Tunability of silicon clathrate film properties by controlled guest-occupation of their cages.

Type I and type II silicon clathrates are guest-host structures made of silicon polyhedral cages large enough to contain atoms that can be either inserted or evacuated with only a slight volume change of the structure. This feature is of interest not only for batteries or storage applications but also for tuning the properties of the silicon clathrate films. The thermal decomposition process can be tuned to obtain Na8Si46 and Na2

Shallow implanted SiC spin qubits used for sensing an internal spin bath and external YIG spins.

Silicon vacancy (VSi) color centers in bulk SiC are excellent electron spin qubits. However, most spin based quantum devices require shallow spin qubits, whose dynamics is often different from that of bulk ones. Here, we demonstrate (i) a new method for creating shallow VSi (V2) spin qubits below the SiC surface by low energy ion implantation through a sacrificial SiO2 layer, (ii) that these shallow VSi are dipolar coupled to an electronic spin bath, analysed by Hahn echo decay, dynamical decoupling (DD), and optically pumped pulsed electron-electron double resonance experiments (OP-PELDOR), (iii) that their coherence time increases with cooling of the spin bath (from 55 µs at 297 K to 107 µs at 28 K), and that it can be further extended to 220 µs at 100 K by DD, thus demonstrating their relevance for PELDOR-based quantum sensors and processors. Finally, (iv) external spin sensing is demonstrated by the shift of VSi magnetic resonance lines induced by the dipolar stray magnetic field of a nearby ferrimagnetic YIG film.

Large-mode-area optical fiber for photonic nanojet generation.

The photonic nanojet (PNJ) generated by a shaped optical fiber tip is an attractive technology for laser micro-machining. The working distance has the same order of size as the fiber core diameter; therefore, multimode (MM) fibers are generally preferred. However, the PNJ is due to the fundamental mode and, therefore, the energy coupled on the high-order modes does not contribute to the process. We demonstrate the benefit of a large-mode-area (LMA) optical fiber in the generation of the PNJ. A homemade 40 µm mode field diameter LMA fiber is compared with a 100/140 MM-shaped fiber tip. Similar micro-peaks are obtained, and an energy gain is demonstrated. The coupled energy required was eight times less intense with the LMA fiber, which may open new possibilities for laser micro- and nano-processing.