Recent progress in tannin and lignin blended metal oxides and metal sulfides as smart materials for electrochemical sensor applications.

Our technologically advanced civilization has made sensors an essential component. They have potential uses in the pharmaceutical sector, clinical analysis, food quality control, environmental monitoring, and other areas. One of the most active fields of analytical chemistry research is the fabrication of electrochemical sensors. An intriguing area of electroanalytical chemistry is the modification of electrodes using polymeric films. Due to their benefits, which include high adhesion to the electrode surface, chemical stability of the coating, superior selectivity, sensitivity, and homogeneity in electrochemical deposition, polymer-modified electrodes have attracted a great deal of interest in the electroanalytical sector. Conducting polymers are an important material for sensing devices because of their fascinating features, which include high mechanical flexibility, electrical conductivity, and the capacity to be electrochemically converted between electronically insulating and conducting states. Tannin or lignin nanomaterials can be an inter-linker leading to flexible and functional polymeric networks. There is a continuing demand for fast and simple analytical methods for the determination of many clinically important biomarkers, food additives, environmental pollutants etc. This review in a comprehensive way summarizes and discusses the various metal oxide and sulfide-incorporated tannin and lignin scaffolds using electrochemical sensing and biosensing.

The rapid detection of methyl tert-butyl ether (MtBE) in water using a prototype gas sensor system.

The gasoline additive Methyl-tertiary-Butyl Ether (MtBE) is the second most common contaminant of groundwater in the USA and represents an important soil contaminant. This compound has been detected in the groundwater in at least 27 states as a result of leaking underground storage facilities (gasoline storage tanks and pipelines). Since the health effects of MtBE are unclear the potential threat to drinking water supplies is serious. Therefore, the ability to detect MtBE at low levels (ppb) and on-line at high-risk groundwater sites would be highly desirable. This paper reports the use of 'commercial' and metal oxide sensor arrays for the detection of MtBE in drinking and surface waters at low ppb level (microg.L(-1) range). The output responses from some of the sensors were found to correlate well with MtBE concentrations under laboratory conditions.