ZnO/CuSe composite-mediated bandgap modulation for enhanced photocatalytic performance against methyl blue dye.

The removal of toxic dye pigments from the environment is of utmost importance since even trace amounts of these pollutants can lead to harmful impacts on ecosystems. Heterogeneous photocatalysis is a potential technique for eliminating microbiological, inorganic, and organic pollutants from wastewater. Here, we report the band gap alteration of ZnO by making its composites with CuSe to enhance photocatalytic activity. The purpose is to develop metal oxide nanocomposites (ZnO/CuSe) as an effective and efficient material for the photodegradation of methyl blue. The photocatalysts, ZnO nanorods, CuSe, and ZnO/CuSe nanocomposites of different weight ratios were synthesized by the simple and cost-effective technique of precipitation. UV-Vis spectra verified that the ZnO/CuSe photocatalyst improved absorption in the visible region. The optical bandgap of ZnO/CuSe nanocomposites reduced from 3.37 to 2.68 eV when CuSe concentration increased from 10 to 50%. ZnO/CuSe composites demonstrated better photocatalytic activity than ZnO when exposed to UV-visible light. The pure ZnO nanorods could absorb UV light and the nanocomposites could absorb visible light only; this was attributed to the transfer of excited high-energy electrons from ZnO to CuSe.

Geochemical and remote sensing integrated with satellite gravity data of Darhib and Atshan talc deposits, South Eastern Desert, Egypt.

The current contribution conducted new geochemical, remote sensing integrated with gravity detailed studies of talc deposits to identify the talc protolith as well as its extension, depth, and structures. There are two examined areas, distributed from north to south, Atshan and Darhib and both belong to the southern sector of the Egyptian Eastern Desert. They occur as individual lenses or pocket bodies in ultramafic-metavolcanics following NNW-SSE and E-W shear zones. Geochemically, among the investigated talc, Atshan samples have high contents of SiO2 (av. 60.73 wt.%), and higher concentrations of transition elements such as Co (av. 53.92 ppm), Cr (781 ppm), Ni (av. 1303.6 ppm), V (av. 16.67 ppm), and Zn (av. 55.7 ppm). Notably, the examined talc deposits contain low contents of CaO (av. 0.32 wt.%), TiO2 (av. 0.04 wt.%), SiO2/MgO (av. 2.15), and Al2O3 (av. 0.72 wt.%), which is comparable with ophiolitic peridotite and forearc setting. False color composite (FCC), principal component analysis (PCA), minimum noise fraction (MNF), and band ratio (BR) have been used to distinguish talc deposits in the investigated areas. Two new proposed band ratios were created to separate talc deposits. FCC band ratios (2/4, 4/7, 6/5) and (4 + 3/5, 5/7, 2 + 1/3) have been derived to focus on talc deposits in two case studies, Atshan and Darhib areas. The application of regional, residual, horizontal gradient (HG), and analytical signal (AS) techniques to gravity data are used in interpreting the structural directions of the study area. The analysis of this technique displays several notable faults trending in NW-SE, NE-SW, NNW-SSE, and E-W directions. Two techniques of gravity depth calculation were applied in the study areas, namely source parameter image (SPI), and Euler deconvolution (EU). The analysis of these techniques reflects that the depth of subsurface sources ranges between 383 and 3560 m. Talc deposits may be attributed to greenschist facies metamorphism or to a magmatic solution that is (associated with granitic intrusions) interacted with the surrounding volcanic rocks forming metasomatic minerals.

The impact of Cu-polluted and organic soil on the fibrous plant; insights into plant growth promotion, antioxidant defences system, and oxidative stress.

Copper (Cu) is an abundant essential micronutrient element in various rocks and minerals and is required for a variety of metabolic processes in both prokaryotes and eukaryotes. However, excess Cu can disturb normal development by adversely affecting biochemical reactions and physiological processes in plants. However, organic soil is rich in micronutrients and can assist plants to tolerate toxicity by promoting growth and biomass. This study explored the potential of organic and Cu-contaminated soil on fibrous jute (Corchorus capsularis ). Plants were grown in the organic soil, natural soil (normal soil) and Cu-contaminated soil for 60days, and we studied different growth, physiological and ultra-structure alterations in the plant. Results showed that the addition of organic acid in the soil showed a remarkable increase in seed germination, plant height, fresh biomass, photosynthetic pigment and gas exchange parameters, and decreased the malondialdehyde (MDA) concentration in the tissues when compared to the plants grown in the natural soil. In contrast, plants grown in the Cu-contaminated soil significantly (P <0.05) decreased the seed germination, plant height, fresh biomass, photosynthetic pigment and gas exchange parameters, and increased MDA content, proline concentration and the activities of various antioxidant compounds; i.e. peroxidase (POD) and superoxidase dismutase (SOD). In addition, Cu toxicity also destroyed many membrane bounded organelles especially the chloroplast, which was revealed from transmission electron microscopy (TEM). We concluded that Cu toxicity affected growth and physiological attributes in C. capsularis , while addition of organic soil increased plant growth and biomass.

Digenic inheritance of IL-36RA and SEC61A1 mutations underlies generalized pustular psoriasis with hypogammaglobulinemia.

We report a female patient presenting with generalized pustular psoriasis and hypogammaglobulinemia due to digenic mutations in IL-36RA and SEC61A1. The patient presented with recurrent fevers, elevated inflammatory markers, hepatosplenomegaly, and recurrent sinopulmonary infections in the context of hypogammaglobulinemia which improved on immunoglobulin replacement. This report demonstrates how digenic inheritance leads to complex phenotypes, and illustrates the importance of following an unbiased approach to identifying variants, especially in patients with atypical clinical presentations.

Influence of tomato waste compost ratios on plant growth and fruit quality of cucumber and summer squash.

Peat-moss (Sphagnum spp.), is currently an expensive material and a nonrenewable resource with variable properties. Therefore, its use should be gradually reduced. Hence, there are numerous attempts aiming to reduce the use of peat-moss as a bulk substrate and to search for high-quality, locally available and low-cost alternatives to peat-moss. Therefore, the main objective of this research is to investigate the effect of partial replacing of peat-moss with tomato waste compost (TWC) on plant growth, productivity, fruit quality, and morphological features of two types of economic cucurbits species under greenhouse conditions. The plants were planted into pots containing different proportions of TWC (0%, 5%, 10%, 15%, 20% and 30%) with peat-moss, sand and clay as growing substrates. The results indicated that the plant height and the leaves number of both plants were significantly influenced by different substrate treatments. TWC ratios of 15% and 20% increased the amount of cucumber and summer squash fruit yield more than the commercial peat media but they had insignificant differences. Also, they were significantly improved fruit quality characteristics, particularly total soluble solid (TSS) and titratable acidity (TA) of crop fruits more than commercial peat-moss treatment.Implications: Because of the high price of peat-moss and that it is a non-renewable material, farmers resorted to using other alternatives, including green residue compost. Thus, the aim of this work is to reduce the use of peat-moss by replacing it with the use of lokw percentages of TWC. When tomato plant residues return to the soil by converting them into compost, this is a valuable agricultural practice to improve soil fertility and increase the organic matter of the soil as well as increase the source of nitrogen (N) that supports the growth of beneficial microorganisms.

Maturity and stability assessment of composted tomato residues and chicken manure using a rotary drum bioreactor.

The efficiency of the composting process for tomato residues and chicken manure was estimated after monitoring of the rotary composting system. Physicochemical parameters and Compost Quality Index were evaluated. The tomato residues (leaves, stems, and some green and damaged fruits) were collected, cut into small pieces, moistened approximately (60-65%), and mixed with 20% chicken manure then distributed into three rotary drum bioreactors. The obtained results showed that, the temperature above 50°C was maintained for more than two days. Carbon: nitrogen (C:N) ratio was reduced from 30:1 to 19.13:1. The pH value ranged between 7 and 8.80 during the composting process, while the electrical conductivity (EC) ranged between 2.67 to 4.53 dS/m. Both compost quality parameters (Dewar and germination index) and (Solvita-CO2 and Solvita-NH3) indicated that, the final compost is stable and mature.Implications: The idea of this research revolves around assessing the maturity and stability of the compost resulting from mixing tomato residues with chicken manure, using a rotary drum bioreactor which is characterized by reducing the time of the active phase to several hours or days instead of weeks or months. Several tests related to the maturity and stability of mixture have been used to judge its quality. Also, many parameters related to this topic were monitored and discussed with many previous researches to determine the importance of benefiting from mixing the different wastes together and obtaining a good fertilizer ready for application as an agricultural substrate or a soil conditioner.