Characterisation of Curing of Vinyl Ester Resin in an Industrial Pultrusion Process: Influence of Die Temperature.

Pultrusion is a high-volume manufacturing process for Fibre-Reinforced Polymer (FRP) composites. It requires careful tuning and optimisation of process parameters to obtain the maximum production rate. The present work focuses on the correlation between the set die temperatures of 80 °C, 100 °C, 120 °C, and 140 °C and the resin cure state at constant pull speeds. Lab-scale oven trials were conducted to understand the thermal behaviour of the resin system and to provide a temperature range for the pultrusion trials. Dielectric Analysis (DEA) was used during pultrusion trials to monitor the effect of die temperature on the cure progression. The DEA results showed that, by increasing die temperature, the exothermic peak shifts closer towards the die entry. Moreover, the degree of cure for samples processed at 140 °C was 97.7%, in comparison to 86.2% for those cured at 100 °C. The rate of conversion and the degree of cure correspond directly to the set die temperatures of the pultrusion trials, contributing to understanding the effect of die temperature on cure progression. Mechanical and thermal material properties were measured. Samples cured at 120 °C showed the highest mechanical performance, exceeding those cured at 140 °C, linked to the generation of higher internal stress due to the higher rate of conversion. This work can be used as a guide for pultruded composite sections, to understand the cure behaviour of resin systems under various applied temperatures and the impact of the die temperature conditions on thermal and mechanical properties.

In Situ Thermoset Cure Sensing: A Review of Correlation Methods.

Thermoset polymer composites have increased in use across multiple industries, with recent applications consisting of high-complexity and large-scale parts. As applications expand, the emphasis on accurate process-monitoring techniques has increased, with a variety of in situ cure-monitoring sensors being investigated by various research teams. To date, a wide range of data analysis techniques have been used to correlate data collected from thermocouple, dielectric, ultrasonic, and fibre-optic sensors to information on the material cure state. The methods used in existing publications have not been explicitly differentiated between, nor have they been directly compared. This paper provides a critical review of the different data collection and cure state correlation methods for these sensor types. The review includes details of the relevant sensor configurations and governing equations, material combinations, data verification techniques, identified potential research gaps, and areas of improvement. A wide range of both qualitative and quantitative analysis methods are discussed for each sensing technology. Critical analysis is provided on the capability and limitations of these methods to directly identify cure state information for the materials under investigation. This paper aims to provide the reader with sufficient background on available analysis techniques to assist in selecting the most appropriate method for the application.

Review on Local Buckling of Hollow Box FRP Profiles in Civil Structural Applications.

Hollow box pultruded fibre-reinforced polymers (PFRP) profiles are increasingly used as structural elements in many structural applications due to their cost-effective manufacturing process, excellent mechanical properties-to-weight ratios, and superior corrosion resistance. Despite the extensive usage of PFRP profiles, there is still a lack of knowledge in the design for manufacturing against local buckling on the structural level. In this review, the local buckling of open-section (I, C, Z, L, T shapes) and closed-section (box) FRP structural shapes was systematically compared. The local buckling is influenced by the unique stresses distribution of each section of the profile shapes. This article reviews the related design parameters to identify the research gaps in order to expand the current design standards and manuals of hollow box PFRP profiles and to broaden their applications in civil structures. Unlike open-section profiles, it was found that local buckling can be avoided for box profiles if the geometric parameters are optimised. The identified research gaps include the effect of the corner (flange-web junction) radius on the local buckling of hollow box PFRP profiles and the interactions between the layup properties, the flange-web slenderness, and the corner geometry (inner and outer corner radii). More research is still needed to address the critical design parameters of layup and geometry controlling the local buckling of pulwound box FRP profiles and quantify their relative contribution and interactions. Considering these interactions can facilitate economic structural designs and guidelines for these profiles, eliminate any conservative assumptions, and update the current design charts and standards.

Bending and Shear Behaviour of Waste Rubber Concrete-Filled FRP Tubes with External Flanges.

An innovative beam concept made from hollow FRP tube with external flanges and filled with crumbed rubber concrete was investigated with respect to bending and shear. The performance of the rubberised-concrete-filled specimens was then compared with hollow and normal-concrete-filled tubes. A comparison between flanged and non-flanged hollow and concrete-filled tubes was also implemented. Moreover, finite element simulation was conducted to predict the fundamental behaviour of the beams. The results showed that concrete filling slightly improves bending performance but significantly enhances the shear properties of the beam. Adding 25% of crumb rubber in concrete marginally affects the bending and shear performance of the beam when compared with normal-concrete-filled tubes. Moreover, the stiffness-to-FRP weight ratio of a hollow externally flanged round tube is equivalent to that of a concrete-filled non-flanged round tube. The consideration of the pair-based contact surface between an FRP tube and infill concrete in linear finite element modelling predicted the failure loads within a 15% margin of difference.

Novel Bending Test Method for Polymer Railway Sleeper Materials.

Alternative sleeper technologies have been developed to address the significant need for the replacement of deteriorating timber railway sleepers. The review of the literature indicates that the railway sleepers might fail while in service, despite passing the evaluation tests of the current composite sleeper standards which indicated that these tests do not represent in situ sleeper on ballast. In this research, a new five-point bending test is developed to evaluate the flexural behaviour of timber replacement sleeper technologies supported by ballast. Due to the simplicity, acceptance level of evaluation accuracy and the lack of in-service behaviour of alternative sleepers, this new testing method is justified with the bending behaviour according to the Beam on Elastic Foundation theory. Three timber replacement sleeper technologies-plastic, synthetic composites and low-profile prestressed concrete sleepers in addition to timber sleepers-were tested under service loading condition to evaluate the suitability of the new test method. To address the differences in the bending of the sleepers due to their different modulus of elasticities, the most appropriate material for the middle support was also determined. Analytical equations of the bending moments with and without middle support settlement were also developed. The results showed that the five-point static bending test could induce the positive and negative bending moments experienced by railway sleepers under a train wheel load. It was also found that with the proposed testing spans, steel-EPDM rubber is the most suitable configuration for low bending modulus sleepers such as plastic, steel-neoprene for medium modulus polymer sleepers and steel-steel for very high modulus sleepers such as concrete. Finally, the proposed bending moment equations can precisely predict the flexural behaviour of alternative sleepers under the five-point bending test.

Behaviour of Polymer Filled Composites for Novel Polymer Railway Sleepers.

A novel concept of polymer railway sleeper is proposed in this study that has the potential to meet static performance requirements within the cost of hardwood timber. The existing challenges of composite sleepers, such as low performance or high cost, can be overcome using this innovative concept. Such a proclamation is proven through limit state design criteria and a series of experimentations. Results show that polyurethane foam as an infill material can provide sufficient strength and stiffness properties to the sleeper, but the inadequate screw holding capacity could be a problem. This limitation, however, can be overcome using a particulate filled resin system. The findings of this study will help the railway industry to develop a timber replacement sleeper.

Tensile Fatigue Behavior of Polyester and Vinyl Ester Based GFRP Laminates-A Comparative Evaluation.

Fatigue loading is critical to fibre reinforced polymer composites due to their anisotropic and heterogenous nature. This study investigated the tensile fatigue behaviour of polyester and vinyl ester based GFRP laminates to understand the critical aspects of failure mode and fatigue life under cyclic loading. GFRP laminates with two different resin systems (polyester and vinyl ester), two different stress ratios (0.1 and 0.5) and two different environmental conditions (air and water) were investigated at an applied stress of 80%, 60%, and 40% of the ultimate capacity. Based on the investigated parameters (i.e., resin types, stress ratio, environmental conditioning, and maximum applied stress), a fatigue model was proposed. Results show that the resin system plays a great role in fatigue failure mode while the stress ratio and environmental condition significantly affect the tensile fatigue life of GFRP laminates. The types of resin used in GFRP laminates and environmental conditions as input parameters in the proposed fatigue model are a unique contribution.