Enhanced emergent electromagnetic inductance in Tb5Sb3 due to highly disordered helimagnetism.

In helimagnetic metals, ac current-driven spin motions can generate emergent electric fields acting on conduction electrons, leading to emergent electromagnetic induction (EEMI). Recent experiments reveal the EEMI signal generally shows a strongly current-nonlinear response. In this study, we investigate the EEMI of Tb5Sb3, a short-period helimagnet. Using small angle neutron scattering we show that Tb5Sb3 hosts highly disordered helimagnetism with a distribution of spin-helix periodicity. The current-nonlinear dynamics of the disordered spin helix in Tb5Sb3 indeed shows up as the nonlinear electrical resistivity (real part of ac resistivity), and even more clearly as a nonlinear and huge EEMI (imaginary part of ac resistivity) response. The magnitude of the EEMI reaches as large as several tens of µH for Tb5Sb3 devices on the scale of several tens of µm, originating to noncollinear spin textures possibly even without long-range helimagnetic order.

Efficient current-induced spin torques and field-free magnetization switching in a room-temperature van der Waals magnet.

The discovery of magnetism in van der Waals (vdW) materials has established unique building blocks for the research of emergent spintronic phenomena. In particular, owing to their intrinsically clean surface without dangling bonds, the vdW magnets hold the potential to construct a superior interface that allows for efficient electrical manipulation of magnetism. Despite several attempts in this direction, it usually requires a cryogenic condition and the assistance of external magnetic fields, which is detrimental to the real application. Here, we fabricate heterostructures based on Fe3GaTe2 flakes that have room-temperature ferromagnetism with excellent perpendicular magnetic anisotropy. The current-driven nonreciprocal modulation of coercive fields reveals a high spin-torque efficiency in the Fe3GaTe2/Pt heterostructures, which further leads to a full magnetization switching by current. Moreover, we demonstrate the field-free magnetization switching resulting from out-of-plane polarized spin currents by asymmetric geometry design. Our work could expedite the development of efficient vdW spintronic logic, memory, and neuromorphic computing devices.

Real-Space Observations of Three-Dimensional Antiskyrmions and Skyrmion Strings.

Nanometric topological spin textures, such as skyrmions (Sks) and antiskyrmions (antiSks), have attracted much attention recently. However, most studies have focused on two-dimensional spin textures in films with inherent or synthetic antisymmetric spin-exchange interaction, termed Dzyaloshinskii-Moriya interaction, although three-dimensional (3D) topological spin textures, such as antiSks composed of alternating Bloch- and Néel-type spin spirals, chiral bobbers carrying emergent magnetic monopoles, and deformed Sk strings, are ubiquitous. To elucidate these textures, we have developed a 3D nanometric magnetic imaging technique, tomographic Lorentz transmission electron microscopy (TEM). The approach enables the visualization of the 3D shape of magnetic objects and their 3D vector field mapping. Here we report 3D vector field maps of deformed Sk-strings and antiSk using the technique. This research approach will lead to discoveries and understanding of fertile 3D magnetic structures in a broad class of magnets, providing insight into 3D topological magnetism.

Formation and Control of Zero-Field Antiskyrmions in Confining Geometries.

Magnetic skyrmions and antiskyrmions have attracted much interest owing to their topological features and spintronic functionalities. In contrast to skyrmions, the generation of antiskyrmions relies on tunning both the magnitude and direction of the external magnetic field. Here, it is reported that antiskyrmions can be efficiently created via quenching and robustly persist at zero field in the Fe1.9 Ni0.9 Pd0.2 P magnet with the S4 -symmetry. It is demonstrated that well-ordered antiskyrmions form in a square lattice in a confining micrometer-scale square geometry, while the antiskyrmion lattice distorts in triangular, circular, or rotated-square geometry; the distortion depends on the relative configuration between sample edges and the two q-vectors arising from the anisotropic Dzyaloshinskii-Moriya interaction, in good agreement with micromagnetic simulations. It is also characterized transformations from antiskyrmions to skyrmions and nontopological bubbles at different directions and values of external field. These results demonstrate a roadmap for generating and controlling antiskyrmions in a confining geometry.

Doping Control of Magnetic Anisotropy for Stable Antiskyrmion Formation in Schreibersite (Fe,Ni)3 P with S4 symmetry.

Magnetic skyrmions, vortex-like topological spin textures, have attracted much interest in a wide range of research fields from fundamental physics to spintronics applications. Recently, growing attention is also paid to antiskyrmions emerging with opposite topological charge in non-centrosymmetric magnets with D2d or S4 symmetry. In these magnets, complex interplay among anisotropic Dzyaloshinskii-Moriya interaction, uniaxial magnetic anisotropy, and magnetic dipolar interactions generates various magnetic textures. However, the precise role of these magnetic interactions in stabilizing antiskyrmions remains to be elucidated. In this work, the uniaxial magnetic anisotropy of schreibersite (Fe,Ni)3 P with S4 symmetry is controlled by doping and its impact on the stability of antiskyrmions is investigated. The authors' magnetometry study, supported by ferromagnetic resonance spectroscopy, shows that the variation of the Ni content and slight doping with 4d transition metals considerably change the magnetic anisotropy. In particular, doping with Pd induces easy-axis anisotropy, giving rise to formation of antiskyrmions, while a temperature-induced spin reorientation is observed in an Rh-doped compound. In combination with Lorentz transmission electron microscopy and micromagnetic simulations, the stability of antiskyrmion as functions of uniaxial anisotropy and demagnetization energy is quantitatively analyzed, and demonstrated that subtle balance between them is necessary to stabilize the antiskyrmions.

Dynamic transition of current-driven single-skyrmion motion in a room-temperature chiral-lattice magnet.

Driving and controlling single-skyrmion motion promises skyrmion-based spintronic applications. Recently progress has been made in moving skyrmionic bubbles in thin-film heterostructures and low-temperature chiral skyrmions in the FeGe helimagnet by electric current. Here, we report the motion tracking and control of a single skyrmion at room temperature in the chiral-lattice magnet Co9Zn9Mn2 using nanosecond current pulses. We have directly observed that the skyrmion Hall motion reverses its direction upon the reversal of skyrmion topological number using Lorentz transmission electron microscopy. Systematic measurements of the single-skyrmion trace as a function of electric current reveal a dynamic transition from the static pinned state to the linear flow motion via a creep event, in agreement with the theoretical prediction. We have clarified the role of skyrmion pinning and evaluated the intrinsic skyrmion Hall angle and the skyrmion velocity in the course of the dynamic transition. Our results pave a way to skyrmion applications in spintronic devices.

Room-temperature antiskyrmions and sawtooth surface textures in a non-centrosymmetric magnet with S4 symmetry.

Topological spin textures have attracted much attention both for fundamental physics and spintronics applications. Among them, antiskyrmions possess a unique spin configuration with Bloch-type and Néel-type domain walls owing to anisotropic Dzyaloshinskii-Moriya interaction in the non-centrosymmetric crystal structure. However, antiskyrmions have thus far only been observed in a few Heusler compounds with D2d symmetry. Here we report a new material, Fe1.9Ni0.9Pd0.2P, in a different symmetry class (S4), in which antiskyrmions exist over a wide temperature range that includes room temperature, and transform into skyrmions on changing magnetic field and lamella thickness. The periodicity of magnetic textures greatly depends on the crystal thickness, and domains with anisotropic sawtooth fractals were observed at the surface of thick crystals and attributed to the interplay between the dipolar interaction and the Dzyaloshinskii-Moriya interaction as governed by crystal symmetry. Our findings provide an arena in which to study antiskyrmions, and should stimulate further research on topological spin textures and their applications.

Bloch Lines Constituting Antiskyrmions Captured via Differential Phase Contrast.

Much scientific capital has been directed toward exotic magnetic spin textures called Bloch lines, that is, Néel-type line boundaries within domain walls, because their geometry promises high-density magnetic storage. While predicted to arise in high-anisotropy magnets, bulk soft magnets, and thin films with in-plane magnetization, Bloch lines also constitute magnetic antiskyrmions, that is, topological antiparticles of skyrmions. Most domain walls occur as Bloch-type or Néel-type, in which the magnetization rotates parallel or perpendicular to the domain wall across its profile, respectively. The Bloch lines' Néel-type rotation and their minute size make them difficult to directly measure. This work utilizes differential phase contrast (DPC) scanning transmission electron microscopy (STEM) to measure the in-plane magnetization of Bloch lines within antiskyrmions emergent in a non-centrosymmetric Heusler magnet with D2d symmetry, Mn1.4 Pt0.9 Pd0.1 Sn, in addition to Bloch-type skyrmions in an FeGe magnet with B20-type crystal structure to benchmark the DPC technique. Both in-focus measurement and identification of Bloch lines at the antiskyrmion's corners are provided.

Nanometric square skyrmion lattice in a centrosymmetric tetragonal magnet.

Magnetic skyrmions are topologically stable spin swirls with a particle-like character and are potentially suitable for the design of high-density information bits. Although most known skyrmion systems arise in non-centrosymmetric systems with a Dzyaloshinskii-Moriya interaction, centrosymmetric magnets with a triangular lattice can also give rise to skyrmion formation, with a geometrically frustrated lattice being considered essential in this case. Until now, it remains an open question if skyrmions can also exist in the absence of both geometrically frustrated lattice and inversion symmetry breaking. Here we discover a square skyrmion lattice state with 1.9 nm diameter skyrmions in the centrosymmetric tetragonal magnet GdRu2Si2 without a geometrically frustrated lattice by means of resonant X-ray scattering and Lorentz transmission electron microscopy experiments. A plausible origin of the observed skyrmion formation is four-spin interactions mediated by itinerant electrons in the presence of easy-axis anisotropy. Our results suggest that rare-earth intermetallics with highly symmetric crystal lattices may ubiquitously host nanometric skyrmions of exotic origins.

Tumor-targeting and imaging micelles for pH-triggered anticancer drug release and combined photodynamic therapy.

Herein, we construct a charge - switchable polymer nano micelles poly (2-(hexamethyl eneimino) ethyl methacrylate) - b - poly (ethylene glycol) monomethyl ether methacrylate) - b - poly (diethyl enetriaminepentaacetic acid methacrylate) - b - poly (1-vinyl imidazole) - b - poly (4-vinyl phenylboronic acid) (PC7A-PEG-DTPA-VI-PBA) in different pH solutions. DOX released faster from micelles in a weakly acidic environment (pH 5.0) than at pH 7.4. In order to enhance the anti-tumor effect, the imidazole functional groups in the polymer were used to coordinate CdSeTe quantum dots (QDs) for photodynamic treatment (PDT). In addition, the surfaces of the micelles were further decorated with phenylboronic acidas a targeting group, using DTPA chelating 99mTc for SPECT imaging.It has been successfully demonstrated that the nanoparticles have a good cumulative effect on the tumor site.The structure of the polymer was characterized by 1HNMR. The morphology and particle size of the micelles were characterized by transmission electron microscopy (TEM) and dynamic light scattering (DLS). The drug loading capacity (DLC) and drug loading efficiency (DLE) of the micelles were analyzed by ultraviolet visible spectroscopy. And the pH-sensitive drug release and cytotoxicity of the micelles were verified in vitro. In vitro experiments showed that the nano micelles were noncytotoxic to different cell lines, while DOX@CdSeTe@PC7A-PEG-DTPA-VI-PBA inhibited the proliferation and promoted the apoptosis of B16F10 cells. An in vivo study with C57BL tumor-bearing mice indicated that DOX@CdSeTe@PC7A-PEG-DTPA-VI-PBA nano micelles efficiently inhibited tumor growth. Results showed that the nano micelles had good pH responsibility and biocompatibility, and the loaded DOX could be released in the weak acidic environment of tumor cells, and it was expected to be a good drug delivery system.

Controlled transformation of skyrmions and antiskyrmions in a non-centrosymmetric magnet.

Control of topological spin textures in magnetic systems may enable future spintronic applications. Magnetic field pulses can switch the vortex polarity1 or the winding number of magnetic bubbles2. Thermal energy can reverse the helicity of skyrmions3 and induce the transformation between meron and skyrmion by modifying the in-plane anisotropy4,5. Among the various topological spin textures, skyrmions6,7 and antiskyrmions8-10 are nanometric spin-whirling structures carrying integer topological charges (N) of -1 and +1 (refs. 7,11,12), respectively, and can be observed in real space8,13. They exhibit different dynamical properties under current flow14-18, for example, opposite signs for the topological Hall effect. Here we observe, in real space, transformations among antiskyrmions, non-topological (NT) bubbles and skyrmions (with N of +1, 0 and -1, respectively) and their lattices in a non-centrosymmetric Heusler magnet, Mn1.4Pt0.9Pd0.1Sn, with D2d symmetry. Lorentz transmission electron microscopy images under out-of-plane magnetic fields show a square lattice of square-shaped antiskyrmions near the Curie temperature and a triangular lattice of elliptically deformed skyrmions with opposite helicities at lower temperatures. The clockwise and counter-clockwise helicities of the skyrmions originate from Dzyaloshinskii-Moriya interactions with opposite signs along the [100] and [010] directions, respectively. A variation of the in-plane magnetic field induces a topological transformation from antiskyrmions to NT-bubbles and to skyrmions, which is accompanied by a change of the lattice geometry. We also demonstrate control of the helicity of skyrmions by variations of the in-plane magnetic field. These results showcase the control of the topological nature of spin configurations in complex magnetic systems.

Skyrmion phase and competing magnetic orders on a breathing kagomé lattice.

Magnetic skyrmion textures are realized mainly in non-centrosymmetric, e.g. chiral or polar, magnets. Extending the field to centrosymmetric bulk materials is a rewarding challenge, where the released helicity/vorticity degree of freedom and higher skyrmion density result in intriguing new properties and enhanced functionality. We report here on the experimental observation of a skyrmion lattice (SkL) phase with large topological Hall effect and an incommensurate helical pitch as small as 2.8 nm in metallic Gd3Ru4Al12, which materializes a breathing kagomé lattice of Gadolinium moments. The magnetic structure of several ordered phases, including the SkL, is determined by resonant x-ray diffraction as well as small angle neutron scattering. The SkL and helical phases are also observed directly using Lorentz-transmission electron microscopy. Among several competing phases, the SkL is promoted over a low-temperature transverse conical state by thermal fluctuations in an intermediate range of magnetic fields.

Relaxation Dynamics of Zero-Field Skyrmions over a Wide Temperature Range.

The promise of magnetic skyrmions in future spintronic devices hinges on their topologically enhanced stability and the ability to be manipulated by external fields. The technological advantages of nonvolatile zero-field skyrmion lattice (SkL) are significant if their stability and reliability can be demonstrated over a broad temperature range. Here, we study the relaxation dynamics including the evolution and lifetime of zero-field skyrmions generated from field cooling (FC) in an FeGe single-crystal plate via in situ Lorentz transmission electron microscopy (L-TEM). Three types of dynamic switching between zero-field skyrmions and stripes are identified and distinguished. Moreover, the generation and annihilation of these metastable skyrmions can be tailored during and after FC by varying the magnetic fields and the temperature. This dynamic relaxation behavior under the external fields provides a new understanding of zero-field skyrmions for their stability and reliability in spintronic applications and also raises new questions for theoretical models of skyrmion systems.

The indispensable role of the transversal spin fluctuations mechanism in laser-induced demagnetization of Co/Pt multilayers with nanoscale magnetic domains.

The switching of magnetic domains induced by an ultrashort laser pulse has been demonstrated in nanostructured ferromagnetic films. This leads to the dawn of a new era in breaking the ultimate physical limit for the speed of magnetic switching and manipulation, which is relevant to current and future information storage. However, our understanding of the interactions between light and spins in magnetic heterostructures with nanoscale domain structures is still lacking. Here, both time-resolved magneto-optical Kerr effect experiments and atomistic simulations are carried out to investigate the dominant mechanism of laser-induced ultrafast demagnetization in [Co/Pt]20 multilayers with nanoscale magnetic domains. It is found that the ultrafast demagnetization time remains constant with various magnetic configurations, indicating that the domain structures play a minor role in laser-induced ultrafast demagnetization. In addition, both in experiment and atomistic simulations, we find a dependence of ultrafast demagnetization time τ M on the laser fluence, which is in contrast to the observations of spin transport within magnetic domains. The remarkable agreement between experiment and atomistic simulations indicates that the local dissipation of spin angular momentum is the dominant demagnetization mechanism in this system. More interestingly, we made a comparison between the atomistic spin dynamic simulation and the longitudinal spin flip model, highlighting that the transversal spin fluctuations mechanism is responsible for the ultrafast demagnetization in the case of inhomogeneous magnetic structures. This is a significant advance in clarifying the microscopic mechanism underlying the process of ultrafast demagnetization in inhomogeneous magnetic structures.

Multiple tuning of magnetic biskyrmions using in situ L-TEM in centrosymmetric MnNiGa alloy.

Magnetic skyrmions are topologically protected spin configurations and have recently received growingly attention in magnetic materials. The existence of biskyrmions within a broad temperature range has been identified in our newly-discovered MnNiGa material, promising for potential application in physics and technological study. Here, the biskyrmion microscopic origination from the spin configuration evolution of stripe ground state is experimentally identified. The biskyrmion manipulations based on the influences of the basic microstructures and external factors such as grain boundary confinement, sample thickness, electric current, magnetic field and temperature have been systematically studied by using real-space Lorentz transmission electron microscopy. These multiple tuning options help to understand the essential properties of MnNiGa and predict a significant step forward for the realization of skyrmion-based spintronic devices.

Real-Space Observation of Nonvolatile Zero-Field Biskyrmion Lattice Generation in MnNiGa Magnet.

Magnetic skyrmions, particular those without the support of external magnetic fields over a wide temperature region, are promising as alternative spintronic units to overcome the fundamental size limitation of conventional magnetic bits. In this study, we use in situ Lorentz microscope to directly demonstrate the generation and sustainability of robust biskyrmion lattice at zero magnetic field over a wide temperature range of 16-338 K in MnNiGa alloy. This procedure includes a simple field-cooling manipulation from 360 K (higher than Curie temperature TC ∼ 350 K), where topological transition easily occurs by adapting the short-range magnetic clusters under a certain magnetic field. The biskyrmion phase is favored upon cooling below TC. Once they are generated, the robust high-density biskyrmions persist even after removing the external magnetic field due to the topological protection and the increased energy barrier.

A Centrosymmetric Hexagonal Magnet with Superstable Biskyrmion Magnetic Nanodomains in a Wide Temperature Range of 100-340 K.

Superstable biskyrmion magnetic nanodomains are experimentally observed for the first time in a hexagonal MnNiGa, a common and easily produced centrosymmetric material. The biskyrmion states in MnNiGa thin plates, as determined by the combination of in situ Lorentz transmission electron microscopy images, magnetoresistivity, and topological Hall effect measurements, are surprisingly stable over a broad temperature range of 100-340 K.

Tuning of Photoluminescence by Cation Nanosegregation in the (CaMg)(x)(NaSc)(1-x)Si2O6 Solid Solution.

Controlled photoluminescence tuning is important for the optimization and modification of phosphor materials. Herein we report an isostructural solid solution of (CaMg)x(NaSc)1-xSi2O6 (0 < x < 1) in which cation nanosegregation leads to the presence of two dilute Eu(2+) centers. The distinct nanodomains of isostructural (CaMg)Si2O6 and (NaSc)Si2O6 contain a proportional number of Eu(2+) ions with unique, independent spectroscopic signatures. Density functional theory calculations provided a theoretical understanding of the nanosegregation and indicated that the homogeneous solid solution is energetically unstable. It is shown that nanosegregation allows predictive control of color rendering and therefore provides a new method of phosphor development.