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1.
Geochem Trans ; 25(1): 2, 2024 Mar 02.
Artigo em Inglês | MEDLINE | ID: mdl-38429600

RESUMO

This study delves into the geochemical dispersion of gold-bearing quartz veins in the Wadi Abu Khusheiba area, southern Jordan, with a focus on uncovering the complex patterns of mineralization and their geological significance. Employing an in-depth geochemical analysis of 24 rock samples from the region, we identified that these samples are predominantly hosted by oversaturated rhyolitic rocks, characterized by high SiO2 content and abundant free Quartz and orthoclase minerals. The mineralized zone of the quartz veins is particularly notable for its gold and silver concentrations, with maximum values reaching up to 5 ppm for gold and 18 ppm for silver. Our investigation into the elemental correlations revealed nuanced relationships, dependent on the 21 sample and analyzed at confidence level of (85%). Contrary to initial assumptions, we did not find a significant positive correlation between gold (Au) and arsenic (As), nor significant negative correlations between gold and other trace elements. These insights are critical for understanding the geochemical behavior of gold in the area and offer a nuanced view of elemental associations. The results of this study are significant for both academic research and practical exploration. They enhance our comprehension of the geological history and mineralization processes in Wadi Abu Khusheiba, providing valuable data that can inform future exploration strategies and deepen our understanding of mineral deposition in similar geological settings. This research not only contributes to the scientific community's knowledge of the area's geochemistry but also has potential implications for the mining and exploration industries.

2.
Environ Res ; 214(Pt 1): 113757, 2022 11.
Artigo em Inglês | MEDLINE | ID: mdl-35753380

RESUMO

The study of metals mobility derived from mining activities in an ultramafic lithology is limited. This study investigates the effects of distance on potentially toxic metals such as Co, Cu, Fe, Mn, Ni, Pb, and Zn pollution, and the geochemical processes of fluvial system downstream of an ex-copper mine (Mamut River). The toxicity level of the river was evaluated using various sediment quality guidelines, ecotoxicological risks (ecological risk and risk index) and pollution indices. The geochemical behavior and stability of these toxic metals in the solid-phase samples were also examined. The results show that elevated concentrations of Ni, Cu, and Fe in the sediments can be linked to the adsorption and precipitation of metals from the aqueous-phase samples. We found that the metal scavenging rate as a function of distance is more evident in tropical environments than it was previously thought (10 km downstream). Such an inference could be explained by the greater amount of rainfall (pH 5.5-6.5) received in the tropics and higher weathering products that could react and form stable complexes. Geochemical analysis of the river sediment indicates that Ni, Cu, and Fe in the river sediment have increased 44-, 81-, and 90-fold compared to the background values, respectively. A significant decrease in the concentration of the potentially toxic metals was found at 5.5 km downstream. The scavenging rate of Fe is the highest (1485.82 µg g-1 km-1) followed by Cu (141.48 µg g-1 km-1), Ni (10.23 µg g-1 km-1), Pb (8.12 µg g-1 km-1) and Zn (5.01 µg g-1 km-1) in the tropical river system. In contrast, the concentration of Co and Mn in the river sediments doubled as the river flows approximately 5 km downstream due to the higher mineral solubility and weaker metal partition coefficient. This study also discusses the possibility of asbestos (mainly as chrysotile in the X-ray diffraction) as a potential hidden risk present within the ultramafic setting. This case study can be extrapolated to explain the dispersion of inorganic pollutants in an ultramafic environment in a global context.


Assuntos
Metais Pesados , Poluentes Químicos da Água , China , Monitoramento Ambiental , Sedimentos Geológicos , Chumbo , Medição de Risco , Rios
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