Heavy metal analysis of water and sediments of the Kaptai Lake in Bangladesh: Contamination and concomitant health risk assessment.

In this study, concentrations of 9 heavy metals (Cr, Fe, Co, Ni, Cu, Zn, As, Cd, and Pb) in water and sediments of the Kaptai Lake were determined by neutron activation analysis and atomic absorption spectrometry techniques to study their distribution and contamination in the lake. Average concentrations of Cr and Co in sediments, and Fe and Pb in water were higher than those of some international guideline values. Different environmental pollution indexes (individual and synergistic) suggested that the sediments of Kaptai Lake are minorly enriched by As and Zn, and have low severity of contamination at most of the sampling sites. For residential receptors exposed to the heavy metals in lake water, both non-carcinogenic and carcinogenic hazards were assessed which indicated that there is no carcinogenic risk for As while Cr shows a slightly carcinogenic risk. Moreover, estimated potential ecological risks and different SQGs suggested low ecotoxicological risks in the sediments of Kaptai Lake. Multivariate statistical analyses revealed the correlation among the studied heavy metals and indicated that the origin of most of the metals is mainly lithogenic and a small number of metals (Cu and Pb) from anthropogenic sources. The results of this study will be helpful in developing a pollution control strategy for the lake.

Fractionation of environmental radioactivity in road dust from a megacity: external and internal health risks.

Naturally occurring radioactive materials (NORMs: 232Th, 226Ra, 40K) can reach our respiratory system by breathing of road dust which can cause severe health risks. Targeting the pioneering consideration of health risks from the NORMs in road dust, this work reveals the radioactivity abundances of NORMs in road dust from a megacity (Dhaka) of a developing country (Bangladesh). Bulk chemical compositions of U, Th, and K obtained from neutron activation analysis were converted to the equivalent radioactivities. Radioactivity concentrations of 226Ra, 232Th, and 40K in road dust ranged from 60-106, 110-159, and 488-709 Bq kg-1 with an average of 84.4 ± 13.1, 126 ± 11, and 549 ± 48 Bq kg-1, respectively. Estimated 226Ra, 232Th, and 40K radioactivities were, respectively, 1.7-3.0-, 3.7-5.3-, and 1.2-1.8-folds greater than the affiliated world average values. Mechanistic pathway of NORMs' enrichment and fractionation relative to the major origin (pedosphere) were evaluated concerning the water logging, relative solubility-controlled leaching and translocation, climatic conditions, and aerodynamic fractionations (dry and wet atmospheric depositions). Computation of customary radiological risk indices invokes health risks. Noticing the ingress of NOMR-holding dust into the human respiratory system along with the associated ionizing radiations, the computed radiological indices represent only the least probable health hazards. Nevertheless, in real situations, α-particles from the radioactive decay products of 232Th and 238U can create acute radiation damages of respiratory system. Policymakers should emphasize on limiting the dust particle evolution, and public awareness is required to alleviate the health risks.

Natural and anthropogenic contributions to the elemental compositions and subsequent ecological consequences of a transboundary river's sediments (Punarbhaba, Bangladesh).

An anthropogenically less affected transboundary river (Punarbhaba, Bangladesh) was studied to detect associated risks from the combined origin(s) of geochemically and toxicologically significant elements in benthic sediments. A total of 30 river bed sediments were analyzed by instrumental neutron activation analysis targeting the 15 chemical elements viz., Na, Al, K, Ti, Cr, Mn, Co, Zn, As, Rb, Sb, Cs, Ba, Th, and U. Among the estimated elements, the mean abundances (µg/g) of Rb (136), Sb (0.66), Cs (6.66), Th (14.6), and U (3.92) were 1.4-1.7 times higher than the crustal origin. These elements are primarily responsible for the contaminated state of the Punarbhaba River. The studied area is 'moderately polluted' (Igeo: 2.01 to 0.02) and possesses 'minor enrichment' (EF: 1.98 to 0.48) in terms of the measured elements. The output of statistical analyses projected that the studied elements are geochemically fractionated in an oxidizing environment (U/Th = 0.44) and mostly originated from felsic sources, thus confirming the mineral is comprised of aluminosilicates and alkali feldspar. However, SQGs-based and ecological risk indices invoked minor (Cr: 6.67%) to no potential ecotoxicological threats for Cr, Mn, Co, Zn, As, and Sb. Nonetheless, altered distribution patterns caused by geogenic activities increased Cr and Zn in the environment which may cause toxicity (Cr: 22-53%, Zn: 35-70%), and pose potential ecological risks, specifically in upstream locations (P-2, P-3, P-5). Further, this study broadened the perspective of sediment deposition from fractionation, fluvial transportation, and weathering events beyond the industrial disintegration of elements, which will aid researchers and policymakers to comprehend combined risks from suspended sediments.

Reconciling the geogenic and non-crustal origins of elements in an Indo-Bangla transboundary river, Atrai: Pollution status, sediment quality, and preliminary risk assessment.

This study has been conducted on an anthropogenically less influenced transboundary river (Atrai: Indo-Bangladesh) to comprehend the inherent geochemistry and identify potential elemental sources. In doing so, across the Bangladeshi portion, 30 river-bed samples were culled and studied by neutron activation analysis to quantify the abundances of 15 geochemically and toxicologically significant elementals (Na, Al, K, Ti, Cr, Mn, Co, Zn, As, Rb, Sb, Cs, Ba, Th, and U). The results revealed that the mean concentrations (µg/g) of Rb (154.6), Cs (7.53), Th (20.90), and U (4.88) were 1.5-2.0 times higher than crustal values. Besides, geo-environmental indices revealed 'uncontaminated to moderately contaminated' pollution status with minor enrichment or contamination for Rb, Th, Sb, U, and Cs, relatively concentrated in the mid-to-downstream zone possessed geogenic and non-crustal origins. The positive matrix factorization and other statistical approaches revealed predominant geogenic enrichment of Na, K, Al, Ti, Zn, Cs, Rb, As, Th, and U from differential mineralogical compositions via weathering, elemental fractionations, and biogeochemical mobilization. Contrariwise, several anthropogenic sources (for Cr, Sb, Co, Mn, Th) were also ascertained in the vicinity of Atari River. However, sediment characterization based on SQG threshold values manifested that Cr and Mn possess rare biological effects on local aquatic organisms. Nevertheless, SQGs-based and ecological risk indices invoked minor to no potential ecotoxicological intimidations for the considered metal(oid)s (Cr, Mn, Co, Zn, As, and Sb). Hence, this study manifested the usefulness of a less anthropogenically affected river to reckon geogenic and non-crustal elemental origins in the compounded riverine sediment.

Road dust-driven elemental distribution in megacity Dhaka, Bangladesh: environmental, ecological, and human health risks assessment.

Road dust, which reflects ambient air quality, receives various pollutants including toxic metal(oid)s from several natural and/or anthropogenic sources. This manuscript reports a comprehensive evaluation of the levels of seventeen metal(oid)s in road dust of a megacity (Dhaka, Bangladesh). Different evaluation approaches were implemented including statistical analysis and GIS mapping, besides environmental, ecological, and human health risk indices. From 30 sampling sites, representative samples were collected, which were analyzed by neutron activation analysis. The average concentrations (± SD) of Na, Mg, Al, Sc, Ti, V, Cr, Mn, Fe, Co, Zn, As, Rb, Sb, Cs, Ba, and W were 11,738 ± 560 µg g-1, 12,410 ± 1249 µg g-1, 62,127 ± 5937 µg g-1, 8.89 ± 0.47 µg g-1, 5224 ± 1244 µg g-1, 66 ± 8 µg g-1, 66.7 ± 6.9 µg g-1, 547 ± 110 µg g-1, 25,150 ± 1723 µg g-1, 8.39 ± 0.65 µg g-1, 125 ± 17 µg g-1, 3.63 ± 0.56 µg g-1, 87 ± 9 µg g-1, 0.75 ± 0.28 µg g-1, 4.40 ± 0.48 µg g-1, 397 ± 87 µg g-1, and 3.82 ± 1.77 µg g-1, respectively. The distance-based redundancy analysis showed that the northern region was enriched with Na, Mn, Al, Fe, Zn, and Rb, while the southern region was enriched with Fe, Al, Ti, Cr, and Mg. The GIS mapping shows hot spots of Sc, Cr, Zn, and Cs were observed mostly in heavy traffic areas. Significant positive correlations of Fe-Sc, Al-Mg, V-Mg, V-Al, Cs-Rb, Cs-Sc, Rb-Sc, As-Na, and Cs-Rb invoked their inter-dependency and persistence in road dust. Depending on a set of environmental and ecological index-based calculation, the degree of metal(oid) pollution followed the descending order as W > Sb > Zn > Cr > As > Ti > Sc > V, while no pollution was recorded by Mn, Fe, Al, Rb, Cs, Co, and Ba. Importantly, the total hazard index values for adults and children were higher than unity, indicating potential non-carcinogenic health risks from exposure of road dust. Furthermore, the total carcinogenic risks from Cr and As through ingestion and dermal contact exceeded the standard guideline values. The implementation of different evaluation approaches strengthens the findings of metal(oid) source apportionment.

Elemental distribution of metals in urban river sediments near an industrial effluent source.

To study the compositional trends associated with the spatial and layer wise distribution of heavy metals as well as the sediment response towards the untreated chemical wastes, we have analyzed river (Buriganga, Bangladesh) sediments by instrumental neutron activation analysis (INAA) and energy dispersive X-ray fluorescence (EDXRF). In nine sediment samples 27 elements were determined where Na, Al, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Zn, As, Rb, Cs, La, Ce, Sm, Dy, Hf, Th and U were determined by INAA and Cu, Sr, Ba, Hg and Pb were determined by EDXRF. Pollution level and the origin of pollutants were evaluated by the aid of geo-accumulation index (Igeo), enrichment factor (EF), pollution load index (PLI) and the inter-element correlation analysis. Major elements are somehow buffered even though the pollution level is severe while the trace metals seem to be highly responsive. Among the heavy metals, Cr is the dominant pollutant, though the pollution level varies systematically with the sampling depth and the distance from the contamination source. Positive linear correlation between Cr and Zn (0.94) ensures the similar anthropogenic source(s) for these two metals, but the sediments of this study respond differently depending upon their geochemical behavior. Rare earth elements (here La, Ce, Sm and Dy), Th and U seem to have crustal origin and the Th/U ratio varies from 2.58 to 4.96.