Oxidized sodium alginate/polyacrylamide hydrogels adhesive for promoting wheat growth.

Chemical modification of sodium alginate (SA) polymer chains can increase its functional group species. Sodium periodate (SP) was usually used to oxidize the hydroxyl groups on the chain of SA to aldehyde groups, the preparation of oxidized sodium alginate (OSA) using SP is not only complicated, also limits the variety of functional groups on the chain of OSA. By contrast, we have developed an innovative strategy for OSA, in which ammonium persulfate (APS) was used to oxidize SA, providing a clear elucidation of the oxidizing process and mechanism. OSA/PAM hydrogels were synthesized using OSA, the hydrogels possess excellent adhesion properties to various non-metallic and metallic substrates. Tensile and compression tests show that the cross-linked OSA/PAM hydrogels have superior mechanical properties. We exploit OSA/PAM hydrogels as soil adhesive and water-retaining agents for wheat growth. OSA/PAM hydrogels significantly improve the survival time of wheat grown in brown loam soil under a water-shortage environment, and slow down the wilting of wheat in a water-shortage environment and prolong the survival time of wheat in sandy soils. Our trials should make hydrogels important for wheat cultivation in brown loam soils and the development of desert areas.

Bionic ordered structured hydrogels: structure types, design strategies, optimization mechanism of mechanical properties and applications.

Natural organisms, such as lobsters, lotus, and humans, exhibit exceptional mechanical properties due to their ordered structures. However, traditional hydrogels have limitations in their mechanical and physical properties due to their disordered molecular structures when compared with natural organisms. Therefore, inspired by nature and the properties of hydrogels similar to those of biological soft tissues, researchers are increasingly focusing on how to investigate bionic ordered structured hydrogels and render them as bioengineering soft materials with unique mechanical properties. In this paper, we systematically introduce the various structure types, design strategies, and optimization mechanisms used to enhance the strength, toughness, and anti-fatigue properties of bionic ordered structured hydrogels in recent years. We further review the potential applications of bionic ordered structured hydrogels in various fields, including sensors, bioremediation materials, actuators, and impact-resistant materials. Finally, we summarize the challenges and future development prospects of bionic ordered structured hydrogels in preparation and applications.