RESUMO
The current study tries to find the impact of the integration of laccase enzyme (Lac) onto magnetized chitosan (Cs) nanoparticles composed of molybdenum disulfide (MoS2 NPs) (Fe3O4/Cs/MoS2/Lac NPs) on the removal of AFM1 in milk samples. The Fe3O4/Cs/MoS2/Lac NPs were characterized by FT-IR, XRD, BET, TEM, FESEM, EDS, PSA, and VSM analysis. The cytotoxic activity of the synthesized nanoparticles in different concentrations was evaluated using the MTT method. The results show that the synthesized nanoparticles don't have cytotoxic activity at concentrations less than 20 mg/l. The ability of the prepared nanoparticles to remove AFM1 was compared by bare laccase enzyme, MoS2, and Fe3O4/Cs/MoS2 composite, indicating that the Fe3O4/Cs/MoS2/Lac NPs the highest adsorption efficiency toward AFM1. Besides, the immobilization efficiency of laccase with a concentration range of 0.5-2.0 was investigated, indicating that the highest activity recovery of 96.8% was obtained using 2 mg/ml laccase loading capacity. The highest removal percentage of AFM1 (68.5%) in the milk samples was obtained by the Fe3O4/Cs/MoS2/Lac NPs at a contact time of 1 h. As a result, Fe3O4/MoS2/Cs/Lac NPs can potentially be utilized as an effective sorbent with high capacity and selectivity to remove AFM1 from milk samples.
Assuntos
Aflatoxina M1 , Quitosana , Dissulfetos , Lacase , Leite , Molibdênio , Nanocompostos , Quitosana/química , Lacase/metabolismo , Lacase/química , Leite/química , Molibdênio/química , Animais , Nanocompostos/química , Aflatoxina M1/química , Dissulfetos/química , Adsorção , Contaminação de Alimentos/análiseRESUMO
Four hundred and sixty-six references with 625 data reports were included in our study. The high frequency of ratio OC/EC for PM0.1 was observed in 3.92-5.93; PM1 in 1.08-3.08; PM2.5, 2.08-4.08; PM10 in 2.70-4.70 and TSP in 2.66-4.66. The rank order of areas based on the pooled concentration of OC bound to PM2.5 was traffic (17.893 µg/m3) > industrial (10.58 µg/m3) > urban (7.696 µg/m3) > rural (4.08 µg/m3). The rank order of areas based on the pooled (mean) concentration of EC in PM2.5 was traffic (17.893 µg/m3) > industrial (2.65 µg/m3) > Urban (1.48 µg/m3) > rural (1.06 µg/m3). The pooled concentrations of OC and EC bound to PM2.5 in traffic areas were higher than in other areas. Therefore, it is recommended that monitoring and effectively reducing concentration plans are carried out, especially in traffic areas.
RESUMO
The concentration of PTEs in the muscle of crabs, was meta-analyzed using a random-effects model based on countries' subgroups. The non-carcinogenic and carcinogenic risks related to the ingestion of PTEs via the consumption of crab fish were estimated. The meta-analysis included one hundred and eight papers with 109 data reports. The rank order of PTEs based on pooled (mean) concentration in the muscle of crabs was Ni (4.490 mg/kg-ww) > Pb (1.891 mg/kg-ww) >As (1.601 mg/kg-ww) > Cd (1.101 mg/kg-ww). The results showed that adults and children consumers in many countries are at risk of non-carcinogenicity due to ingestion of Ni, Pb, As, and Cd and carcinogenicity risk due to As. Therefore, the bioaccumulation of PTEs in the muscle of crabs can be considered a global health risk. Hence, to decrease the health risk of PTEs in the muscle of crabs, continuous monitoring and reducing the emission of PTEs in aquatic environments are recommended.
Assuntos
Braquiúros , Metais Pesados , Poluentes do Solo , Animais , Adulto , Criança , Humanos , Metais Pesados/análise , Monitoramento Ambiental/métodos , Cádmio/análise , Chumbo/análise , Músculos , Medição de Risco , Poluentes do Solo/análise , SoloRESUMO
Essential oils (EOs) are natural products called volatile oils or aromatic and ethereal oils derived from various parts of plants. They possess antioxidant and antimicrobial properties, which offer natural protection against a variety of pathogens and spoilage microorganisms. Studies conducted in the last decade have demonstrated the unique applications of these compounds in the fields of the food industry, agriculture, and skin health. This systematic article provides a summary of recent data pertaining to the effectiveness of EOs and their constituents in combating fungal pathogens through diverse mechanisms. Antifungal investigations involving EOs were conducted on multiple academic platforms, including Google Scholar, Science Direct, Elsevier, Springer, Scopus, and PubMed, spanning from April 2000 to October 2023. Various combinations of keywords, such as "essential oil," "volatile oils," "antifungal," and "Aspergillus species," were used in the search. Numerous essential oils have demonstrated both in vitro and in vivo antifungal activity against different species of Aspergillus, including A. niger, A. flavus, A. parasiticus, A. fumigatus, and A. ochraceus. They have also exhibited efficacy against other fungal species, such as Penicillium species, Cladosporium, and Alternaria. The findings of this study offer novel insights into inhibitory pathways and suggest the potential of essential oils as promising agents with antifungal and anti-mycotoxigenic properties. These properties could make them viable alternatives to conventional preservatives, thereby enhancing the shelf life of various food products.
RESUMO
The health risks (non-carcinogenic and carcinogenic risk) were calculated in both adults and children, using target hazard quotient (THQ) and carcinogenic risk (CR). The concentrations of Cd, Pb, and Ni were higher than the standard limits but they did not pose any non-carcinogenic health risks in adult and children's consumers (THQ <1). Meanwhile, the risk assessment of iAs indicates THQ > 1 for children in Egypt. Moreover, the THQ value due to Me Hg for adult in Tunisia and for children in Tunisia, Malta, Portugal, Latvia, Cambogia, Peru, South Korea, Romania, Hong Kong, United Arab Emirates, Morocco, and Egypt was higher than 1 value. In addition, the calculated CR values of iAs for the adults and children were within the threshold risk of developing cancer (Between 1.00E-4 to 1.00E-6). Therefore, it is recommended to continuously monitor the concentration of PTEs in canned tuna.
RESUMO
With the increasing use of nuclear technology, concerns about the contamination of water resources with radionuclides and the contamination of seafood are increasing. In the current investigation, a meta-analysis and exposure assessment regarding the concentration of radionuclides, including lead-210 (Pb-210), polonium -210 (Po-210), and cesium-137 (Cs-137) in the muscle of Sardin fish were conducted. In this regard, some databases including Scopus and PubMed were selected to retrieve papers on the concentration of radionuclides in the muscle of Sardin fish from January 2000 to 25 June 2021. The used keywords were polonium-210, natural radioactivity, lead-210, radiocesium, cesium-137, radionuclides, radium-226, seafood, marine foods, fish, sardine fish, sardinella longiceps, and Clupeidae. Also, effective dose (ED) was calculated to estimate carcinogenic risk in Sardine fish consumers. The rank order of radionuclides in the muscle of sardine fish was Po-210 (31.50 Bq/kg) > Pb-210 (3.34 Bq/kg) > Cs-137 (0.48 Bq/kg). Based on level of Pb-210 rank of countries was France (12.00 Bq/kg) > India (4.06 Bq/kg) > Turkey (3.29 Bq/kg) > Spain (1.00 Bq/kg) > Slovenia (0.55 Bq/kg); Po-210 was Turkey (74.96 Bq/kg) > Spain (48.00 Bq/kg) > France (31.500 Bq/kg > India (30.25 Bq/kg) > Slovenia (25.00 Bq/kg) > Kuwait (7.28 Bq/kg) and also, Cs-137 was Japan (1.22 Bq/kg) > Croatia (0.18 Bq/kg) > India (0.23 Bq/kg). The lowest and highest ED of 210Po was observed in Kuwait (5.10E-04 msv/y, female) and France (3.14E-01, male); Pb-210, Slovenia (7.24E-05 msv/y, male) and France (1.48E-02 msv/y, female), and Cs-137, Croatia (8.47E-08 msv/y, male) and Japan (2.54E-05 msv/y, female), respectively. The risk assessment shows that the exposed population are at an acceptable range of risk (H < 1 mSv/y).
Assuntos
Polônio , Animais , Feminino , Masculino , Radioisótopos de Césio/análise , Chumbo/análise , Músculos/química , Polônio/análise , Alimentos Marinhos/análiseRESUMO
Contamination of food with mycotoxins can pose harmful effects on the health of consumers in the long term. Coffee contamination with mycotoxins has become a global concern. This study attempted to meta-analyze the concentration and prevalence of ochratoxin A (OTA) in coffee products and estimate consumers' health risks. The search was conducted among international databases, including Scopus, PubMed, Embase, and Web of Science, for 1 January 2010 to 1 May 2022. The concentration and prevalence of OTA in coffee products were meta-analyzed according to country subgroups. Health risk assessment was conducted based on Margin of Exposures (MOEs) using the Monte Carlo simulation (MCS) technique. The three countries that had the highest Pooled concentration of OTA in coffee were observed in Chile (100.00%), Kuwait (100.00%), and France (100.00%). The overall prevalence of OTA in coffee products was 58.01%, 95% CI (48.37-67.39). The three countries that had the highest concentration of OTA were Philippines (39.55 µg/kg) > Turkey (39.32 µg/kg) > and Panama (21.33 µg/kg). The mean of MOEs in the adult consumers in Panama (9,526) and the Philippines (8,873) was lower than 10,000, while the mean of MOEs in other countries was higher than 10,000. Therefore, monitoring and control plans should be carried out in different countries.
RESUMO
Regarding the cost-effective photo-degradation of ofloxacin (OFL), present study investigates UV/sulfite /ZnO (USZ) in reactor conventional (without baffles) and baffled photocatalytic reactor (BPCR). The optimal condition was 0.77:2:50 sulfite/ZnO/OFL molar ratio, pH 7, and 30 min reaction time for 100% degradation of 200 mg L-1 concentration of OFL. As information obtained, the UZI process reduces the BOD and COD level about 66% to 86.29% within 80 min reaction, respectively. Also, BOD/COD ratio initial from 0.26 reaches 0.6 after 30 min of reaction time. Kinetic investigation increasing OFL concentration, kobs and robs increase, and, secondly, in the conventional and BPCR reactor, kobs increase is about 17% and 50% with increasing OFL concentration from 50 to 200 mgL-1. Also, figure-of-merit EEo varies from 12.66 to 17.41 and 7.26 to 10.15 kWhm3 for conventional reactor and 8.66-13.61 to 5.24-8.12 kWhm3, respectively. Also, kinetic model EEo declines from 15.23 to 8.61 and from 13.31 to 5.37 kWh m-3 in conventional and BPCR, respectively. Total cost of the system (TCS) decreases from 7.31 to 2.16 $ in conventional reactor and 4.57 to 0.55 $ in PCBR reactor. Total cost of the system (TCS) was investigated at different concentrations.
Assuntos
Poluentes Químicos da Água , Óxido de Zinco , Cinética , Ofloxacino , SulfitosRESUMO
Exposure to radionuclides, especially in food, can endanger the health of consumers. In this study, a systematic review and meta-analysis were performed regarding the concentration of radionuclides in tuna fish muscle. International databases including PubMed, Scopus, and Embase were searched to find articles regarding the concentration of radionuclides in tuna fish muscle from 1 January 2000 to 20 February 2021. The lowest and highest concentration of radionuclides was related to Caesium-137 (137Cs) and Potassium-40 (4 K), respectively. The rank order of radionuclides based on their pooled concentration was 4 K (370.157 Bq/kg) > 210Po Polonium-210 (26.312 Bq/kg) > 210Pb (5.339 Bq/kg) > 226Ra (4.005 Bq/kg) > 137Cs (0.415 Bq/kg). The health risk assessment based on annual effective dose indicates that consumers are at the safe range of health risk (H < 1 mSv/y). The continuous monitoring concentration of radionuclides in seafood and health risk assessment should be recommended.
Assuntos
Monitoramento de Radiação , Atum , Animais , Músculos , Medição de RiscoRESUMO
In the current study, the concentration and prevalence of birds' egg's mycotoxins among 11 articles (66 studies) based on countries, part of eggs, and type of mycotoxins subgroups were meta-analyses using a random-effect model. The order of mycotoxin according to concentration of mycotoxin was Deoxynivalenol (20.083 µg/kg) > Zearalenone (2.065 µg/kg) > Enniatin (1.120 µg/kg) > Total aflatoxin (0.371 µg/kg) > Beauvericin (0.223 µg/kg) > Ochratoxins (0.087 µg/kg) > Citrinin (0.010 µg/kg). Further, the mycotoxins' concentration in the yolk part (2.070 µg/kg) was higher than the mixed eggs (0.283 µg/kg). The rank order of mycotoxin based on country was China (14.990 µg/kg) > Cameroon (7.594 µg/kg) > Thailand (1.870 µg/kg) > Finland (0.920 µg/kg) > Iran (0.312 µg/kg) > Jordan (0.202 µg/kg) > Belgium (0.183 µg/kg) > Spain (
Assuntos
Micotoxinas , Tricotecenos , Animais , Aves , Contaminação de Alimentos/análise , Micotoxinas/análise , Prevalência , Tricotecenos/análiseRESUMO
The contamination of fish type products such as silver pomfret fish fillets by potentially toxic elements (PTEs) has raised global health concerns. Related studies regarding the concentration of PTEs in fillets of silver pomfret fish were retrieved among some international databases such as Scopus, PubMed and Embase between 1 January 1983 and 10 March 2020. The pooled (mean) concentration of PTEs in fillets of silver pomfret fish was meta-analyzed with the aid of a random-effect model (REM). Also, the non-carcinogenic risk was estimated via calculating the 95th percentile of the total target hazard quotient (TTHQ). The meta-analysis of 21 articles (containing 25 studies or data reports) indicated that the ranking of PTEs in fillets of silver pomfret fish was Fe (11,414.81 µg/kg wet weight, ww) > Zn (6055.72 µg/kg ww) > Cr (1825.79 µg/kg ww) > Pb (1486.44 µg/kg ww) > Se (1053.47 µg/kg ww) > Cd (992.50 µg/kg ww) > Ni (745.23 µg/kg ww) > Cu (669.71 µg/kg ww) > total As (408.24 µg/kg ww) > Co (87.03 µg/kg ww) > methyl Hg (46.58 µg/kg ww). The rank order of health risk assessment by country based on the TTHQ for adult consumers was Malaysia (2.500) > Bangladesh (0.886) > Iran (0.144) > China (0.045) > Pakistan (0.020) > India (0.015), while the corresponding values for child consumers was Malaysia (11.790) > Bangladesh (4.146) > Iran (0.675) > China (0.206) > Pakistan (0.096) > India (0.077). The adult consumers in Malaysia and children in Malaysia and Bangladesh were at considerable non-carcinogenic risk. Therefore, following the recommended control plans in order to reduce the health risk associated with the ingestion of PTEs via consumption of silver pomfret fish fillets is crucial.
Assuntos
Metais Pesados , Medição de Risco , Prata , Adulto , Animais , Criança , China , Monitoramento Ambiental , Humanos , Índia , Irã (Geográfico) , Malásia , Metais Pesados/análise , PaquistãoRESUMO
The contamination of seafood like narrow-barred Spanish mackerel (Scomberomorus commerson) fillets by potentially toxic elements (PTEs) has converted to worldwide health concerns. In this regard, the related citations regarding the concentration of PTEs in fillets of narrow-barred Spanish mackerel were collected through some of the international databases such as Scopus, Cochrane, PubMed, and Scientific Information Database (SID) up to 10 March 2020. The concentration of PTEs in fillets of narrow-barred Spanish mackerel fish was meta-analyzed and the health risk (non-carcinogenic risk) was estimated by the total target hazard quotient (TTHQ). The meta-analysis of data indicated that the rank order of PTEs in fillet of narrow-barred Spanish mackerel was Fe (10,853.29 µg/kg-ww) > Zn (4007.00 µg/kg-ww) > Cu (1005.66 µg/kg-ww) > total Cr (544.14 µg/kg-ww) > Mn (515.93 µg/kg-ww) > Ni (409.90 µg/kg-ww) > Pb (180.99 µg/kg-ww) > As (93.11 µg/kg-ww) > methyl Hg (66.60 µg/kg-ww) > Cd (66.03 µg/kg-ww). The rank order of health risk assessment based on the country by the aid of TTHQ for adult consumers was Malaysia (0.22251) > Philippines (0.21912) > Egypt (0.08684) > Taiwan (0.07430) > Bahrain (0.04893) > Iran (0.03528) > China (0.00620) > Pakistan (0.00316) > Yemen (0.00157) > India (0.00073). In addition, the rank order of health risk assessment based on the country by the aid of TTHQ for child consumers was Malaysia (1.03838) > Philippines (1.02257) > Egypt (0.40523) > Taiwan (0.34674) > Bahrain (0.22832) > Iran (0.16466) > China (0.02892) > Pakistan (0.01474) > Yemen (0.00731) > India (0.00340). Therefore, the children in Malaysia and the Philippines were at considerable non-carcinogenic risk. Hence, approaching the recommended control plans in order to decrease the non-carcinogenic risk associated with the ingestion of PTEs via the consumption of narrow-barred Spanish mackerel fish fillets is crucial.
Assuntos
Metais Pesados , Perciformes , Poluentes do Solo , Adulto , Animais , Criança , China , Egito , Monitoramento Ambiental , Humanos , Índia , Irã (Geográfico) , Malásia , Metais Pesados/análise , Paquistão , Medição de Risco , Poluentes do Solo/análise , TaiwanAssuntos
Arsênio , Poluentes Químicos da Água , Animais , Arsênio/análise , Peixes , Humanos , Paquistão , Rios , Poluentes Químicos da Água/análiseRESUMO
The application of nanotechnology in food packaging is widely considered during the last two decades. In this regard, numerous studies have been conducted regarding applying nanomaterials such as zinc oxide, clay, silver, carbon nanotube, titanium dioxide, and copper, and copper oxide in food packaging which were summarized in the current study. The employing of nano food packaging increases the physicochemical quality of food (color, flavor, moisture content, weight, bioavailability, and texture) and reduces the microbial load by cell-membrane function, Trojan-horse, and reactive oxygen mechanisms while they improve the barrier/mechanical properties of food packaging. Although nano food packaging has many advantages for public health, the associated toxicity due to migration, especially in acidic conditions, is considerable. Further studies regarding the advantages and disadvantages of this technique are recommended.
Assuntos
Embalagem de Alimentos , Nanoestruturas , Inocuidade dos AlimentosRESUMO
Exposure to heavy metals such as arsenic (As), lead (Pb), and cadmium (Cd) in either the short or the long term can cause cancers in humans. Dietary intake and consumption of rice (Oryza sativa L.) is increasing in Iran, and several studies on the concentration of heavy metals in rice have been carried out in this country in recent years. In this perspective, the main objective of the present study was to investigate, even via a meta-analysis of the existing literature, the presence of As and Pb in rice from many geographical areas in Iran, as well as to estimate the carcinogenic risk of these heavy metals in rice consumers. The results of the present ten years-spanning systematic review indicate that 21 reports, collecting a total of 2088 samples, were performed between 2008 and October 2017. The minimum and maximum concentration of As was observed in the Golestan area (0.01⯱â¯0.01â¯mg/kg d.w) and the Gillan region (3â¯mg/kg d.w); and Pb in the Shahrekord (0.07⯱â¯0.02â¯mg/kg d.w) and Mazandaran (35â¯mg/kg d.w). The meta-analysis of data showed that pooled concentration of As in the rice was 0.04 (95%CI: 0.02-0.06â¯mg/kg d.w), which resulted lower than the National Standard (NS) limits. However, the pooled concentration of Pb in the rice was 0.38 (95%CI: 0.25-0.5â¯mg/kg d.w), i.e., higher than NS limits. The heterogeneity was significant between As (I2â¯=â¯63%, P valueâ¯=â¯.003) and Pb (I2â¯=â¯96%, P valueâ¯<â¯.001) studies. The carcinogenic risk assessment showed that minimum and maximum incremental lifetime cancer risk (ILCR) of As was in the 45-54 (4.53â¯×â¯10-2) and 15-24 (5.50â¯×â¯10-2) year age groups consumers; and Pb, 45-54 (2.442â¯×â¯10-3) and 15-24 (2.96â¯×â¯10-3), respectively. The overall carcinogenesis risk of As (4.864â¯×â¯10-2) was 18.5 times higher than Pb (2.623â¯×â¯10-3). All age groups consumers of rice content of As and Pb are at considerable carcinogenesis risk (ILCRâ¯>â¯10-3). Therefore a decreased level of heavy metals in rice cultivation should be encouraged and performed in next planning.