Influence of graphene oxide on rheology, mechanical, dielectric, and triboelectric properties of poly(vinyl alcohol) nanocomposite hydrogels prepared via a facile one step process.

The present investigation aims to develop hydrogels with higher mechanical stability for triboelectric applications by adopting a simple method to fabricate a graphene oxide (GO) incorporated poly(vinyl alcohol) (PVA) nanocomposite hydrogel. Instead of the traditional repeated freeze-thaw method, high-shear solution mixing followed by solvent exchange with deionized water was adopted. Morphological observations showed dense and undulated microstructures in the nanocomposite hydrogel with increased GO concentration. Attenuated Total Reflection Fourier Transform Infrared spectroscopy confirmed a higher degree of intermolecular H-bonding between the hydroxyl group of PVA and oxygenated groups of GO, which leads to a robust gel formation. The formation of a robust PVA/GO nanocomposite hydrogel was examined through rheological investigations at room temperature. Nanoindentation analysis estimated a significant increase in hardness and Young's modulus of the nanocomposite hydrogels. Broadband dielectric spectroscopy showed the variation of the dielectric properties of the PVA/GO nanocomposite hydrogels with increased GO concentration. The PVA/GO nanocomposite hydrogels exhibited a maximum output voltage of 3.65 V at 0.075 wt% GO content during finger tapping experiment suggesting the potential for triboelectric applications. The extensive analysis demonstrates the influence of a very low concentration of GO on the variation of the morphology, rheology, mechanical, dielectric, and triboelectric properties of PVA/GO nanocomposite hydrogels.

Fast Transport of Water Droplets over a Thermo-Switchable Surface Using Rewritable Wettability Gradient.

In spite of the reported temperature dependent tunability in wettability of poly(N-isopropylacrylamide) (PNIPAAm) surfaces for below and above lower critical solution temperature (32 °C), the transport of water droplets is inhibited by the large contact angle hysteresis. Herein, for the first time, we report on-demand, fast, and reconfigurable droplet manipulation over a PNIPAAm grafted structured polymer surface using temperature-induced wettability gradient. Our study reveals that the PNIPAAm grafted on intrinsically superhydrophobic surfaces exhibit hydrophilic nature with high contact angle hysteresis below 30 °C and superhydrophobic nature with ultralow contact angle hysteresis above 36 °C. The transition region between 30 and 36 °C is characterized by a large change in water contact angle (∼100°) with a concomitant change in contact angle hysteresis. By utilizing this "transport zone" wherein driving forces overcome the frictional forces, we demonstrate macroscopic transport of water drops with a maximum transport velocity of approximately 40 cm/s. The theoretical calculations on the force measurements concur with dominating behavior of driving forces across the transport zone. The tunability in transport velocity by varying the temperature gradient along the surface or the inclination angle of the surface (maximum angle of 15° with a reduced velocity 0.4 mm/s) is also elucidated. In addition, as a practical application, coalescence of water droplets is demonstrated by using the temperature controlled wettability gradient. The presented results are expected to provide new insights on the design and fabrication of smart multifunctional surfaces for applications such as biochemical analysis, self-cleaning, and microfluidics.