Interstitial decoration of Ag linking 3D Cu2O octahedron and 2D CaWO4 for augmented visible light active photocatalytic degradation of rifampicin and genotoxicity studies.

A morphological oriented highly active Cu2O-Ag-CaWO4 (CAC) nano-heterojunction was fabricated for the visible light driven degradation of rifampicin (RFP). Octahedron shaped Cu2O being a base material, where the Tagetes shaped CaWO4 and Ag were embedded on it. The shape-controlled morphology of Cu2O and CaWO4 as well as Ag decoration influence high degree of adsorption of RFP and interfacial charge transfer between the nano-heterojunction. Further, the larger specific surface area (129.531 m2/g) and narrow band gap energy (2.57 eV) of CAC nano-heterojunction than the controls support the statement. Positively, CAC nano-heterojunction following Z-scheme-type charge transport mechanism attained 96% of RFP degradation within 100 min. O2•- and •OH are the primarily involved reactive oxidation species (ROS) during the photocatalytic reactions, determined by scavenger study and ESR analysis. The stability and reusability of the CAC nano-heterojunction was assessed through performing cyclic experiment of RFP degradation and it holds 96.8% of degradation even after 6th cycle. The stability of CAC nano-heterojunction after photodegradation was further confirmed based on crystalline pattern (XRD analysis) and compositional states (XPS analysis). Intermediates formed during RFP degradation and its toxicity was discovered by using GC-MS/MS and ECOSAR analysis respectively. The end-product toxicity against bacterial system and genotoxicity of CAC nano-heterojunction against Allium cepa were evaluated and the results were seemed to have no negative causes for the aquatic lives.

Construction of p-n-p nano heterojunction through coupling La2O3, (BiO)2CO3 and Ag3PO4 for effective photocatalytic degradation of doxycycline: Insights into mechanism, pathway and intermediate toxicity evaluation.

The present work is centred around the development of La2O3/(BiO)2CO3/Ag3PO4 (LBA), a p-n-p nano-heterojunction to photodegrade doxycycline under visible light irradiation. Here, ultrasonication assisted co-precipitation method was employed to synthesize the photocatalyst. The photocatalyst was characterized using different analysis such as SEM, TEM, elemental mapping, XRD, XPS, FTIR, Raman, BET, DRS, PL and EIS which confirmed the successful fabrication of LBA and their excellent ability to refrain the e-/h+ recombination owing to the construction of the heterojunction. LBA was found to degrade DOX by 91.75 % with the high mineralization of 87.23%. The impact of the reaction parameters influencing the photodegradation process including the concentration of the NCs and DOX, pH and the influence of the commonly present anions were studied. The stability and reusability of the LBA was assessed through subjecting it to four cycles of photodegradation of DOX. In addition, the recovered LBA was characterized through XPS and XRD analysis to confirm the particles stability and reusability. The active participation of the photogenerated charges and the reactive oxygen species were identified through the scavenging assay and ESR analysis. Further, GC-MS/MS analysis was performed to put forward a plausible photodegradation pathway. The toxicity of the end products as well as the intermediates was predicted through ECOSAR software.

Congregating Ag into γ-Bi2O3 coupled with CoFe2O4 for enhanced visible light photocatalytic degradation of ciprofloxacin, Cr(VI) reduction and genotoxicity studies.

The work attempts to construct a highly effective γ-Bi2O3/CoFe2O4/Ag visible active photocatalyst for the enhanced degradation of ciprofloxacin (CIP) and Cr(VI) reduction. γ-Bi2O3/CoFe2O4/Ag photocatalyst was prepared by simple solid phase and co-precipitation methods. The nanosphere shaped CoFe2O4 photocatalyst are embedded on top of γ-Bi2O3 nanotriangle. The addition of Ag into γ-Bi2O3/CoFe2O4 heterojunction primitively facilitates the photocatalytic activity in higher rate. The quantitative analysis of photocatalyst possesses to have lower e-/h+ recombination rate compared to its counterparts. The prepared γ-Bi2O3/CoFe2O4/Ag photocatalyst showed 96.6% degradation of CIP in 220 min and 99.2% reduction of Cr(VI) in 120 min. Additionally, γ-Bi2O3/CoFe2O4/Ag showed outstanding recyclability and long-term stability with a degradation efficiency of 96.5% even after six cycles. The intermediate products formed were identified and the degradation pathway was elucidated by gas chromatography-mass spectrometry analysis. Total organic carbon measurement was carried over to assess the efficiency of complete degradation and the removal percentage was found to be 98%. The end product toxicity study towards bacteria was proven to have less toxicity level when compared to parent compound. Lastly, the genotoxicity of γ-Bi2O3/CoFe2O4/Ag photocatalyst was tested in Allium cepa and the results confirmed to have no cause of toxicity impacts. Overall, the work not only tends to provide a highly visible active γ-Bi2O3/CoFe2O4/Ag photocatalyst, but also attributes to have no further negative imprints in the environment.

Double Z-Scheme ZnCo2O4/MnO2/FeS2 photocatalyst with enhanced photodegradation of organic compound: Insights into mechanisms, kinetics, pathway and toxicity studies.

The present work highlights the preparation of double Z-scheme ZnCo2O4/MnO2/FeS2 nanocomposite (NCs) and investigated its photocatalytic activity against methyl orange (MO) dye degradation under visible light. An array of techniques was carried out to characterize the nanoparticles (NPs) in order to evaluate their morphological, structural, optical, and photocatalytic properties using FE-SEM, TEM, XRD, N2 adsorption and desorption studies, PL, UV-visible spectrophotometer, XPS, Raman, and UV-vis DRS analysis. The degradation efficiency of NCs was tested along with different parameter studies such as different pH, NCs concentration, dye concentration, reusability and structural stability. The NCs exhibited complete photodegradation of MO dye under visible light within 80 min at pH 4. The structural and compositional stability of the prepared NCs over 6 consecutive cycles was tested via XRD and XPS analysis. The results of active species trapping experiments showed that O2-• and OH• are responsible for the degradation of MO dye. The TOC analysis showed 95% of mineralization by the prepared NCs. The MO dye degradation pathway was determined using GC-MS/MS analysis and drafted all the intermediates involved. End product toxicity via seed germination and intermediate toxicity study using ECOSAR software results in less toxicity of end product compared to parent compound. Finally, the genotoxicity of the prepared NCs was evaluated using Allium cepa and showed its no causes of cytotoxicity & genotoxicity by the prepared NCs. ZnCo2O4/MnO2/FeS2 NCs exhibited its high photocatalytic activity and the toxicity studies confirms that there is no cause of any environmental impact.

A prominent dual heterojunction framed CuWO4/Bi2WO6/MnS ternary NCs for para-chlorophenol degradation, Cr(VI) reduction & toxicity studies.

In account of environmental remediation, an ideal photocatalyst was fabricated for the effective treatment of water systems. Herein, dual heterojunctions framed CuWO4/Bi2WO6/MnS nanocomposite (NCs) was synthesized via simple co-precipitation method followed by ultra-sonicated assisted route. The prepared NCs were investigated its photocatalytic degradation performance using para-chlorophenol (4-CP) and reduction of chromium VI (Cr (VI)) under visible light irradiation. The photocatalyst were characterized by various analytical techniques including XRD, HR-TEM, XPS, UV-vis DRS, FE-SEM, EIS, PL, ESR, Raman and N2 adsorption and desorption studies. The excellent photodegradation of 4-CP was observed within 180 min by the NCs. Similarly, the Cr (VI) reduction was about 97% within 140 min. The effect of pH and influence of different dosage of NCs and 4-CP on the photodegradation efficiency was investigated. The reusability and stability of the NCs was examined over 6 consecutive runs where the XRD and XPS confirm the structural stability of the prepared NCs. The scavenging experiment were carried out to elucidate the mechanism and the active species involved were O2-• and OH• radicals. The TOC analysis affirmed the complete mineralization of the prepared NCs. The ecotoxicity analysis was carried out to determine the toxicity effect of intermediates using ECOSAR software and the end product toxicity was also evaluated against E. coli and S. epidermis. The end product toxicity study also confirmed that the degraded product was less toxic compared to parent compound. Further, the genotoxicity study was done to understand the environmental impact using allium cepa and results confirms that there are no causes of cytotoxicity & genotoxicity by the prepared NCs. Therefore, the prepared NCs can be economical, efficient with excellent photocatalytic performance and environment friendly.

Recent advances in degradation of organic pollutant in aqueous solutions using bismuth based photocatalysts: A review.

Today, a major concern associated with the environment is the water pollution occurred due to the introduction of variety of persistent organic pollutants and residual dyes from different sources (e.g., dye and dye intermediates industries, paper and pulp industries, textile industries, tannery and craft bleaching industries, pharmaceutical industries, etc.) into our natural water resources. Recently, advanced oxidation processes (AOPs) by photocatalyst have garnered great attention as a new frontier promising eco-friendly and sustainable wastewater treatment technology. Utilization of the photocatalytic technology efficiently is significant for cleaner environment. Bismuth based photocatalyst have aroused widespread attention as a visible light responsive photocatalyst for waste water treatment due to their non-toxicity, low cost, modifiable morphology, and outstanding optical and chemical properties. In this review, we have dealt with the research progress on bismuth-based photocatalysts for waste water treatment. However, it seems to give limitation over pristine photocatalysts such as slow migration of charge carriers, charge carrier recombination, low visible light absorption, etc., Various bismuth based photocatalyst and its modifications via doping, heterojunction, Z-scheme etc., are discussed in detail. Further, the strategies adopted to improve the photocatalytic activity of bismuth based photocatalyst to improve the waste water treatment (mostly drugs and dyes) are critically reviewed. Also, we have discussed the bacterial inactivation by bismuth based photocatalyst. Finally, the challenges and future aspects against bismuth based photocatalyst are explored for further research.