Sustainable biofuel synthesis from non-edible oils: a mesoporous ZSM-5/Ni/Pt catalyst approach.

This work examines the hydrodeoxygenation (HDO) activity of non-edible oils using a high surface area catalyst. The HDO activity was thoroughly examined and contrasted using the high surface area catalyst Ni/Pt-ZSM-5 as well as other supports like MCM-48 and H-beta. Ni/Pt bimetals supported on mesoporous ZSM-5 were created via reverse order impregnation to facilitate HDO of non-edible oils. Techniques such as XRD, FT-IR, BET, HR-TEM, HR-SEM, TPD, and TGA were used to characterize the produced catalysts. The synthesized catalysts considerably influenced the hydrodeoxygenation activities for the synthesis of lengthy chain hydrocarbons in a stainless-steel reactor with a high-pressure fixed bed between 300 and 375 °C under 10-40 bar hydrogen pressure. High levels of Ni/Pt-ZSM-5 acidity, textural, and H2 consumption qualities were discovered. Distributions of the products were also reviewed, along with comparisons of the structure-activity connections.

Value stream mapping for identification and assessment of material waste in construction: A case study.

Construction sites are plagued with numerous problems, such as improper planning and management, high amounts of waste generation and low awareness of waste reduction. Construction and demolition waste literature provides several best practises and prescriptive strategies that help minimise waste during construction. However, it lacks in the systematic identification and minimisation approach of all possibilities of waste. Therefore, studies focusing on principles and tools that help systematically analyse the inefficiencies of on-site processes leading to waste generation and philosophies addressing waste minimisation are necessary. As eliminating waste is one of the key lean principles, this article discusses the need and importance of integrating the lean construction with the construction and demolition waste management. This article aims to estimate and assess the causes of waste generation in a high-rise building construction through a case study in Chennai city (India) using value stream mapping, a key lean construction tool. Onsite monitoring and measurement were performed to quantify the amount of waste generated. A waste generation rate of 66.26 kg m-2 was identified, of which concrete, cement mortar and brick waste represented almost 90% of the total construction waste. Direct observation and interviews of site personnel were conducted to understand the causes of waste generation. A strategic framework has been proposed to improve construction and demolition waste minimisation depicting the synergy of combining lean construction principles with construction and demolition waste management strategies. The proposed framework helps in the systematic identification, assessment and minimisation of on-site construction waste generation.

Nocardia farcinica pleuritis in a lepromatous patient with severe necrotizing reaction: an unusual presentation.

A young, male, lepromatous leprosy patient with a severe necrotizing erythema nodosum leprosum reaction treated with prolonged oral steroids and thalidomide developed pleuritis that was caused by a rare opportunistic pathogen, Nocardia farcinica. This organism was resistant to most antibiotics but was susceptible to amikacin and minocycline. During the course of treatment the patient developed severe gastritis which necessitated the removal of clofazimine and the inclusion of an H2 receptor antagonist. Bilateral steroid-induced cataracts needed surgical correction. This case is being presented for its rare opportunistic bacterial infection and for the multiple complications which made treatment difficult.