Synthesis and investigation of novel boron- and magnesium-doped YAG:Ce and LuAG:Ce phosphor ceramics.

YAG:Ce and LuAG:Ce ceramics are widely used as scintillator materials that convert high-energy radiation into visible light. For the practical application of such compounds, short decay times are a necessity. One way of shortening the existing decay times even more is to change the local environment of emitting ions by means of doping the matrix with additional elements, for example, boron or magnesium. Furthermore, boron ions also can help absorb gamma rays more efficiently, therefore improving overall applicability. Due to the aforementioned reasons, YAG and LuAG ceramics doped with cerium, boron, and magnesium were synthesized. Initial amorphous powders have been obtained by means of sol-gel synthesis and pressed into pellets under isostatic pressure and finally calcinated to form crystalline ceramics. The effects of boron and magnesium doping on the morphological, structural, and luminescence properties were investigated. The key results showed that doping with boron has indeed shortened the decay times of the garnet pellets. Overall, boron doping of ceramics is a relatively new research area; however, it is rather promising as it helps both to improve the luminescence properties and to increase particle growth rate.

Synthesis and Investigation of Novel Optical Active SiO2 Glasses with Entrapped YAG:Ce Synthesized via Sol-Gel Method.

We present a crack-free optically active SiO2 glass-composite material containing YAG:Ce synthesized via a modified sol-gel technique. A glass-composite material consisting of yttrium aluminum garnet doped with Ce3+ (YAG:Ce) was entrapped into a SiO2 xerogel. This composite material was prepared using a sol-gel technique with modified gelation and a drying process to obtain crack-free optically active SiO2 glass. The concentration of the YAG:Ce was from 0.5 to 2.0 wt%. All synthesized samples were characterized via X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques, confirming their exceptional quality and structural integrity. The luminescence properties of the obtained materials were studied. Overall, the prepared samples' excellent structural and optical quality makes them great candidates for further investigation, or even potential practical application. Furthermore, boron-doped YAG:Ce glass was synthesized for the first time.

Enhanced optical properties of yttrium aluminum garnet with the yttrium vanadate impurity phase.

Yttrium aluminum garnet doped with europium with an additional impurity phase of yttrium vanadate doped europium has been prepared in different ways: synthesized by a sol-gel route and mechanically mixed in a mortar. The obtained samples were characterized by X-ray diffraction analysis, and scanning electron microscopy. Photoluminescence spectra were recorded to understand the role of the impurity phase in the garnet's optical properties. The impurity phase showed a significant contribution to the optical properties of Y3Al5O12:1%Eu.