DMA study of water's glass transition in nanoscale confinement.

Dynamic mechanical analysis (DMA) measurements of water confined in nanoporous silica have been performed as a function of temperature and frequency for different pore sizes (2.5-10 nm) at heating and cooling. Most of the data show three processes, P1, P2 and P3, where P1 and P2 depend on measurement frequency and P3 does not. The characteristic shift of P3 with pore size shows that this process corresponds to freezing/melting of "internal water", i.e. in the core of the pores. Thermal expansion data indicate - in agreement with e.g. [A. Taschin, P. Bartolini and R. Torre, Meas. Sci. Technol., 2017, 28, 014009] - that in all our nanoporous systems about 2 layers of water remain liquid much below the freezing point. Dynamic elastic measurements show clear signatures of glass freezing of this supercooled water in the vicinity of P1. Extrapolating the DMA data to the timescale (103 s) of adiabatic calorimetry unveils a systematic behaviour: P1(T) shows a clear size dependence for a broad range of pore diameters, i.e. 2.5 nm ≤ d ≤ 52 nm, implying (together with the corresponding activation energy 0.5 eV) that P1 corresponds to the glass-liquid transition of a few layers of supercooled water at Tg(d). An extrapolation of Tg(d) to d → ∞ yields Tg(∞) ≈ 136 K, the traditional value for bulk water. The small (liquid like) value of Young's modulus in a temperature region above P1 is most naturally explained assuming that the supercooled water in this range is still liquid, implying that Tg values of 160 K or even 210 K - as suggested by various authors - are unlikely.

Strain intermittency due to avalanches in ferroelastic and porous materials.

The avalanche statistics in porous materials and ferroelastic domain wall systems has been studied for slowly increasing compressive uniaxial stress with stress rates between 0.2 and 17 kPa s-1. Velocity peaks [Formula: see text] are calculated from the measured strain drops and used to determine the corresponding Energy distributions [Formula: see text]. Power law distributions [Formula: see text] have been obtained over 4-6 decades. For most of the porous materials and domain wall systems an exponent [Formula: see text] was obtained in good agreement with mean-field theory of the interface pinning transition. For charcoal, shale and calcareous schist we found significant deviations of the exponents from mean-field values in agreement with recent acoustic emission experiments.

Nematic susceptibility of hole-doped and electron-doped BaFe2As2 iron-based superconductors from shear modulus measurements.

The nematic susceptibility, χφ, of hole-doped Ba(1-x)K(x)Fe2As2 and electron-doped Ba(Fe(1-x)Co(x))2As2 iron-based superconductors is obtained from measurements of the elastic shear modulus using a three-point bending setup in a capacitance dilatometer. Nematic fluctuations, although weakened by doping, extend over the whole superconducting dome in both systems, suggesting their close tie to superconductivity. Evidence for quantum critical behavior of χφ is, surprisingly, only found for Ba(Fe(1-x)Co(x))2As2 and not for Ba(1-x)K(x)Fe2As2--the system with the higher maximal Tc value.

Quantification of pulmonary microcirculation by dynamic contrast-enhanced magnetic resonance imaging: comparison of four regularization methods.

Tissue microcirculation can be quantified by a deconvolution analysis of concentration-time curves measured by dynamic contrast-enhanced magnetic resonance imaging. However, deconvolution is an ill-posed problem, which requires regularization of the solutions. In this work, four algebraic deconvolution/regularization methods were evaluated: truncated singular value decomposition and generalized Tikhonov regularization (GTR) in combination with the L-curve criterion, a modified LCC (GTR-MLCC), and a response function model that takes a-priori knowledge into account. To this end, dynamic contrast-enhanced magnetic resonance imaging data sets were simulated by an established physiologically reference model for different signal-to-noise ratios and measured on a 1.5-T system in the lung of 10 healthy volunteers and 20 patients. Analysis of both the simulated and measured dynamic contrast-enhanced magnetic resonance imaging datasets revealed that GTR in combination with the L-curve criterion does not yield reliable and clinically useful results. The three other deconvolution/regularization algorithms resulted in almost identical microcirculatory parameter estimates for signal-to-noise ratios > 10. At low signal-to-noise ratios levels (<10) typically occurring in pathological lung regions, GTR in combination with a modified L-curve criterion approximates the true response function much more accurately than truncated singular value decomposition and GTR in combination with response function model with a difference in accuracy of up to 76%. In conclusion, GTR in combination with a modified L-curve criterion is recommended for the deconvolution of dynamic contrast-enhanced magnetic resonance imaging curves measured in the lung parenchyma of patients with highly heterogeneous signal-to-noise ratios.

Directional magnetoelectric effects in MnWO4: magnetic sources of the electric polarization.

The ferroelectric order and magnetic field induced effects observed in the spiral phase of MnWO4 are described theoretically. It is demonstrated explicitly that the Dzyaloshinskii-Moriya antisymmetric interactions contribute to the correlation between spins and electric dipoles in the incommensurate and commensurate ferroelectric phases of magnetic multiferroics. However, other single-site symmetric interactions are shown to be involved in the magnetoelectric process, suggesting the possible existence of an electric polarization originating from purely symmetric effects.

How to couple Landau theory to an equation of state.

We show how to construct a Landau-type free energy based on a primary order parameter coupled to finite strain with an elastic energy derived from an arbitrary equation of state V = V(P). The resulting class of models provides an excellent and efficient framework for the systematic study of phase transformations for a wide range of materials up to ultrahigh pressures.

Suppression of the order parameter correlation length by inhomogeneous strains

Very recently we presented puzzling results of diffuse neutron scattering experiments on KSCN and RbSCN. The data yield an increase of the diffuse intensity with increasing temperature below T(c), whereas the width remains constant. Using molecular dynamics and 3D Monte Carlo simulations, we have shown that below T(c) the width of the correlation functions can be stabilized by strain fields originating from the order parameter strain interactions. Here we construct a novel analytic model which predicts the existence of a second characteristic length scale and explains the suppression of the growth of precursor clusters by the influence of inhomogeneous strain fields.

Ferroelastic domain freezing and low-frequency elastic behaviour of [Formula: see text] (ALHS).

In this work elastic measurements on [Formula: see text] (ALHS) which were carried out in the low-frequency range between 1 and 50 Hz are presented. The temperature dependence of the inverse elastic compliance [Formula: see text] has been determined between 90 K and 420 K. Distinct anomalies have been found in the temperature dependence of [Formula: see text], which are connected to the motion of domain walls in the ferroelastic phase below [Formula: see text]. Around [Formula: see text] a (partial) ferroelastic `domain freezing' phenomenon has been observed. To the knowledge of the authors this is the first time that pure ferroelastic domain freezing has been reported. However, below [Formula: see text] the domain walls seem to retain a certain vibrational degree of freedom which could be responsible for an additional anomaly of the loss modulus which was observed. The elastic behaviour of a crystal of ALHS is dependent on the `history' of the given sample. During temperature cycling [Formula: see text] shows differences between the first run of heating and cooling and later runs. Finally, some basic insights concerning the domain wall motion were obtained; it was found that the domain wall mobility decreases by three orders of magnitude in the temperature region 170 - 230 K.

[Spectrum of indications for flexible bronchoscopy. Importance in a general hospital]. / Indikationsspektrum der flexiblen Bronchoskopie. Die Bedeutung in einem Krankenhaus der Grundversorgung.

Fiberbronchoscopy is an extremely safe procedure carrying only minimal risk to the patient. Diagnostic application may include a transbronchial biopsy, brushing, and bronchoalveolar lavage. The indications for therapeutic bronchoscopy are, in particular, targeted irrigation and aspiration, extraction of foreign bodies, and hemostasis. Diagnostic and therapeutic indications are demonstrated in a number of cases.