Methodologies to Evaluate the Micromechanics Flexural Strength Properties of Natural-Fiber-Reinforced Composites: The Case of Abaca-Fiber-Reinforced Bio Polyethylene Composites.

There is growing emphasis on developing green composites as a substitute for oil-based materials. In the pursuit of studying and enhancing the mechanical properties of these composites, tensile tests are predominantly employed, often overlooking the flexural properties. This study focuses on researching the flexural properties of abaca-fiber-reinforced bio-based high-density polyethylene (BioPE) composites. Specifically, composites containing 30 wt% of abaca fiber (AF) were treated with a coupling agent based on polyethylene functionalized with maleic acid (MAPE). The test results indicate that incorporating 8 wt% of the coupling agent significantly improved the flexural strength of the composites. Thereafter, composites with AF content ranging from 20 to 50 wt% were produced and subjected to flexural testing. It was observed that flexural strength was positively correlated with AF content. A micromechanics analysis was conducted to evaluate the contributions of the phases. This analysis involved assessing the mechanical properties of both the reinforcement and matrix to facilitate the modeling of flexural strength. The findings of this study demonstrate the feasibility of replacing oil-based matrices, such as high-density polyethylene (HDPE), with fully bio-based composites that exhibit comparable flexural properties to their oil-based counterparts.

Evaluation of the Interface Strength in the Abaca-Fiber-Reinforced Bio-Polyethylene Composites.

Bio-based polymers, with any of their constituents based on nonrenewable sources, can answer the demands of society and regulations regarding minimizing the environmental impact. The more similar such biocomposites are to oil-based composites, the easier the transition, especially for companies that do not like the uncertainty. A BioPE matrix, with a structure similar to that of a high-density polyethylene (HDPE), was used to obtain abaca-fiber-reinforced composites. The tensile properties of these composites are displayed and compared with commercial glass-fiber-reinforced HDPE. Since the strength of the interface between the reinforcements and the matrix is responsible for the exploitation of the strengthening abilities of the reinforcements, several micromechanical models were used to obtain an estimation of the strength of the interface and the intrinsic tensile strength of the reinforcements. Biocomposites require the use of a coupling agent to strengthen their interface, and once an 8 wt.% of such coupling agent was added to the composites, these materials returned tensile properties in line with commercial glass-fiber-reinforced HDPE composites.

Comparative Evaluation of the Stiffness of Abaca-Fiber-Reinforced Bio-Polyethylene and High Density Polyethylene Composites.

The use of bio-based matrices together with natural fibers as reinforcement is a strategy for obtaining materials with competitive mechanical properties, costs, and environmental impacts. However, bio-based matrices, unknown by the industry, can be a market entry barrier. The use of bio-polyethylene, which has properties similar to polyethylene, can overcome that barrier. In this study, composites reinforced with abaca fibers used as reinforcement for bio-polyethylene and high density polyethylene are prepared and tensile tested. A micromechanics analysis is deployed to measure the contributions of the matrices and reinforcements and to measure the evolution of these contributions regarding AF content and matrix nature. The results show that the mechanical properties of the composites with bio-polyethylene as a matrix were slightly higher than those of the composites with polyethylene as a matrix. It was also found that the contribution of the fibers to the Young's moduli of the composites was susceptible to the percentage of reinforcement and the nature of the matrices. The results show that it is possible to obtain fully bio-based composites with mechanical properties similar to those of partially bio-based polyolefin or even some forms of glass fiber-reinforced polyolefin.

Evaluation of the Strength of the Interface for Abaca Fiber Reinforced Hdpe and Biope Composite Materials, and Its Influence over Tensile Properties.

In this study, tensile properties of abaca-reinforced HDPE and BioPE composites have been researched. The strength of the interface between the matrix and the reinforcement of a composite material noticeably impacts its mechanical properties. Thus, the strength of the interface between the reinforcements and the matrices has been studied using micromechanics models. Natural fibers are hydrophilic and the matrices are hydrophobic, resulting in weak interfaces. In the study, a coupling agent based on polyethylene functionalised with maleic acid was used, to increase the strength of the interface. The results show that 8 wt% coupling agent contents noticeably increased the tensile strength of the composites and the interface. Tensile properties obtained for HDPE and BioPE-based coupled composites were statistically similar or better for BioPE-based materials. The use of bio-based matrices increases the possibility of decreasing the environmental impact of the materials, obtaining fully bio-based composites. The article shows the ability of fully bio-based composites to replace others using oil-based matrices.