity and then tunes the different optical responses of the CLC. When the voltage applied on the CLC is relatively low (15-40 V), the TENG drives the switching between the bistable planar state and focal conic state of the CLC, which shows potential applications in self-powered smart windows or E-paper displays. When the voltage supplied by the TENG is larger than 60 V, a self-powered optical switch is demonstrated by utilizing the transformation between focal conic state and instantons homeotropic state of the CLC. This triboelectric-optical responsive device consumes no extra electric power and suggests a great potential for future smart electronics.

Boosting performances of triboelectric nanogenerators by optimizing dielectric properties and thickness of electrification layer.

Triboelectric nanogenerators (TENGs) with excellent flexibility and high outputs are promising for powering wearable/wireless electronics with electricity converted from ubiquitous mechanical energies in the working environment. In this work, the effects of the dielectric properties and thickness of the electrification film on the performance of the TENG are discussed. BaTiO3 nanoparticles are added into poly(vinylidene fluoride) (PVDF) to improve the dielectric constant of the composite film. The TENG using a BaTiO3/PVDF nanocomposite film with 11.25 vol% BaTiO3 as the tribo-negative electrification layer is demonstrated to be the optimized one, and generates an open-circuit voltage of 131 V and transferred short-circuit charge density of 89 µC m-2, 6.5 fold higher than those of a TENG using bare a PVDF layer. Furthermore, by reducing the thickness of the BaTiO3/PVDF film to 5 µm, the voltage and charge density increase to 161 V and 112 µC m-2, respectively, and an instantaneous peak power density of 225.6 mW m-2 is obtained.