Characterization and synthesis of new adsorbents with some natural waste materials for the purification of aqueous solutions.

In this study, hexavalent chromium Removal from aqueous environments was investigated by using polyaniline composites with some natural waste materials. Batch experiments were used, and some parameters such as contact time, pH and adsorption isotherms were determined for the best composite with the highest removal efficiency. Scanning Electron Microscope (SEM), Fourier Transform Infrared (FTIR) spectroscopy, and X-ray Diffraction (XRD) were used to characterize the composites. According to the results, the polyaniline/walnut shell charcoal/PEG composite outperformed other composites and showed the highest chromium removal efficiency of 79.22%. Polyaniline/walnut shell charcoal/PEG has a larger specific surface area of 9.291 (m2/gr) which leads to an increase in its removal efficiency. For this composite, the highest removal efficiency was obtained at the pH = 2 and 30 min contact time. The maximum calculated adsorption capacity was 500 mg/g.

Removal of chromium (VI) from aqueous environments using composites of polyaniline-cherry leaves.

Composites of Polyaniline (PANI)-prune, peach, cherry, grape, fig and walnut leaves were synthesized under various conditions and were used to remove chromium (VI) from aqueous environments in discontinuous experiments. The results showed that the highest percentage of Cr (VI) removal (40.3%) belonged to the composite consisting of cherry leaves and PANI. Synthesis conditions of this composite were then studied to increase Cr (VI) removal. The results of the experiment on the various solvents are used in the synthesis of the composite of PANI-cherry leaves indicated that the best solvent (with 40.93% Crn(VI) removal) was water. The effects of polyvinyl alcohol (PVA) and polyethylene glycol (PEG) as additives on the synthesis of the composite PANI-cherry leaves were studied and it was revealed that the best-synthesized composite (with 51.64% Cr removal) was produced in presence of PVA (2 g/L), and the optimum pH and contact time were 2 and 30 min, respectively. Moreover, the adsorption process followed Langmuir and Freundlich adsorption isotherms, and the maximum Cr adsorption capacity was 33.01 mg/g. The results of the FTIR and XRD tests and SEM images for this composite were studied. The SEM images demonstrated that the addition of PVA reduced the size of the particles and made them more uniform. The XRD test indicated that the synthesized composite was amorphous, and the FTIR test confirmed the synthesis of the composite.

Investigating the hexavalent chromium removal from aqueous solution applying bee carcasses and corpses modified with Polyaniline.

There are currently heavy metals in most industrial effluents which are among the most significant environmental pollutants. Hexavalent chromium is one of the most significant heavy metals. In this research for the first time, eliminating the hexavalent chromium from the aqueous medium/aquedia applying bee carcasses and corpses modified with polyethylene was examined. Adsorption experiments were conducted discontinuously on laboratory solutions, including hexavalent chromium. The optimal adsorption conditions such as different pH factors, contact time, initial chromium concentration, and adsorbent value on the adsorption rate were examined at different levels, and adsorption isotherms were plotted. Some adsorbent properties were examined using Field Emission Scanning Electron Microscopy, XRD analysis, Fourier Transform Infrared Spectroscopy, and BET test to study the properties of the synthesized adsorbent. This study indicated that the highest percentage of removal related to polyethylene composite and bee carcasses in the presence of polyethylene glycol was 50.56% among the bee carcasses composites. The parameters effective on the adsorption process for polyethylene composite and bee carcasses and losses in the presence of polyethylene glycol suggested that the adsorption percentage increased for this composite by decreasing the pH, increasing the contact time, and increasing the adsorbent. The highest percentage of adsorption was obtained when the pH was 2, the contact time was 120 min and the adsorbent value was 8 g/L and the initial concentration of chromium was 100 ppm. The most optimal removal percentage was achieved at the pH = 2, the contact time was 30 min, and the adsorbent value was 2 g/L, and the initial chromium concentration was 100 ppm. The results of drawing adsorption isotherms also indicated that higher R2 had a better fit than Langmuir for polyethylene composite and bee carcasses in the polyethylene glycol Freundlich equation.

Removal of hexavalent chromium from water using polyaniline/ wood sawdust/ poly ethylene glycol composite: an experimental study.

Polyaniline/ Sawdust /Poly Ethylene Glycol/ (PANi/SD/PEG) composite synthesized chemically is used as an adsorbent to remove hexavalent chromium from water. Adsorption experiments have been done in batch and continuous (column) mode. Some parameter such as pH, contact time, PANi/SD/PEG dose, isotherms in batch mode and pH, column bed depth and fluid flow rate in column mode were investigated. Result shows that PANi/SD/PEG has a good performance to remove hexavalent chromium ion from aqueous media. By presence of PEG, prepared composite has been homogenized and further absorption has been occurred. The best adsorption occurs under pH 2 and optimum contact time for removal of hexavalent chromium ion in batch experiment was about 30 min. Adsorption of Cr (VI) by PANi/SD/PEG fitted well in Langmuir isotherms. Maximum adsorption of hexavalent chromium was calculated 3.2 (mg/g). In column experiments, pH and column bed depth were found to be more prominent than fluid flow rate. Though, about 22% of Cr (VI) can be recovered using 0.1 M NaOH in the batch system, the recovered Cr (VI) in column system was less than 7.9%.

Removal of chromium from aqueous solution using polyaniline--poly ethylene glycol composite.

The adsorption of chromium compounds from solutions by a composite of polyaniline/poly ethylene glycol (PANi/PEG) was investigated in this study. Experiments were conducted in batch mode under various operational conditions including agitation time, solution pH, PANi/PEG dose and initial concentration of chromium salts. Results showed that concentration of PEG at synthesizing stage has a significant effect on the capacity of produced composite for removal of chromium. Morphologically, PANi/PEG composite is closely dependent on the concentration of PEG. Maximum removal of hexavalent chromium was experienced when 2g/L of PEG was used in synthesis of PANi/PEG. Removal of hexavalent chromium by PANi/PEG composite included surface adsorption and reduction reaction. The optimum pH was 5 and the equilibrium time for hexavalent chromium removal was about 30 min. Investigation of the isothermal characteristics showed that chromium adsorption by PANi/PEG composite was in high accordance with Langmuir's isotherm.