Continuous wave Fe2+:ZnSe mid-IR optical fiber lasers.

Today fiber lasers in the visible to near-infrared region of the spectrum are well known, however mid-infrared fiber lasers have only recently approached the same commercial availability and power output. There has been a push to fabricate optical fiber lasers out of crystalline materials which have superior mid-IR performance and the ability to directly generate mid-IR light. However, these materials cannot currently be fabricated into an optical fiber via traditional means. We have used high pressure chemical vapor deposition (HPCVD) to deposit Fe2+:ZnSe into a silica optical fiber template. These deposited structures have been found to exhibit laser threshold behavior and emit CW mid-IR laser light with a central wavelength of 4.12 µm. This is the first reported solid state fiber laser with direct laser emission generated beyond 4 µm and represents a new frontier of possibility in mid-IR laser development.

The Significance of Metal Coordination in Imidazole-Functionalized Metal-Organic Frameworks for Carbon Dioxide Utilization.

The grafting of imidazole species onto coordinatively unsaturated sites within metal-organic framework MIL-101(Cr) enables enhanced CO2 capture in close proximity to catalytic sites. The subsequent combination of CO2 and epoxide binding sites, as shown through theoretical findings, significantly improves the rate of cyclic carbonate formation, producing a highly active CO2 utilization catalyst. An array of spectroscopic investigations, in combination with theoretical calculations reveal the nature of the active sites and associated catalytic mechanism which validates the careful design of the hybrid MIL-101(Cr).

Nitrous oxide detection at 5.26 µm with a compound glass antiresonant hollow-core optical fiber.

Laser-based gas sensors utilizing various light-gas interaction phenomena have proved their capacity for detecting different gases. However, achieving reasonable sensitivity, especially in the mid-infrared, is crucial. Improving sensor detectivity usually requires incorporating multipass cells, which increase the light-gas interaction path length at a cost of reduced stability. An unconventional solution comes with the aid of hollow-core fibers. In such a fiber, light is guided inside an air-core which, when filled with the analyte gas can serve as a low-volume and robust absorption cell. Here we report on the use of a borosilicate antiresonant hollow-core fiber for laser-based gas sensing. Due to its unique structure and guidance, this fiber provides low-loss, single-mode transmission $ {\gt} {5}\;{\unicode{x00B5}{\rm m}}$>5µm. The feasibility of using the fiber as a gas cell was verified by detecting nitrous oxide at 5.26 µm with a minimum detection limit of 20 ppbv.

Composite material anti-resonant optical fiber electromodulator with a 3.5 dB depth.

The hollow regions of an anti-resonant fiber (ARF) offer an excellent template for the deposition of functional materials. When the optical properties of such materials can be modified via external stimuli, it offers a method to control the transmission properties of the fiber device. In this Letter, we show that the integration of a ${{\rm MoS}_2}$MoS2 film into the ARF voids allows the fiber to act as an electro-optical modulator. We record a maximum modulation depth of 3.5 dB at 744 nm, with an average insertion loss of 7.5 dB.

Thermal Poling of Optical Fibers: A Numerical History.

This review gives a perspective of the thermal poling technique throughout its chronological evolution, starting in the early 1990s when the first observation of the permanent creation of a second order non-linearity inside a bulk piece of glass was reported. We then discuss a number of significant developments in this field, focusing particular attention on working principles, numerical analysis and theoretical advances in thermal poling of optical fibers, and conclude with the most recent studies and publications by the authors. Our latest works show how in principle, optical fibers of any geometry (conventional step-index, solid core microstructured, etc) and of any length can be poled, thus creating an advanced technological platform for the realization of all-fiber quadratic non-linear photonics.

All-fiber sixth harmonic generation of deep UV: erratum.

This erratum corrects the mistyped pump repetition rate in Opt. Lett.42, 4671 (2017)OPLEDP0146-959210.1364/OL.42.004671.

Hollow core fibers for optical amplification.

Hollow core optical fibers are normally passive light transport components. In contrast, within this Letter, we numerically investigate the possibility of using them as optical amplifiers, through the adoption of a novel fiber structure. We show that optical amplification can be achieved in hollow core fibers, where the cladding region is partially doped and composed of both resonant and anti-resonant elements. A balance between loss and glass/optical mode overlap is obtained, which allows efficient amplification over a limited spectral bandwidth. We discuss the case of a thulium-doped optical amplifier based on this novel technological approach.

All-fiber sixth-harmonic generation of deep UV.

We simulate and experimentally demonstrate deep ultraviolet generation from a 1550 nm laser source in a fully fiberized system by cascading second- and third-harmonic generation using a periodically poled silica fiber and an optical sub-micron diameter fiber. Harmonic generation is achieved by harnessing intermodal phase matching in optical microfibers and a permanent χ(2) induced via thermal poling. As a result, efficient nonlinear processes can be observed, despite the low third-order nonlinear susceptibility of silica glass.

Composite material hollow antiresonant fibers.

We study novel designs of hollow-core antiresonant fibers comprising multiple materials in their core-boundary membrane. We show that these types of fibers still satisfy an antiresonance condition and compare their properties to those of an ideal single-material fiber with an equivalent thickness and refractive index. As a practical consequence of this concept, we discuss the first realization and characterization of a composite silicon/glass-based hollow antiresonant fiber.

Single-fluxon controlled resistance switching in centimeter-long superconducting gallium-indium eutectic nanowires.

The ability to manipulate a single quantum object, such as a single electron or a single spin, to induce a change in a macroscopic observable lies at the heart of nanodevices of the future. We report an experiment wherein a single superconducting flux quantum, or a fluxon, can be exploited to switch the resistance of a nanowire between two discrete values. The experimental geometry consists of centimeter-long nanowires of superconducting Ga-In eutectic, with spontaneously formed Ga nanodroplets along the length of the nanowire. The nonzero resistance occurs when a Ga nanodroplet traps one or more superconducting fluxons, thereby driving a Josephson weak-link created by a second nearby Ga nanodroplet normal. The fluxons can be inserted or flipped by careful manipulation of the magnetic field or temperature to produce one of many metastable states of the system.

Extreme electronic bandgap modification in laser-crystallized silicon optical fibres.

For decades now, silicon has been the workhorse of the microelectronics revolution and a key enabler of the information age. Owing to its excellent optical properties in the near- and mid-infrared, silicon is now promising to have a similar impact on photonics. The ability to incorporate both optical and electronic functionality in a single material offers the tantalizing prospect of amplifying, modulating and detecting light within a monolithic platform. However, a direct consequence of silicon's transparency is that it cannot be used to detect light at telecommunications wavelengths. Here, we report on a laser processing technique developed for our silicon fibre technology through which we can modify the electronic band structure of the semiconductor material as it is crystallized. The unique fibre geometry in which the silicon core is confined within a silica cladding allows large anisotropic stresses to be set into the crystalline material so that the size of the bandgap can be engineered. We demonstrate extreme bandgap reductions from 1.11 eV down to 0.59 eV, enabling optical detection out to 2,100 nm.

Silicon p-i-n junction fibers.

Flexible Si p-i-n junction fibers made by high pressure chemical vapor deposition offer new opportunities in textile photovoltaics and optoelectronics, as exemplified by their photovoltaic properties, gigahertz bandwidth for photodetection, and ability to waveguide light.

Confined high-pressure chemical deposition of hydrogenated amorphous silicon.

Hydrogenated amorphous silicon (a-Si:H) is one of the most technologically important semiconductors. The challenge in producing it from SiH(4) precursor is to overcome a significant kinetic barrier to decomposition at a low enough temperature to allow for hydrogen incorporation into a deposited film. The use of high precursor concentrations is one possible means to increase reaction rates at low enough temperatures, but in conventional reactors such an approach produces large numbers of homogeneously nucleated particles in the gas phase, rather than the desired heterogeneous deposition on a surface. We report that deposition in confined micro-/nanoreactors overcomes this difficulty, allowing for the use of silane concentrations many orders of magnitude higher than conventionally employed while still realizing well-developed films. a-Si:H micro-/nanowires can be deposited in this way in extreme aspect ratio, small-diameter optical fiber capillary templates. The semiconductor materials deposited have ~0.5 atom% hydrogen with passivated dangling bonds and good electronic properties. They should be suitable for a wide range of photonic and electronic applications such as nonlinear optical fibers and solar cells.

Polycrystalline silicon optical fibers with atomically smooth surfaces.

We investigate the surface roughness of polycrystalline silicon core optical fibers fabricated using a high-pressure chemical deposition technique. By measuring the optical transmission of two fibers with different core sizes, we will show that scattering from the core-cladding interface has a negligible effect on the losses. A Zemetrics ZeScope three-dimensional optical profiler has been used to directly measure the surface of the core material, confirming a roughness of only ~0.1 nm. The ability to fabricate low-loss polysilicon optical fibers with ultrasmooth cores scalable to submicrometer dimensions should establish their use in a range of nonlinear optical applications.

Spontaneous waveguide Raman spectroscopy of self-assembled monolayers in silica micropores.

Advances in nanoscience are critically dependent on the ability to control and probe chemical and physical phenomena in confined geometries. A key challenge is to identify confinement structures with high surface area to volume ratios and controlled surface boundaries that can be probed quantitatively at the molecular level. Herein we report an approach for probing molecular structures within nano- to microscale pores by the application of spontaneous Raman spectroscopy. We demonstrate the method by characterization of the structural features of picomole quantities of well-organized octadecyltrichlorosilane (OTS) monolayers self-assembled on the interior pore surfaces of high aspect ratio (1 µm diameter × 1-10 cm length), near-atomically smooth silica microstructured optical fibers (MOFs). The simple Raman backscattering collection geometry employed is well suited for a wide variety of diagnostic applications as demonstrated by tracking the combustion of the hydrocarbon chains of the OTS self-assembled monolayer (SAM) and spectral confirmation of the formation of an adsorbed monolayer of human serum albumin (HSA) protein. Using this MOF Raman approach, molecular processes in precisely defined, highly confined geometries can be probed at high pressures and temperatures, with a wide range of excitation wavelengths from the visible to the near-IR, and under other external perturbations such as electric and magnetic fields.

Organosilane self-assembled monolayer growth from supercritical carbon dioxide in microstructured optical fiber capillary arrays.

Microstructured optical fibers form a new class of extreme aspect ratio templates that are well-suited for precise, designed spatial organization of materials and molecules at dimensions down to the nanoscale. The extreme aspect ratios of the nanoscale to microscale pores in the templates necessitates new approaches to fabrication of nanowires, nanotubes, and self-assembled monolayers within them. High-pressure fluids, which have lower viscosities than liquids and no surface tension, are well-suited for penetrating such extreme aspect ratio capillaries. Here we report an approach to fabricating self-assembled monolayers within microstructured optical fibers using near supercritical or supercritical carbon dioxide. An AFM-based "shaving" technique has been developed to characterize the monolayers formed in capillaries that are too small to allow for characterization by conventional approaches.

Microstructured optical fibers as high-pressure microfluidic reactors.

Deposition of semiconductors and metals from chemical precursors onto planar substrates is a well-developed science and technology for microelectronics. Optical fibers are an established platform for both communications technology and fundamental research in photonics. Here, we describe a hybrid technology that integrates key aspects of both engineering disciplines, demonstrating the fabrication of tubes, solid nanowires, coaxial heterojunctions, and longitudinally patterned structures composed of metals, single-crystal semiconductors, and polycrystalline elemental or compound semiconductors within microstructured silica optical fibers. Because the optical fibers are constructed and the functional materials are chemically deposited in distinct and independent steps, the full design flexibilities of both platforms can now be exploited simultaneously for fiber-integrated optoelectronic materials and devices.