Ion chromatography for the analysis of glyphosate and its selected metabolites. A review.

Among all known compounds with herbicide activity glyphosate, has been the most commercially successful one. Currently, it is under evaluation because of its possible cancerogenic properties. However, the question is-if it is possible to completely withdraw it from use. Before it can happen, it is important to be sure of all its benefits and limitations, and this requires further detailed research. Due to the extent and prevalence of its use, glyphosate ends up in the environment and then in food and our bodies. There are several methods used for their determination. One of them is ion chromatography. Taking into account its advantages and disadvantages, as well as its rapid development, their importance in this field can be expected to increase in the near future. This paper summarizes the literature data from the past 22 years. The applications of ion chromatography in the determination of glyphosate in various types of environmental, food, and other samples are described. Moreover, the methods used so far are compared with the possibilities offered by ion chromatography, which main advantages and benefits are easy availability, low operating costs, green chemistry aspects, and suitable validation parameters.

Determination of ammonium and biogenic amines by ion chromatography. A review.

The amount and type of chemical compounds found in food products and the environment, which are and should be controlled, is increasing. This is associated with toxicological knowledge, resulting regulations, rapid development of analytical methods and techniques, and sample preparation methods for analysis. These include, among others, ammonia derivatives such as ammonium, and amines, including biogenic amines. Their occurrence in the environment and food is related to their widespread use in many areas of life and their formation as a result of various physical and chemical changes. Analysts use various methods both classical and instrumental to theirs quantify in different matrices such as food, medicinal and environmental samples. Nevertheless, there is still a need for analytical methods with increased matrix-tolerance, selectivity, specificity, and higher sensitivity. While in the determination of ammonium, ion chromatography is a reference method. In the case of biogenic amines, its use for these purposes is not yet so common. However, given ion chromatography its advantages and rapid development, its importance can be expected to increase in the near future, especially at the expense of gas chromatography methods. This paper is a summary of the advantages and limitations of ion chromatography in this important analytical field and a literature review of the past 15 years.

Ion Chromatography and Related Techniques in Carboxylic Acids Analysis.

Ion chromatography (IC) is a variant of high-performance liquid chromatography. Its most important applications include the determination of inorganic and some organic ions in different types of liquid samples. The development of new types of stationary phases with various separation mechanisms, sample preparation methods, and detection modes has extended ion chromatography applications to practically all ionic and ionogenic substances, as well as extending sample types to include gaseous and solid matrices. Carboxylic acids and their derivatives are examples of compounds that are becoming more frequently analyzed using ion chromatography and related techniques. Their occurrence in the environment can be natural or anthropogenic in origin and are broadly used in various industries and daily life. This article discusses the applications of ion chromatography and related techniques for the determination of carboxylic acids in different types of liquid, solid, and gaseous matrices. It also presents detailed methodologies and literature data on this subject from the last 15 years.

Health risk assessment of selected metals through tap water consumption in Upper Silesia, Poland.

The research focused on assessing the risk to human health resulting from the content of selected Cr, Co, Mn, Cu, Ni, Pb, As, Zn and Sr metals in tap water supplied by Upper Silesia Water Plant to the inhabitants of the Upper Silesia region (Poland). It is the main supplier of drinking water to several million inhabitants of this agglomeration. Samples were taken and analyzed quarterly in 2019. The sampling points were chosen to help identify the source when an elevated level of a particular contaminant is observed. ICP-MS and ICP-OES have been used to measure the concentrations of those elements. The chronic daily intake (CDI), hazard quotient (HQ) and hazard index (HI) results for non-carcinogenic risk assessment of metals in tap water has been assessed. CDI values of non-carcinogenic metals were higher in children than in adults; the CDI values for adults and children were found in the order of: Zn > Sr > Cu > Mn > Ni > Pb > Cr > Co > As. All the studied metals had HQ values below 1, the risks caused by the non-carcinogenic metals decreased in the following order: Zn > Cu > Co > As > Sr > Pb > Cr > Ni > Mn. HI values were also less than 1, that meaning that the analyzed tap water is safe for human consumption. The concentration of As, Cr, Cu, Mn and Ni in analyzed tap water is in accordance with Polish and international requirements.