Evaluation of the Effect of Polyethylenimine on Boron Adsorption by Soil Minerals.

The removal of hazardous ions from water is crucial for safeguarding both the environment and human health. Soil minerals, integral components of soil, play a vital role as adsorbents for various contaminants, including heavy metal ions, organic dyes, and detergents. This study investigates the interaction between boron ions and soil minerals (gibbsite, kaolinite, and montmorillonite) in the presence of polyethylenimine (PEI). The minerals underwent characterization based on specific surface area, particle size distribution, zeta potential, and the presence of functional groups. The influence of PEI addition on the stability of the soil mineral suspension was evaluated by turbidimetry. Mineral-boron and mineral-boron-PEI interactions were explored under varying conditions, including pH, initial boron concentration, and mineral quantity, with all adsorption experiments conducted over 24 hours. Using the Langmuir isotherm, the maximum adsorption capacity of the studied minerals was determined for boron both without and in the presence of PEI. For gibbsite, kaolinite and montmorillonite, it was 30.63, 24.55 and 26.62 mg g-1, respectively, while in the presence of PEI, it increased to 33.11, 26.61 and 45.47 mg g-1, respectively. The addition of PEI enhanced boron adsorption from aqueous solutions, increasing the removal efficiency from 65 % to about 80 %.

Bioconversion of waste glycerol into viscosinamide by Pseudomonas fluorescens DR54 and its activity evaluation.

Lipopeptides, derived from microorganisms, are promising surface-active compounds known as biosurfactants. However, the high production costs of biosurfactants, associated with expensive culture media and purification processes, limit widespread industrial application. To enhance the sustainability of biosurfactant production, researchers have explored cost-effective substrates. In this study, crude glycerol was evaluated as a promising and economical carbon source in viscosinamide production by Pseudomonas fluorescens DR54. Optimization studies using the Box - Behnken design and response surface methodology were performed. Optimal conditions for viscosinamide production including glycerol 70.8 g/L, leucine 2.7 g/L, phosphate 3.7 g/L, and urea 9.3 g/L were identified. Yield of viscosinamide production, performed under optimal conditions, reached 7.18 ± 0.17 g/L. Preliminary characterization of viscosinamide involved the measurement of surface tension. The critical micelle concentration of lipopeptide was determined to be 5 mg/L. Furthermore, the interactions between the viscosinamide and lipase from Candida rugosa (CRL) were investigated by evaluating the impact of viscosinamide on lipase activity and measuring circular dichroism. It was observed that the α-helicity of CRL increases with increasing viscosinamide concentration, while the random coil structure decreases.

Application of amino-hypophosphite polyampholyte for purification of wastewater containing Ni(ii) ions.

This study investigated the sorption of Ni(ii) ions from an aqueous solution using novel, synthetic amino-hypophosphite polyampholyte resin (AHP) in a batch adsorption system. The removal of Ni(ii) ions was determined as a function of pH (2.0-8.0), initial concentration of Ni(ii) ions (2.0-20.0 mM), resin dosage (1.0-10.0 g dm-3), contact time (0.04-24 h), and temperature (298-318 K). Moreover, continuous fixed-bed column sorption was also studied using model solutions and actual wastewater from the galvanising plant. The batch sorption experimental data showed that the maximum pH for efficient Ni(ii) ion removal was about 5.0. An equilibrium was reached after about 24 hours. The kinetics results were fitted using pseudo-first-order (PFO), pseudo-second-order (PSO), liquid film (LFD), and intraparticle diffusion (IPD) models. Freundlich and Langmuir isotherm models were applied for sorption equilibrium data. The maximum sorption capacity was obtained from the Langmuir equation to be 2.39, 2.52, and 2.62 mmol g-1 at 298, 308, and 318 K, respectively. The thermodynamic parameters for the sorption of Ni(ii) ions on AHP imply the endothermic and spontaneous character of the process. The experimental results demonstrated that amino-hypophosphite polyampholyte resin could be used to effectively remove Ni(ii) ions from model solutions and real wastewater.

Production and characterization of lipopeptide biosurfactant from a new strain of Pseudomonas antarctica 28E using crude glycerol as a carbon source.

Pseudomonas is a cosmopolitan genus of bacteria found in soil, water, organic matter, plants and animals and known for the production of glycolipid and lipopeptide biosurfactants. In this study bacteria (laboratory collection number 28E) isolated from soil collected in Spitsbergen were used for biosurfactant production. 16S rRNA sequencing and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF) revealed that this isolate belongs to the species Pseudomonas antarctica. In the present study, crude glycerol, a raw material obtained from several industrial processes, was evaluated as a potential low-cost carbon source to reduce the costs of lipopeptide production. Among several tested glycerols, a waste product of stearin production, rich in nitrogen, iron and calcium, ensured optimal conditions for bacterial growth. Biosurfactant production was evidenced by a reduction of surface tension (ST) and an increase in the emulsification index (E24%). According to Fourier-transform infrared spectroscopy (FTIR) and electrospray ionization mass spectrometry (ESI-MS), the biosurfactant was identified as viscosin. The critical micelle concentration (CMC) of lipopeptide was determined to be 20 mg L-1. Interestingly, viscosin production has been reported previously for Pseudomonas viscosa, Pseudomonas fluorescens and Pseudomonas libanensis. To the best of our knowledge, this is the first report on viscosin production by a P. antarctica 28E. The results indicated the potential of crude glycerol as a low-cost substrate to produce a lipopeptide biosurfactant with promising tensioactive and emulsifying properties.

Accumulation of toxic Pb(II) ions by the iron-containing minerals in the presence of ionic polyacrylamide soil conditioner.

The aim of this research was to determine the adsorption-desorption, surface, electrokinetic, and stability properties of aqueous suspensions of iron-containing minerals in the presence of anionic polyacrylamide (AN PAM) and lead(II) ions. Three minerals found in the soil environment, akaganeite, goethite, and magnetite, were synthesized based on the precipitation method. The interaction mechanism of heavy metal ions with polymer flocculant, which are adsorbed on the soil mineral particles, was proposed. It was shown that the best affinity to the AN PAM or/and Pb(II), adsorbed both from single and mixed solution, shows akageneite (characterized by the highly developed specific surface area). Polymer-metal complexes formed in the mixed adsorbate systems are rather stable, evidence of which is reduced desorption and consequently limited bioavailability of toxic lead ions for organisms and plants in soil environment.

Copper(II) ions removal from model galvanic wastewater by green one-pot synthesised amino-hypophosphite polyampholyte.

The amino-hypophosphite polyampholyte (AHP) obtained from cheap and safe building blocks lacks a typical ion-scavenger matrix derived from crude-oil intermediates like poly(divinylbenzene), which is an advantage to commercial solutions. AHP is characterised by sorption capacity comparable to some ion scavengers available on the market, as it was found that its maximum capacity in the temperature range from 298 K to 328 K varies between 114 and 146 mg Cu(II) g-1 of dry AHP. The possible application of the AHP in the Cu(II) removal process from galvanic effluent was investigated. The results show that it is possible to achieve a good removal rate for model wastewater. The inlet Cu2+ concentrations of model wastewater were 6.4 mg Cu(II) dm-3 and 36,2 mg Cu(II) dm-3, acidic and basic galvanic wastewater respectively. After the removal process concentrations were lowered to 1.3 mg Cu(II) dm-3 and 5.1 mg Cu(II) dm-3, for acidic and basic galvanic wastewater respectively. It was found that the presence of Ca(II) and Na(I) did not significantly influence the Cu(II) removal process. The obtained results indicate that the prepared more environmentally safe ion scavenger can be applicable in a wide range of metal ion removal processes.

Effect of ultrasound pre-treatment on carbonaceous copper-bearing shale flotation.

Although numerous studies have been implemented on identifying the impact of acoustic waves on mineral beneficiation, its fundamental aspects remain unclear in the literature. The present work, for the first time, systematically investigates the role of ultrasound pre-treatment (UPT) in the carbonaceous copper-bearing shale flotation. To this end, conditioning was carried out at different powers of applied ultrasound. Non-treated and UPT shale flotation tests were performed in the presence of frother (MIBC) and collector (KEX). To analyse particle surface charge variation and collector adsorption properties after application of UPT, zeta potential and ultraviolet-visible spectroscopy measurements were implemented, respectively. The generation of sub-micron bubbles due to the acoustic cavitation was characterised by laser-based particle size measurements. Shale hydrophobicity was determined using the sessile drop and captive bubble techniques. The micro-flotation results showed that the mass recovery increased by 40% at 20 W of applied ultrasonic power. The positive effect of UPT on the copper-bearing shale flotation was related to: i) generation of ultrafine bubbles due to the acoustic cavitation phenomenon and ii) the cleaning effect through transient bubble collapse. However, rigorous ultra-sonication diminished the recoverability of the sample owing to the less intensified number of ultrafine bubbles on the particle surfaces and formation of free H and OH radicals, which led to the oxidation of particle surfaces. These statements were correlated well with the observations of the zeta potential, particle size analysis and quantified ultrafine bubbles. Finally, we briefly highlighted fundamental knowledge gaps in flotation and ultrasound-related issues for future work.

Rhamnolipids as Effective Green Agents in the Destabilisation of Dolomite Suspension.

In this paper, we describe an application of mono- and dirhamnolipid homologue mixtures of a biosurfactant as a green agent for destabilisation of a dolomite suspension. Properties of the biosurfactant solution were characterised using surface tension and aggregate measurements to prove aggregation of rhamnolipids at concentrations much lower than the critical micelle concentration. Based on this information, the adsorption process of biosurfactant molecules on the surface of the carbonate mineral dolomite was investigated, and the adsorption mechanism was proposed. The stability of the dolomite suspension after rhamnolipid adsorption was investigated by turbidimetry. The critical concentration of rhamnolipid at which destabilisation of the suspension occurred most effectively was found to be 50 mg·dm-3. By analysing backscattering profiles, solid-phase migration velocities were calculated. With different amounts of biomolecules, this parameter can be modified from 6.66 to 20.29 mm·h-1. Our study indicates that the dolomite suspension is destabilised by hydrophobic coagulation, which was proved by examining the wetting angle of the mineral surface using the captive bubble technique. The relatively low amount of biosurfactant used to destabilise the system indicates the potential application of this technology for water treatment or modification of the hydrophobicity of mineral surfaces in mineral engineering.

A review of polyampholytic ion scavengers for toxic metal ion removal from aqueous systems.

Pollution by heavy metal ions in aqueous systems gained researchers attention gradually. Toxic metal ions were always present in the environment and the living organisms could get used to specific concentrations of contaminants with given time, however, sudden concentration rise we are observing can make it impossible for the living organisms to adapt. Many ion removal technologies were developed and optimised over the years to cope with this problem, including chemical precipitation, adsorption, membrane filtration and ion-exchange. Adsorption and ion exchange are processes that employ certain materials, that can be collectively named ion scavengers, to remove ions from aqueous solutions. Some of the scavenger materials are still barely studied, in particular polyampholytes - polymeric zwitterionic materials. This review showcases papers published on toxic metal ion removal by polyampholytes, both commercial and experimental, over last two decades. Many recent publications show promising properties of experimental materials that match or even outperform commercial scavengers. This review was prepared to encourage other researchers to investigate this broad and still not well-studied class of materials especially in context of their ion-scavenging properties. Polyamphytes which may be especially worth the attention and further research have been highlighted as literature studies show that the most unexplored materials in the class of polyamphytes are those containing aminomethylphosphonate, aminomethylsulfonate or hypophosphorous acid group.

Comparison of Cr(VI) Adsorption Using Synthetic Schwertmannite Obtained by Fe3+ Hydrolysis and Fe2+ Oxidation: Kinetics, Isotherms and Adsorption Mechanism.

Good sorption properties and simple synthesis route make schwertmannite an increasingly popular adsorbent. In this work, the adsorption properties of synthetic schwertmannite towards Cr(VI) were investigated. This study aimed to compare the properties and sorption performance of adsorbents obtained by two methods: Fe3+ hydrolysis (SCHA) and Fe2+ oxidation (SCHB). To characterise the sorbents before and after Cr(VI) adsorption, specific surface area, particle size distribution, density, and zeta potential were determined. Additionally, optical micrographs, SEM, and FTIR analyses were performed. Adsorption experiments were performed in varying process conditions: pH, adsorbent dosage, contact time, and initial concentration. Adsorption isotherms were fitted by Freundlich, Langmuir, and Temkin models. Pseudo-first-order, pseudo-second-order, intraparticle diffusion, and liquid film diffusion models were used to fit the kinetics data. Linear regression was used to estimate the parameters of isotherm and kinetic models. The maximum adsorption capacity resulting from the fitted Langmuir isotherm is 42.97 and 17.54 mg·g-1 for SCHA and SCHB. Results show that the adsorption kinetics follows the pseudo-second-order kinetic model. Both iron-based adsorbents are suitable for removing Cr(VI) ions from aqueous solutions. Characterisation of the adsorbents after adsorption suggests that Cr(VI) adsorption can be mainly attributed to ion exchange with SO42- groups.

Surfactin as a Green Agent Controlling the Growth of Porous Calcite Microstructures.

This study presents a new, simple way to obtain mesoporous calcite structures via a green method using an eco-friendly surface-active compound, surfactin, as a controlling agent. The effects of synthesis time and surfactin concentration were investigated. The obtained structures were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) coupled with gas mass spectrometry (QMS) analysis. The experimental data showed that surfactin molecules significantly changed the morphology of the calcite crystals, roughening and deforming the surface and creating a greater specific surface area, even at low biosurfactant concentrations (10 ppm). The size of the crystals was reduced, and the zeta potential value of calcium carbonate was more negative when more biosurfactant was added. The XRD data revealed that the biomolecules were incorporated into the crystals and slowed the transformation of vaterite into calcite. It has been shown that as long as vaterite is present in the medium, the calcite surface will be less deformed. The strong influence of surfactin molecules on the crystal growth of calcium carbonate was due to the interaction of surfactin molecules with free calcium ions in the solution as well as the biomolecules adsorption at the formed crystal surface. The role of micelles in crystal growth was examined, and the mechanism of mesoporous calcium carbonate formation was presented.

Effect of a lipopeptide biosurfactant on the precipitation of calcium carbonate.

Observing flora and fauna, it can be said that nature is a great architect. Nature can create amazing structures with unique properties that may find potential applications in industry. This phenomenon is why the biomimetic synthesis of calcium carbonate with various polymorphs, sizes and morphologies using natural biomolecules, such as proteins and polysaccharides, has become an interesting topic in recent years. This novel work uses natural surfactants produced by Bacillus species (surfactins) in the formation of calcium carbonate particles. Calcium carbonate was synthesized by the reaction of Na2CO3 and CaCl2. The effects of surfactin concentration and pH on calcium carbonate crystal growth were investigated. Precipitated calcium carbonate was characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) analysis, scanning electron microscopy (SEM) and atomic force microscopy (AFM). The pore size and specific surface area were measured via the BET isotherm method. Surfactin molecules were observed to prevent the transformation of vaterite into calcite in the reaction system, especially at pH 8. Surfactin possesses two negatively charged groups (COO-), which have strong affinity towards metal ions at pH 8. When the surfactin concentration was 20 ppm, the surfaces of calcite crystals were punctuated by spherical and oval depressions. Surface roughness may substantially improve the properties of the obtained structures, for example, as inorganic templates for polymeric capsules.

Synthetic Iron Oxides for Adsorptive Removal of Arsenic.

Removal of arsenic from water reservoirs is the issue of great concern in many places around the globe. As adsorption is one of the most efficient techniques for treatment of As-containing media, thus the present study concerns application of iron oxides-hydroxides (akaganeite) as adsorbents for removal of this harmful metal from aqueous solution. Two types of akaganeite were tested: synthetic one (A) and the same modified using hexadecyltrimethylammonium bromide (AM). Removal of As was tested in batch studies in function of pH, adsorbent dosage, contact time, and initial arsenic concentration. The adsorption isotherms obey Langmuir mathematical model. Adsorption kinetics complies with pseudo-second-order kinetic model, and the constant rates were defined as 2.07 × 10-3and 0.92 × 10-3 g mg-1 min-1 for the samples (A) and (AM), respectively. The difference was caused by significant decrease in adsorption rate in initial state of the process carried out for the sample AM. The maximum adsorption capacity achieved for (A) and (AM) akaganeite taken from Langmuir isotherm was 148.7 and 170.9 mg g-1, respectively. The results suggest that iron oxides-hydroxides can be used for As removal from aqueous solutions.

Protein-Mediated Precipitation of Calcium Carbonate.

Calcium carbonate is an important component in exoskeletons of many organisms. The synthesis of calcium carbonate was performed by mixing dimethyl carbonate and an aqueous solution of calcium chloride dihydrate. The precipitation product was characterized by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR) measurements. In addition, the turbidity of the reaction solution was acquired to monitor the kinetics of the calcium carbonate structure's growth in the investigated system. In this study, samples of CaCO3 particles obtained with individual proteins, such as ovalbumin, lysozyme, and a mixture of the proteins, were characterized and compared with a control sample, i.e., synthesized without proteins. The obtained data indicated that the addition of ovalbumin to the reaction changed the morphology of crystals from rhombohedral to 'stack-like' structures. Lysozyme, however, did not affect the morphology of calcium carbonate, yet the presence of the protein mixture led to the creation of more complex composites in which the calcium carbonate crystals were constructed in protein matrices formed by the ovalbumin-lysozyme interaction. It was also observed that in the protein mixture, ovalbumin has a major influence on the CaCO3 formation through a strong interaction with calcium ions, which leads to the coalescence and creation of a steric barrier reducing particle growth. The authors proposed a mechanism of calcium carbonate grain growth in the presence of both proteins, taking into account the interaction of calcium ions with the protein.

Conformational state of ß-hydroxynaphthylamides: Barriers for the rotation of the amide group around CN bond and dynamics of the morpholine ring.

Three ß-hydroxynaphthylamides (morpholine, pyrrolidine and dimethylamine derivatives) have been synthesized and their conformational state was analyzed by NMR, X-ray and DFT calculations. In aprotic solution the molecules contain intramolecular OHO hydrogen bonds, which change into intermolecular ones in solid state. The energy barriers for the amide group rotation around the CN bond were estimated from the line shape analysis of (1)H and (13)C NMR signals. A tentative correlation between the barrier height and the strength of OHO bond was proposed. Calculations of the potential energy profiles for the rotations around CC and CN bonds were done. In case of morpholine derivative experimental indications of additional dynamics: chair-chair 'ring flip' in combination with the twisting around CC bond were obtained and confirmed by quantum chemistry calculations.

Oxidation of hydrocarbons on the surface of tin dioxide chemical sensors.

The paper presents the results of our investigation on the effect of the molecular structure of organic vapors on the characteristics of resistive chemical gas sensors. The sensors were based on tin dioxide and prepared by means of thick film technology. The electrical and catalytic examinations showed that the abstraction of two hydrogen atoms from the organic molecule and formation of a water in result of reaction with a chemisorbed oxygen ion, determine the rate of oxidation reactions, and thus the sensor performance. The rate of the process depends on the order of carbon atoms and Lewis acidity of the molecule. Therefore, any modification of the surface centers of a sensor material, modifies not only the sensor sensitivity, but also its selectivity.

Use of fly ash agglomerates for removal of arsenic.

The aim of this work is to investigate the application of fly ash adsorbent for removal of arsenite ions from dilute solution (100-1,000 ppm). Experiments were carried out using material from the "Turów" (Poland) brown-coal-burning power plant, which was wetted, then mixed and tumbled in a granulator to form spherical agglomerates. Measurements of arsenic adsorption from aqueous solution were carried out at room temperature and natural pH of fly ash agglomerates, in either a shaken flask or circulating column, to compare two different methods of contacting solution with adsorbent. Adsorption isotherms of arsenic were determined for agglomerated material using the Freundlich equation. Kinetic studies indicated that sorption follows a pseudo-second-order model. Preferable method to carry out the process is continuous circulation of arsenite solution through a column.