CoFe2O4/PANI/MWCNTs ternary hybrid composites. Synthesis, characterization, the effect of MWCNTs ratio and dye removal capability.

We have synthesized cobalt ferrite (CoFe2O4) using the sucrose auto-combustion method and subsequently employed the in situ polymerization technique to fabricate ternary composites comprising CoFe2O4, polyaniline (PANI), and multi-walled carbon nanotubes (MWCNTs). In this novel investigation, we explored the influence of varying MWCNTs ratios on these composites' structural, magnetic, thermal, and electrical properties. The crystal structures of the synthesized composites were analyzed using X-ray diffraction (XRD), while Fourier transform infrared (FT-IR) spectroscopy revealed changes in bonding patterns, including the disappearance of ferrite bonds and the emergence of new ones. Transmission electron microscopy (TEM) images illustrated a complete coating of PANI on both MWCNTs and CoFe2O4 particles, resulting in a substantial reduction in magnetization compared to pure CoFe2O4 ferrite due to PANI's nonmagnetic nature. Vibrating sample magnetometer (VSM) measurements confirmed this reduction, indicating a decrease to 7.3 emu.g-1. Thermal analysis demonstrated an enhancement in thermal stability with increasing MWCNTs content, as evidenced by an increase in the temperature equivalent for half decomposition (T50) from 486 to 522 °C for composites with 40% MWCNTs. Moreover, the electrical conductivity showed a corresponding rise with MWCNTs content, increasing from 3.1 × 10-3 Ω-1.cm-1 to 2.2 × 10-2 Ω-1.cm-1, possibly indicating charge transfer from PANI to MWCNTs. To assess practical applications, we investigated the ability of the composite with 40% MWCNTs to remove phenol red (PR) dye from aqueous solutions. Through a systematic study of adsorption parameters and kinetics, we determined optimal conditions for effective dye removal and elucidated the underlying adsorption mechanism. Our results demonstrated the composite's efficiency in dye removal, with a 6.4 mg·g-1 capacity for PR dye, highlighting its potential for environmental remediation efforts.

Green synthesis of lead oxide nanoparticles for photo-electrocatalytic and antimicrobial applications.

Synthesis of nanoparticles (NPs) for many different uses requires the development of environmentally friendly synthesis protocols. In this article, we present a simple and environmentally friendly method to synthesize lead oxide (PbO) NPs from the plant material of the Mangifera indica. Analytical techniques such as spectroscopy, X-ray diffraction, and microscopy were used to characterize the synthesized PbO NPs, and their photo-electrocatalytic and antifungal properties were also evaluated. H2O2 was used to investigate the efficacy of removing methylene blue dye. At a range of pH values, H2O2 was used to study the role of hydroxyl radicals in the breakdown of methylene blue dye. Methylene blue dyes are more easily eliminated due to increased generation of the *OH radical during removal. Dye degradation was also significantly affected by the aqueous medium's pH. Additionally, the electrocatalytic properties of the PbO NPs adapted electrode were studied in CH3COONa aqueous solution using cyclic voltammetry. Excellent electrocatalytic properties of the PbO NPs are shown by the unity of the anodic and cathodic peaks of the modified electrode in comparison to the stranded electrode. Aspergillus flavus, Aspergillus niger, and Candida glabrata were some fungi tested with the PbO NPs. Against A. flavus (40%) and A. niger (50%), and C. glabrata (75%), the PbO NPs display an excellent inhibition zone. Finally, PbO NPs were used in antioxidant studies with the powerful antioxidant 2, 2 diphenyl-1-picrylhydrazyl (DPPH). This study presents a simple and environmentally friendly method for synthesizing PbO NPs with multiple uses, including photo-electrocatalytic and antimicrobial activity.

Active and durable R2MnRuO7 pyrochlores with low Ru content for acidic oxygen evolution.

The production of green hydrogen in water electrolyzers is limited by the oxygen evolution reaction (OER). State-of-the-art electrocatalysts are based on Ir. Ru electrocatalysts are a suitable alternative provided their performance is improved. Here we show that low-Ru-content pyrochlores (R2MnRuO7, R = Y, Tb and Dy) display high activity and durability for the OER in acidic media. Y2MnRuO7 is the most stable catalyst, displaying 1.5 V at 10 mA cm-2 for 40 h, or 5000 cycles up to 1.7 V. Computational and experimental results show that the high performance is owed to Ru sites embedded in RuMnOx surface layers. A water electrolyser with Y2MnRuO7 (with only 0.2 mgRu cm-2) reaches 1 A cm-2 at 1.75 V, remaining stable at 200 mA cm-2 for more than 24 h. These results encourage further investigation on Ru catalysts in which a partial replacement of Ru by inexpensive cations can enhance the OER performance.

Desalination technologies, membrane distillation, and electrospinning, an overview.

Water is a critical component for humans to survive, especially in arid lands or areas where fresh water is scarce. Hence, desalination is an excellent way to effectuate the increasing water demand. Membrane distillation (MD) technology entails a membrane-based non-isothermal prominent process used in various applications, for instance, water treatment and desalination. It is operable at low temperature and pressure, from which the heat demand for the process can be sustainably sourced from renewable solar energy and waste heat. In MD, the water vapors are gone through the membrane's pores and condense at permeate side, rejecting dissolved salts and non-volatile substances. However, the efficacy of water and biofouling are the main challenges for MD due to the lack of appropriate and versatile membrane. Numerous researchers have explored different membrane composites to overcome the above-said issue, and attempt to develop efficient, elegant, and biofouling-resistant novel membranes for MD. This review article addresses the 21st-century water crises, desalination technologies, principles of MD, the different properties of membrane composites alongside compositions and modules of membranes. The desired membrane characteristics, MD configurations, role of electrospinning in MD, characteristics and modifications of membranes used for MD are also highlighted in this review.

Highly active and stable OER electrocatalysts derived from Sr2MIrO6 for proton exchange membrane water electrolyzers.

Proton exchange membrane water electrolysis is a promising technology to produce green hydrogen from renewables, as it can efficiently achieve high current densities. Lowering iridium amount in oxygen evolution reaction electrocatalysts is critical for achieving cost-effective production of green hydrogen. In this work, we develop catalysts from Ir double perovskites. Sr2CaIrO6 achieves 10 mA cm-2 at only 1.48 V. The surface of the perovskite reconstructs when immersed in an acidic electrolyte and during the first catalytic cycles, resulting in a stable surface conformed by short-range order edge-sharing IrO6 octahedra arranged in an open structure responsible for the high performance. A proton exchange membrane water electrolysis cell is developed with Sr2CaIrO6 as anode and low Ir loading (0.4 mgIr cm-2). The cell achieves 2.40 V at 6 A cm-2 (overload) and no loss in performance at a constant 2 A cm-2 (nominal load). Thus, reducing Ir use without compromising efficiency and lifetime.

Photocatalytic response in water pollutants with addition of biomedical and anti-leishmanial study of iron oxide nanoparticles.

Public health is a major concern globally, owing to the presence of industrial dyes in the effluent. Nanoparticles with green synthesis are an enthralling research field with various applications. This study deals with investigating the photocatalytic potential of Fe-oxide nanoparticles (FeO-NPs) for the degradation of methylene blue dye and their potential biomedical investigations. Biosynthesis using Anthemis tomentosa flower extract showed to be an effective method for the synthesis of FeO-NPs. The freshly prepared FeO-NPs were characterized through UV/Vis spectroscopy showing clear peak at 318 nm. The prepared FeO-NPs were of smaller size and spherical shape having large surface area and porosity with no aggregations. The FeO-NPs were characterized using XRD, FTIR, HRTEM, SEM and EDX. The HRTEM results showed that the particle size of FeO-NPs was 60-90 nm. The antimicrobial properties of FeO-NPs were investigated against two bacterial Staphylococcus aureus 13 (±0.8) and Klebsiella pneumoniae 6(±0.6) and three fungal species Aspergillus Niger, Aspergillus flavus, and Aspergillus fumigatus exhibiting a maximum reduction of 57% 47% and 50%, respectively. Moreover, FeO-NPs exhibited high antioxidant properties evaluated against ascorbic acid. Overall, this study showed high photocatalytic, antimicrobial, and antioxidant properties of FeO-NPs owing to their small size and large surface area. However, the ecotoxicity study of methylene blue degradation products showed potential toxicity to aquatic organisms.

Synthesis of zeolite/geopolymer composite for enhanced sequestration of phosphate (PO43-) and ammonium (NH4+) ions; equilibrium properties and realistic study.

Zeolite impeded geopolymer (Z/G) was synthesized from natural kaolinite and diatomite. The structure (Z/G) was characterized as an enhanced adsorbent for PO43- and NH4+ ions from aqueous solutions, groundwater, and sewage water. The synthetic Z/G structure exhibits sequestration capacities of 206 mg/g and 140 mg/g for PO43- and NH4+, respectively which are higher values than the recognized results for the geopolymer and other adsorbents in literature. The sequestration reactions of PO43- and NH4+ by Z/G are of Pseudo-Second order kinetic behavior considering both the Chi-squared (χ2) and correlation coefficient (R2) values. The sequestration reactions occur in homogenous and monolayer forms considering their agreement with Langmuir behavior. The Gaussian energies (12.4 kJ/mol (PO43-) and 10.47 kJ/mol (NH4+)) demonstrate the operation of a chemical sequestration mechanism that might be involved zeolitic ion exchange process and chemical complexation. Additionally, these reactions are exothermic processes of spontaneous and favorable properties based on thermodynamic studies. The Z/G structure is of significant affinity for both PO43- and NH4+ even in the existence of other anions as Cl-, HCO3-, SO42-, and NO3-. Finally, the structure used effectively in the purification of groundwater and sewage water from PO43- and NH4+ in addition to nitrate, sulfate, and some metal ions.

Insight into the role of the zeolitization process in enhancing the adsorption performance of kaolinite/diatomite geopolymer for effective retention of Sr (II) ions; batch and column studies.

Diatomite/kaolinite-based geopolymer (GP) was synthesized and incorporated in zeolitization process (Z/GP) to investigate the role of the zeolite phases in inducing its retention capacity of the dissolved Sr (II) ions in water. The retention of Sr (II) ions using Z/GP in comparison with GP was evaluated based on both batch and fixed-bed column studies. In the batch study, the zeolitized geopolymer (Z/GP) shows enhancement in the Sr (II) retention capacity (193.7 mg/g) as compared to the normal geopolymer (102 mg/g). Moreover, the recyclability studies demonstrate higher stability for Z/GP than GP with a retention percentage higher than 90% for five reusing runs. The kinetic and the equilibrium properties of the occurred Sr (II) retention reactions follow the assumption of the Pseudo-Second order model (R2 > 0.96) and Langmuir model (R2 > 0.97), respectively. The Gaussian energies (15.4 kJ/mol (GP) and 11.47 kJ/mol (Z/GP)) related to retention mechanism of chemical type and within the suggested range for the zeolitic ion exchange processes. The Sr (II) retention reactions by GP and Z/GP are of spontaneous and exothermic properties which qualifies the products to be used at low-temperature conditions (20 °C). The column studies also declared higher performance for the Z/GP fixed bed as compared to the normal GP bed considering the total Sr (II) retention percentage (72.9%), treated volume (8 L), saturation time (1620 min), and a maximum capacity of Z/GP particles in the bed (567.6 mg/g).

Effective decontamination of Ca2+ and Mg2+ hardness from groundwater using innovative muscovite based sodalite in batch and fixed-bed column studies; dynamic and equilibrium studies.

A novel form of sodalite was synthesized from muscovite (M.SD) as low-cost softening material for both Ca2+ and Mg2+ ions from real groundwater in batch and column studies. The sodalite sample showed significant surface area (105 m2/g) and ion exchange capacity (87.3 meq/100 g) which qualifies it strong for softening applications. The incorporation of the M.SD as a fixed bed in column system at a fixed thickness of 4 cm and flow rates of 5 mL/min resulted in removal percentages of 90.5% and 92.2% for Ca2+ and Mg2+, respectively at pH 7.6. Considering the real concentrations of the ions (Ca2+ (233 mg/L) and Mg2+ (114 mg/L)), the M.SD bed has the ability to reduce their concentrations according to the recommended limits (75 mg/L for Ca2+ and 50 mg/L for Mg2+). These conditions resulted in purification of about 8.1 L and 8.7 L with breakthrough intervals of 1380 min and 1440 min; and saturation interval more than 1620 min for Ca2+ and Mg2+, respectively. The M.SD columns' performances were described considering the assumption of the Thomas model, Adams-Bohart model, and Yoon-Nelson model. The batch studies demonstrate the uptake of both Ca2+ and Mg2+ ions according to the Pseudo-First order kinetics and Langmuir equilibrium behaviour. Considering the values of Gaussian energies (0.77 KJ/mol (Ca2+) and 1.36 KJ/mol (Mg2+)), the uptake of these ions occurred by homogenous reactions of monolayer form and physical nature. The thermodynamic studies declared the spontaneous properties of the reactions and their exothermic properties.

Biomedical response under visible-light irradiation promoted by new hydrothermally synthesized SiO2-Zn@Fe2O3 nanofibers.

In the presence of Fe3O4 nano-fibers, we prepared SiO2-Zn@Fe2O3 hybrid Nano-fibers through a novel and simple one-pot redox reaction between ZnSO4 & SiO2. The Fe3O4 exterior nano-fibers would be homogenously covered by SiO2 coating to arrange a distinctive core-shell construction and then Zn nanoparticles are intercalated in the covering of SiO2. The synthesized nanofibers were tested for photodegradation of methylene blue (MB). The result showed that 99 % MB was degraded in 60 min. Furthermore, the antibacterial potential of SiO2-Zn@Fe2O3 nanofibers was tested against E. coli and S. aureus bacteria both in light and dark. The impact of different analysis such as Reactive oxygen species (ROS) analysis, irradiation effect on bacterial inhibition, concentration effect of SiO2-Zn@Fe2O3 nanofibers and reduction of DPPH studied. The findings clearly demonstrate that ROS is produced in the presence of SiO2-Zn@Fe2O3 nanofibers in bacterial cells and is responsible for their inhibition. Findings have shown that synthesized nanostructures can also increase the stability of DPPH radicals with increasing concentrations of nanomaterials, making them a strong candidate for DPPH reduction. The overall results show that the efficacy of SiO2-Zn@Fe2O3 nanofibers for inhibition was more pronounced than that of individual iron oxides.

Self-decoration of N-doped graphene oxide 3-D hydrogel onto magnetic shrimp shell biochar for enhanced removal of hexavalent chromium.

In this work, a novel decorated and combined N-doped graphene oxide hydrogel with shrimp shell magnetic biochar (NGO3DH-MSSB) biosorbent was fabricated as an effective material for Cr(VI) removal. Three-dimensional self-assembled graphene oxide hydrogel was synthesized using nitrogen source, ethylenediamine (EDA). Characterizations of NGO3DH-MSSB biosorbent were established by FT-IR, TGA, SEM and BET, where high surface area (398.05 m2/g) compared with that of MSSB (138.64 m2/g) was characterized. The maximum achieved swelling ratio (800%) was only after 300 min. The binding mechanisms between Cr(VI) ions and NGO3DH-MSSB biosorbent were controlled by electrostatic adsorption (ion-pair), pore filling, and reduction-coordination reaction. Adsorption was described by the pseudo-second order kinetic (R2 =0.9994, 0.9983 and 0.9992) at 10, 50 and 100 mg/L and Langmuir isotherm model (R2 =0.9997, 0.9957 and 0.9912) at 25, 40 and 50 °C. The adsorption capacity (350.42 mg/g) was achieved at pH 1.0, using initial Cr(VI) concentration (100 mg/L) and contact time (180 min) at room temperature. NGO3DH-MSSB biosorbent could be successfully reused after eight cycles. The percentage removal of Cr(VI) were confirmed as 99.79%, 99.20% and 98.00% from tap water, sea water and wastewater, respectively.

Enhancing the removal of organic and inorganic selenium ions using an exfoliated kaolinite/cellulose fibres nanocomposite.

Exfoliated kaolinite sheets/cellulose fibres nanocomposite (EXK/CF) was synthesised as a novel hybrid of materials of enhanced surface area and adsorption capacities for inorganic-selenate [Se(VI)] and selenite [Se(IV)]-and organic selenium pollutants-selenomethionine (SeMt). The adsorption reactions of the addressed selenium forms followed pseudo-first-order as a kinetic model and Langmuir as an isotherm model. The fitting results and the calculated Gaussian energies-Se (VI) at 2.0 KJ/mol, Se (IV) at 2.2 KJ/mol, and SeMt at 1.7 KJ/mol-suggested physisorption uptake in a monolayer and homogeneous form. The theoretical maximum selenium uptake capacity (qmax) for Se (VI), Se (IV), and SeMt was 137.5 mg/g, 161.4 mg/g, and 95.4 mg/g, respectively. The thermodynamic investigation verified spontaneous and exothermic properties of the selenium uptake reactions by the EXK/CF composite.

Enhanced decontamination of levofloxacin as toxic pharmaceutical residuals from water using CaO/MgO nanorods as a promising adsorbent.

Novel MgO/CaO nanocomposite (MgO/CaO NRs) was synthesized by the hydrothermal method using diatomite porous frustules as a substrate under the microwave irradiation. The composite appeared as well crystalline rod-like nanoparticles with 52.3 nm as average particle size and 112.8 m2/g as BET surface area. The synthetic MgO/CaO NRs were addressed as a novel adsorbent for promising removal of levofloxacin (LVX) as pharmaceutical residuals. The adsorption studies revealed effective uptake of levofloxacin by MgO/CaO NRs with theoretical qmax of 106.7 mg/g and the equilibrium time of 720 min considering the best pH value (pH 7). The equilibrium studies highly fitted with the Langmuir model of monolayer adsorption considering the values of Chi-squared (χ2) and determination coefficient. The estimated adsorption energy from Dubinin-Radushkevich (0.2 kJ/mol) signifies physisorption mechanisms that might be coulombic attractive forces considering the kinetic studies. The thermodynamic addressing for the reactions verified their spontaneous and exothermic nature within a temperature range from 303 to 333 K. Additionally, the prepared MgO/CaO NRs show significant recyclability properties to be used in realistic remediation process and its uptake capacity is higher than several studied adsorbents in literature.

Effective oxidation of methyl parathion pesticide in water over recycled glass based-MCM-41 decorated by green Co3O4 nanoparticles.

Pieces of glass as solid wastes were recycled in the synthesis of highly order MCM-41 that decorated by green fabricated Co3O4 nanoparticles using the green extract of green tea leaves forming novel green nano-composite. The synthetic Co3O4/MCM-41 exhibit high surface area, low bandgap energy (1.63 eV), and typical spherical morphology decorated by Co3O4 nanoparticles. The composite was evaluated as green photocatalyst in effective oxidation of methyl parathion pesticide in the presence of a visible light source. The degradation results revealed complete removal of 50 mg/L and 100 mg/L after 60 min and 90 min, respectively using 0.25 of the catalyst at pH 8. The detection of the TOC in the treated methyl parathion solution gives strong indications about the formation of organic intermediate compounds during the oxidation steps. The main detected intermediate compound are C6H5OH(NO2), C6H5OH, (CH3O)3P(S), C6H4(OH)2, C6H3(OH)3, C6H4(NH2)OP(O)(OCH3)2, (CH3O)2P(O)OH, (CH2)2C(OH)OH(CHO)OC(O), and HO2C(CH2)2C(O)CHO. The detected intermediate compounds converted into SO42-, PO43-, NO3-, and CO2 under the extensive photocatalytic of them over Co3O4/MCM-41. The oxidizing species trapping test verified the controlling of the methyl parathion degradation pathway by the hydroxyl radicals. Finally, the composite showed significant reusability properties and applied five times in the oxidation of methyl parathion with considerable degradation percentages.

Effective decontamination of As(V), Hg(II), and U(VI) toxic ions from water using novel muscovite/zeolite aluminosilicate composite: adsorption behavior and mechanism.

Muscovite/phillipsitic zeolite was introduced as a novel inorganic composite of stunning adsorption properties. The composite was investigated in the uptake reactions of Hg(II), As(V), and U(VI) as highly toxic water contaminants considering different adsorption factors. The adsorption properties of muscovite/phillipsitic zeolite are highly dependent on the pH values and the best decontamination percentages can be obtained at pH 4, pH 5, and pH 5 for Hg(II), As(V), and U(VI), respectively. The kinetic studies demonstrated adsorption equilibrium for Hg(II), As(V), and U(VI) after 360 min, 300 min, and 360 min, respectively. The equilibrium modeling suggested monolayer uptake for all the metals and represented mainly by the Langmuir model considering both the values of determination coefficient and chi-squared (χ2). The estimated maximum capacities are 117 mg/g (Hg(II)), 122.5 mg/g (As(V)), and 138.5 mg/g (U(VI)) which are higher values than several studied adsorbents. The Dubinin-Radushkevich adsorption energies of Hg(II) (19.4 kJ/mol), As(V) (25.6 kJ/mol), and U(VI) (26.47 kJ/mol) signify chemical adsorption mechanisms and close to the obtained values for the ion-exchange process. Additionally, the composite is of high reusability properties and was applied effectively for five decontamination cycles. Graphical abstract.