RESUMO
This paper reports chemiresistive multiarray gas sensors through the synthesized ternary nanocomposites, using a one-pot method to integrate two-dimensional MXene (Ti3C2Tx) with Ti-doped WO3 (Ti-WO3/Ti3C2Tx) and Ti3C2Tx with Pd-doped SnO2 (Pd-SnO2/Ti3C2Tx). The gas sensors based on Ti-WO3/Ti3C2Tx and Pd-SnO2/Ti3C2Tx exhibit exceptional sensitivity, particularly in detecting 70% at 1 ppm acetone and 91.1% at 1 ppm of H2S. Notably, our sensors demonstrate a remarkable sensing performance in the low-ppb range for acetone and H2S. Specifically, the Ti-WO3/Ti3C2Tx sensor demonstrates a detection limit of 0.035 ppb for acetone, and the Pd-SnO2/Ti3C2Tx sensor shows 0.116 ppb for H2S. Simultaneous measurements with Ti-WO3/Ti3C2Tx- and Pd-SnO2/Ti3C2Tx-based sensors enable the evaluation of both the concentration and type of unknown target gases, such as acetone or H2S. Furthermore, density functional theory calculations are performed to clarify the role of Ti and Pd doping in enhancing the performance of Ti-WO3/Ti3C2Tx and Pd-SnO2/Ti3C2Tx nanocomposites. Theoretical simulations contribute to a deeper understanding of the doping effects, providing essential insights into the mechanisms underlying the enhanced gas response of the gas sensors. Overall, this work provides valuable insights into the gas-sensing mechanisms and introduces a novel approach for high-performance multiarray gas sensing.
RESUMO
The rising importance of gas detection has prompted rigorous research on flexible and transparent high-performance gas sensors. We demonstrated a sensor for NO2 detection at room temperature, in which our device was fabricated via screen printing on a flexible substrate, and MoS2 and single-walled carbon nanotube (SWCNT) were coated on a specific area by the self-assembly method. This fabrication process is rapid, facile, and cost-effective. The proposed sensor enables precise and stable NO2 gas sensing from 50 ppb to 100 ppm. This method should also be applicable to the selective detection of other gases.