Increasing co-occurrence of fine particulate matter and ground-level ozone extremes in the western United States.

Wildfires and meteorological conditions influence the co-occurrence of multiple harmful air pollutants including fine particulate matter (PM2.5) and ground-level ozone. We examine the spatiotemporal characteristics of PM2.5/ozone co-occurrences and associated population exposure in the western United States (US). The frequency, spatial extent, and temporal persistence of extreme PM2.5/ozone co-occurrences have increased significantly between 2001 and 2020, increasing annual population exposure to multiple harmful air pollutants by ~25 million person-days/year. Using a clustering methodology to characterize daily weather patterns, we identify significant increases in atmospheric ridging patterns conducive to widespread PM2.5/ozone co-occurrences and population exposure. We further link the spatial extent of co-occurrence to the extent of extreme heat and wildfires. Our results suggest an increasing potential for co-occurring air pollution episodes in the western US with continued climate change.

Co-occurrence of extremes in surface ozone, particulate matter, and temperature over eastern North America.

Heat waves and air pollution episodes pose a serious threat to human health and may worsen under future climate change. In this paper, we use 15 years (1999-2013) of commensurately gridded (1° x 1°) surface observations of extended summer (April-September) surface ozone (O3), fine particulate matter (PM2.5), and maximum temperature (TX) over the eastern United States and Canada to construct a climatology of the coincidence, overlap, and lag in space and time of their extremes. Extremes of each quantity are defined climatologically at each grid cell as the 50 d with the highest values in three 5-y windows (∼95th percentile). Any two extremes occur on the same day in the same grid cell more than 50% of the time in the northeastern United States, but on a domain average, co-occurrence is approximately 30%. Although not exactly co-occurring, many of these extremes show connectedness with consistent offsets in space and in time, which often defy traditional mechanistic explanations. All three extremes occur primarily in large-scale, multiday, spatially connected episodes with scales of >1,000 km and clearly coincide with large-scale meteorological features. The largest, longest-lived episodes have the highest incidence of co-occurrence and contain extreme values well above their local 95th percentile threshold, by +7 ppb for O3, +6 µg m-3 for PM2.5, and +1.7 °C for TX. Our results demonstrate the need to evaluate these extremes as synergistic costressors to accurately quantify their impacts on human health.

Effect of climate change on surface ozone over North America, Europe, and East Asia.

The effect of future climate change on surface ozone over North America, Europe, and East Asia is evaluated using present-day (2000s) and future (2100s) hourly surface ozone simulated by four global models. Future climate follows RCP8.5, while methane and anthropogenic ozone precursors are fixed at year-2000 levels. Climate change shifts the seasonal surface ozone peak to earlier in the year and increases the amplitude of the annual cycle. Increases in mean summertime and high-percentile ozone are generally found in polluted environments, while decreases are found in clean environments. We propose climate change augments the efficiency of precursor emissions to generate surface ozone in polluted regions, thus reducing precursor export to neighboring downwind locations. Even with constant biogenic emissions, climate change causes the largest ozone increases at high percentiles. In most cases, air quality extreme episodes become larger and contain higher ozone levels relative to the rest of the distribution.