RESUMO
We present a comprehensive experimental study of magnetization (2
RESUMO
The low temperature magnetic behaviour of the multiferroic quadruple perovskite CaMn7O12 is investigated. The magneto-caloric effect in this material is presented for the first time. Along with the established magnetic transitions, T N1 ~ 90 K and T N2 ~ 45 K, an anomaly at 20 K is observed in our dc magnetization, ac susceptibility and dielectric measurements; below which, an inverse magnetocaloric effect is also observed in our -ΔS M (T) plots. The neutron scattering measurements show minimal change between 10 K and 30 K in static correlations, but a clear change in energy and linewidth of the magnetic excitations is evident. The results suggest that only dynamic correlations change across T M ~ 20 K. The existence of multiple magnetic interactions below 45 K, with significant coupling between them, is demonstrated using an Arrott plot analysis of our magnetic data. Compatible conclusions are drawn from magnetocaloric plots. The peak change in isothermal magnetic entropy (-ΔS M) is 1.3 JK-1 kg-1 and the value of refrigeration capacity in CaMn7O12 is 34.5 J · kg-1 at 7 T.
RESUMO
A very recent report on the observation of superconductivity in Bi(4)O(4)S(3) [Mizuguchi, Y.; http://arxiv.org/abs/1207.3145] could potentially reignite the search for superconductivity in a broad range of layered sulfides. We report here the synthesis of Bi(4)O(4)S(3) at 500 °C by a vacuum encapsulation technique and its basic characterizations. The as-synthesized Bi(4)O(4)S(3) was contaminated with small amounts of Bi(2)S(3) and Bi impurities. The majority phase was found to be tetragonal (space group I4/mmm) with lattice parameters a = 3.9697(2) Å and c = 41.3520(1) Å. Both AC and DC magnetization measurements confirmed that Bi(4)O(4)S(3) is a bulk superconductor with a superconducting transition temperature (T(c)) of 4.4 K. Isothermal magnetization (M-H) measurements indicated closed loops with clear signatures of flux pinning and irreversible behavior. The lower critical field (H(c1)) at 2 K for the new superconductor was found to be ~15 Oe. Magnetotransport measurements showed a broadening of the resistivity (ρ) and a decrease in T(c) (ρ = 0) with increasing magnetic field. The extrapolated upper critical field H(c2)(0) was ~31 kOe with a corresponding Ginzburg-Landau coherence length of ~100 Å . In the normal state, the ρ ~ T(2) dependence was not indicated. Hall resistivity data showed a nonlinear magnetic field dependence. Our magnetization and electrical transport measurements substantiate the appearance of bulk superconductivity in as-synthesized Bi(4)O(4)S(3). On the other hand, Bi heat-treated at the same temperature is not superconducting, thus excluding the possibility of impurity-driven superconductivity in the newly discovered superconductor Bi(4)O(4)S(3).