Synthesis, Characterization, and Fabrication of Nickel Metal-Organic Framework-Incorporated Polymer Electrolyte Membranes for Fuel-Cell Applications.

Proton-conducting sulfonated polymer metal-organic framework (MOF)-based composite membranes were synthesized by anchoring the nickel MOF (Ni-MOF) to the aromatic sulfonated polymer backbone. In this work, we sulfonated two different polymers, poly(1,4-phenylene ether ether sulfone) (PEES) and poly ether ether ketone (PEEK), with a controllable sulfonation degree, and the synthesized Ni-MOF was incorporated into the sulfonated polymers to prepare a polymer electrolyte membrane. The effect of an MOF as a pendant moiety on the polymer backbone had a significant effect on properties such as water uptake, thermal, mechanical, and oxidative stabilities, swelling ratio, ion-exchange capacity (IEC), morphology, proton conductivity, and fuel-cell performance. The presence of an MOF structure enhanced the water retention capacity of the composite membranes. Adding Ni-MOF to the composite membrane improved the fuel-cell performance by increasing the OCV and power density. Among the synthesized electrolytes, the 3 wt % Ni-MOF-incorporated sPEEK membrane displayed a power density of 319 mW/cm2 with a cell voltage of 0.79 V, which was higher than the pure sulfonated polymer. Thus, the developed composite membranes are suitable for fuel-cell applications.

Sulfonated polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene/sulfonated poly(ether sulfone) and hexagonal boron nitride electrolyte membrane for fuel cell applications.

Novel proton exchange membranes consisting of sulfonated polystyrene ethylene butylene polystyrene (sPSEBPS), sulfonated poly ether sulfone (SPES) and hexagonal boron nitride (hBN) were fabricated using a facile solution casting technique. The PSEBPS polymer was functionalized using chlorosulfonic acid as the sulfonating agent. Polymerization was typically conducted by taking three different monomers, namely 3,6-dihydroxy naphthalene-2,7-disulfonic acid disodium salt, 4,4'-dichlorodiphenyl sulfone, and bisphenol-A, to yield sulfonated poly ether sulfone (SPES). The resultant SPES polymer was blended with sPSEBPS followed by incorporation with an appropriate quantity of hBN. The physicochemical and structural properties of the membranes were studied in order to evaluate their compatibility with fuel cell applications. X-Ray photoelectron spectroscopy data validated the successful incorporation of the filler into the polymer matrix. Water absorption of the membranes was found in the range between 19.5 and 29.8%. The membrane loaded with 4.0 wt% of hBN showed the maximum ion-exchange capacity of 1.21 meq g-1, whereas the control sPSEBPS/SPES membrane was restricted to 0.48 meq g-1. The composite membrane loaded with hBN displayed higher thermal stability than that of the control sample. The sPSEBPS/SPES/hBN-4 composite membrane exhibited an ionic conductivity of 0.0329 S cm-1 at 30 °C. Overall, the experimental data of the prepared composite membranes revealed that the materials are potential candidates for fuel cells.