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J Hazard Mater ; 178(1-3): 469-82, 2010 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-20185231

RESUMO

A mathematical model describing the dry-scrubbing of gaseous hydrogen chloride (HCl) with solid hydrated lime particles (Ca(OH)(2)) was developed and experimentally verified. The model applies to cyclone systems with and without recirculation, where reaction and particle collection occurs in the same processing unit. The Modified Grain Model was selected to describe the behavior of the reaction process and it was assumed that the gas and the solid particles flow in the reactor with a plug flow. In this work, this behavior is approximated by a cascade of N CSTRs in series. Some of the model parameters were estimated by optimization taking into account the experimental results obtained. A good agreement was observed between the experimental results and those predicted by the model, where the main control resistance is the diffusion of the gaseous reactant in the layer of solid product formed.


Assuntos
Poluição do Ar/prevenção & controle , Compostos de Cálcio/química , Desenho de Equipamento , Ácido Clorídrico/química , Óxidos/química , Algoritmos , Previsões , Gases , Modelos Estatísticos , Material Particulado , Reprodutibilidade dos Testes
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