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1.
Artigo em Inglês | MEDLINE | ID: mdl-38090871

RESUMO

Data-dependent hashing methods aim to learn hash functions from the pairwise or triplet relationships among the data, which often lead to low efficiency and low collision rate by only capturing the local distribution of the data. To solve the limitation, we propose central similarity, in which the hash codes of similar data pairs are encouraged to approach a common center and those of dissimilar pairs to converge to different centers. As a new global similarity metric, central similarity can improve the efficiency and retrieval accuracy of hash learning. By introducing a new concept, hash centers, we principally formulate the computation of the proposed central similarity metric, in which the hash centers refer to a set of points scattered in the Hamming space with a sufficient mutual distance between each other. To construct well-separated hash centers, we provide two efficient methods: 1) leveraging the Hadamard matrix and Bernoulli distributions to generate data-independent hash centers and 2) learning data-dependent hash centers from data representations. Based on the proposed similarity metric and hash centers, we propose central similarity quantization (CSQ) that optimizes the central similarity between data points with respect to their hash centers instead of optimizing the local similarity to generate a high-quality deep hash function. We also further improve the CSQ with data-dependent hash centers, dubbed as CSQ with learnable center (CSQ [Formula: see text] ). The proposed CSQ and CSQ [Formula: see text] are generic and applicable to image and video hashing scenarios. We conduct extensive experiments on large-scale image and video retrieval tasks, and the proposed CSQ yields noticeably boosted retrieval performance, i.e., 3%-20% in mean average precision (mAP) over the previous state-of-the-art methods, which also demonstrates that our methods can generate cohesive hash codes for similar data pairs and dispersed hash codes for dissimilar pairs.

2.
Polymers (Basel) ; 14(22)2022 Nov 10.
Artigo em Inglês | MEDLINE | ID: mdl-36432970

RESUMO

Airborne sound absorption in porous materials involves complex mechanisms of converting mechanical acoustic energy into heat. In this work, the effective piezoelectric properties of polyethylene ferroelectret foams on sound absorption were investigated by comparable samples with and without the piezoelectric response. Corona poling and thermal annealing treatments were applied to the samples in order to enable and remove the piezoelectric property, respectively, while the microstructure and the mechanical properties remained substantially unchanged. The effective piezoelectric properties and airborne sound absorption coefficients of the polyethylene foam samples before and after material treatments were measured and analyzed. Our experimental results and theoretical analysis showed that the open-cell ferroelectret polymer foam with an effective piezoelectric property provides an additional electromechanical energy conversion mechanism to enhance the airborne acoustic absorption performance.

3.
Artigo em Inglês | MEDLINE | ID: mdl-29505412

RESUMO

Piezoelectric materials are vital in determining ultrasonic transducer and imaging performance as they offer the function for conversion between mechanical and electrical energy. Ultrasonic transducers with high-frequency operation suffer from performance degradation and fabrication difficulty of the demanded piezoelectric materials. Hence, we propose 1-D polymeric piezoelectric nanostructure with controlled nanoscale features to overcome the technical limitations of high-frequency ultrasonic transducers. For the first time, we demonstrate the integration of a well-aligned piezoelectric nanotube array to produce a high-frequency ultrasonic transducer with outstanding performance. We find that nanoconfinement-induced polarization orientation and unique nanotube structure lead to significantly improved piezoelectric and ultrasonic transducing performance over the conventional piezoelectric thin film. A large bandwidth, 126% (-6 dB), is achieved at high center frequency, 108 MHz. Transmission sensitivity of nanotube array is found to be 46% higher than that of the monolithic thin film transducer attributed to the improved electromechanical coupling effectiveness and impedance match. We further demonstrate high-resolution scanning, ultrasonic imaging, and photoacoustic imaging using the obtained nanotube array transducers, which is valuable for biomedical imaging applications in the future.

4.
Artigo em Inglês | MEDLINE | ID: mdl-28880167

RESUMO

This paper starts from a review on the progress in fabrication of piezoelectric ceramic coatings by thermal spray method. For our experimental work, two types of lead-free piezoelectric ceramic coatings, including potassium-sodium niobate-based and bismuth sodium titanate-based, are fabricated by thermal spray process, and their structure, morphology, and piezoelectric properties are characterized. Our obtained lead-free ceramic coatings exhibit single phase of perovskite structure, relatively dense morphology, and competitive piezoelectric coefficients. The mechanism of forming the piezoelectric perovskite crystalline phase by thermal spray involving melting-recrystallization process is analyzed in comparison to that of ceramic synthesis through solid-state reaction. Suppression of volatile loss and decomposition at high temperature due to the extremely high melting and cooling rate in the thermal spray process, and the impact on the resulting structure are discussed. Significant advantages of the thermal spray method over alternative processing methods for forming piezoelectric ceramic coatings are summarized. The combination of environmentally friendly lead-free compositions and the scalable thermal spray processing method will promote more applications of piezoelectric ceramic coatings for producing distributive sensors and transducers, and forming advanced smart structures and systems.

5.
Med Biol Eng Comput ; 55(4): 673-684, 2017 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-27423438

RESUMO

In multi-body models of scoliotic spine, personalization of mechanical properties of joints significantly improves reconstruction of the spine shape. In personalization methods based on lateral bending test, simulation of bending positions is an essential step. To simulate, a force is exerted on the spine model in the erect position. The line of action of the force affects the moment of the force about the joints and thus, if not correctly identified, causes over/underestimation of mechanical properties. Therefore, we aimed to identify the line of action, which has got little attention in previous studies. An in-depth analysis was performed on the scoliotic spine movement from the erect to four spine positions in the frontal plane by using pre-operative X-rays of 18 adolescent idiopathic scoliosis (AIS) patients. To study the movement, the spine curvature was considered as a 2D chain of micro-scale motion segments (MMSs) comprising rigid links and 1-degree-of-freedom (DOF) rotary joints. It was found that two MMSs representing the inflection points of the erect spine had almost no rotation (0.0028° ± 0.0021°) in the movement. The small rotation can be justified by weak moment of the force about these MMSs due to very small moment arm. Therefore, in the frontal plane, the line of action of the force to simulate the left/right bending position was defined as the line that passes through these MMSs in the left/right bending position. Through personalization of a 3D spine model for our patients, we demonstrated that our line of action could result in good estimates of the spine shape in the bending positions and other positions not included in the personalization, supporting our proposed line of action.


Assuntos
Processamento de Imagem Assistida por Computador/métodos , Escoliose/diagnóstico por imagem , Escoliose/fisiopatologia , Coluna Vertebral/fisiopatologia , Adolescente , Fenômenos Biomecânicos , Criança , Feminino , Humanos , Masculino , Modelos Teóricos , Movimento , Postura , Medicina de Precisão/métodos , Radiografia , Reprodutibilidade dos Testes , Rotação , Coluna Vertebral/diagnóstico por imagem , Coluna Vertebral/fisiologia , Adulto Jovem
6.
Sci Rep ; 6: 22253, 2016 Feb 24.
Artigo em Inglês | MEDLINE | ID: mdl-26905285

RESUMO

Triboelectric nanogenerators (TENGs) have emerged as a potential solution for mechanical energy harvesting over conventional mechanisms such as piezoelectric and electromagnetic, due to easy fabrication, high efficiency and wider choice of materials. Traditional fabrication techniques used to realize TENGs involve plasma etching, soft lithography and nanoparticle deposition for higher performance. But lack of truly scalable fabrication processes still remains a critical challenge and bottleneck in the path of bringing TENGs to commercial production. In this paper, we demonstrate fabrication of large scale triboelectric nanogenerator (LS-TENG) using roll-to-roll ultraviolet embossing to pattern polyethylene terephthalate sheets. These LS-TENGs can be used to harvest energy from human motion and vehicle motion from embedded devices in floors and roads, respectively. LS-TENG generated a power density of 62.5 mW m(-2). Using roll-to-roll processing technique, we also demonstrate a large scale triboelectric pressure sensor array with pressure detection sensitivity of 1.33 V kPa(-1). The large scale pressure sensor array has applications in self-powered motion tracking, posture monitoring and electronic skin applications. This work demonstrates scalable fabrication of TENGs and self-powered pressure sensor arrays, which will lead to extremely low cost and bring them closer to commercial production.

7.
Sci Rep ; 5: 9790, 2015 May 12.
Artigo em Inglês | MEDLINE | ID: mdl-25966301

RESUMO

Vertically aligned piezoelectric P(VDF-TrFE) nanotube array comprising nanotubes embedded in anodized alumina membrane matrix without entanglement has been fabricated. It is found that the crystallographic polar axes of the P(VDF-TrFE) nanotubes are oriented along the nanotubes long axes. Such a desired crystal orientation is due to the kinetic selection mechanism for lamellae growth confined in the nanopores. The preferred crystal orientation in nanotubes leads to huge piezoelectric coefficients of the P(VDF-TrFE). The piezoelectric strain and voltage coefficients of P(VDF-TrFE) nanotube array are observed to be 1.97 and 3.40 times of those for conventional spin coated film. Such a significant performance enhancement is attributed to the well-controlled polarization orientation, the elimination of the substrate constraint, and the low dielectric constant of the nanotube array. The P(VDF-TrFE) nanotube array exhibiting the unique structure and outstanding piezoelectric performance is promising for wide applications, including various electrical devices and electromechanical sensors and transducers.

8.
Phys Chem Chem Phys ; 15(2): 515-20, 2013 Jan 14.
Artigo em Inglês | MEDLINE | ID: mdl-23171985

RESUMO

Poly(vinylidene-fluoride-co-trifluoroethylene) (P(VDF-TrFE)) ferroelectric nanotube arrays were fabricated using an anodized alumina membrane (AAM) as a template and silver electrodes were deposited on both the outer and inner sides of the nanotubes by an electroless plating method. The nanotubes have the unique structure of being sealed at one end and linked at the open end, thus preventing electrical shorting between the inner and outer electrodes. Compared with a P(VDF-TrFE) film with a similar overall thickness, the idealized nanotube array has a theoretical capacitance that is 763 times larger due to the greatly enlarged contact area between the electrodes and the polymer dielectric. A capacitance that is 95 times larger has been demonstrated experimentally, thus indicating that such nanotube arrays are promising for realizing high density capacitance and high power dielectric energy storage.

9.
Artigo em Inglês | MEDLINE | ID: mdl-21937333

RESUMO

Although batteries possess high energy storage density, their output power is limited by the slow movement of charge carriers, and thus capacitors are often required to deliver high power output. Dielectric capacitors have high power density with fast discharge rate, but their energy density is typically much lower than electrochemical supercapacitors. Increasing the energy density of dielectric materials is highly desired to extend their applications in many emerging power system applications. In this paper, we review the mechanisms and major characteristics of electric energy storage with electrochemical supercapacitors and dielectric capacitors. Three types of in-house-produced ferroic nonlinear dielectric thin film materials with high energy density are described, including (Pb(0.97)La(0.02))(Zr(0.90)Sn(0.05)Ti(0.05))O(3) (PLZST) antiferroelectric ceramic thin films, Pb(Zn(1/3)Nb(2/3))O(3-)Pb(Mg(1/3)Nb(2/3))O(3-)PbTiO(3) (PZN-PMN-PT) relaxor ferroelectric ceramic thin films, and poly(vinylidene fluoride) (PVDF)-based polymer blend thin films. The results showed that these thin film materials are promising for electric storage with outstandingly high power density and fairly high energy density, comparable with electrochemical supercapacitors.

10.
Age (Dordr) ; 33(3): 229-46, 2011 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-20730501

RESUMO

Thymic involution and shrinkage of secondary lymphoid organs are leading causes of the deterioration of the T-cell compartment with age. Inflamm-aging, a sustained inflammatory status, has been associated with chronic diseases and shortened longevity. This is the first study to investigate the effect of treating aging hybrid mice with long-term, low-dose resveratrol (RSV) in drinking water by assessing multiple immunological markers and profiles in the immune system. We found that hybrid mice exhibited marked age-related changes in the CD3+CD4+, C3+CD8+, CD4+CD25+, CD4M and CD8M surface markers. RSV reversed surface phenotypes of old mice to that of young mice by maintaining the CD4+ and CD8+ population in splenocytes as well as reducing CD8+CD44+ (CD8M) cells in the aged. RSV also enhanced the CD4+CD25+ population in old mice. Interestingly, pro-inflammatory status in young mice was transiently elevated by RSV but it consequently mitigated the age-dependent increased pro-inflammatory cytokine profile while preserving the anti-inflammatory cytokine condition in the old mice. Age-dependent increase in 8OHdG, an oxidative DNA damage marker was ameliorated by RSV. Immunological-focused microarray gene expression analysis showed that only the CD72 gene was significantly downregulated in the 12-month RSV-treated mice compared to age-matched controls. Our study indicates that RSV even at low physiological relevant levels is able to affect the immune system without causing marked gene expression changes.


Assuntos
Envelhecimento/efeitos dos fármacos , Antioxidantes/farmacologia , Citocinas/imunologia , Dano ao DNA/efeitos dos fármacos , Estilbenos/farmacologia , Subpopulações de Linfócitos T/imunologia , Envelhecimento/imunologia , Animais , Antígenos de Superfície/imunologia , Contagem de Células , Inflamação/imunologia , Camundongos , Camundongos Endogâmicos , Modelos Animais , Análise de Sequência com Séries de Oligonucleotídeos , Estresse Oxidativo/efeitos dos fármacos , Resveratrol , Baço/imunologia
11.
Free Radic Biol Med ; 46(6): 799-809, 2009 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-19159678

RESUMO

Resveratrol (RSV), a naturally occurring phytoalexin that can be found in red wine, berries, and peanuts, has been shown to extend both mean and maximum life span in model organisms. RSV has also been reported to shift the physiology of middle-aged mice on a high-calorie diet toward that of mice on a standard diet. These beneficial effects of RSV have been suggested to resemble caloric restriction. Our study in F2 four-way cross-hybrid mice was the first to evaluate the effects of aging and long-term RSV treatment (14.09+/-3.4 mg/L in drinking water for 6 or 12 months) on biomarkers of oxidative damage to DNA, 8-hydroxy-2'-deoxyguanosine (8OHdG); lipid, 8-iso-prostaglandin(2 alpha) (8-iso-PGF(2 alpha)); and protein, protein carbonyl content (PCC). There was a significant age-dependent accumulation of oxidative damage to DNA, lipid, and protein as well as a clear increase in urine 8-iso-PGF(2 alpha) levels in the majority of mouse tissues. Rates of age-dependent increases in damage biomarkers varied between tissues. Chronic RSV treatment elevated total RSV plasma levels and reduced the observed age-dependent accumulation of (1) 8OHdG in liver and heart, (2) 8-iso-PGF(2 alpha) in heart and urine, and (3) PCC in liver and kidney. However, a 12-month RSV intake resulted in significant elevation of 8-iso-PGF(2 alpha) and PCC in kidney. Our studies demonstrate that RSV treatment consistently attenuated oxidative damage in tissues where age-related oxidative damage accumulation was prominent, but also suggested that chronic RSV treatment may induce nephrotoxicity.


Assuntos
Biomarcadores/metabolismo , Desoxiguanosina/análogos & derivados , Rim/metabolismo , Prostaglandinas A/metabolismo , Estilbenos/administração & dosagem , 8-Hidroxi-2'-Desoxiguanosina , Administração Oral , Envelhecimento/imunologia , Animais , Cruzamento , Dano ao DNA , Desoxiguanosina/genética , Desoxiguanosina/metabolismo , Rim/imunologia , Rim/patologia , Camundongos , Miocárdio/metabolismo , Miocárdio/patologia , Especificidade de Órgãos , Estresse Oxidativo/imunologia , Prostaglandinas A/genética , Carbonilação Proteica/imunologia , Resveratrol , Estilbenos/efeitos adversos
12.
Free Radic Res ; 40(4): 393-402, 2006 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-16517504

RESUMO

The extent of in vivo oxidative damage has been known to be cumulative over the period of the life of mammals. Our hypothesis is that there should be a positive correlation between the levels of 8-hydroxy-2'-deoxyguanosine (8OHdG) and 8-iso-prostaglandin F(2alpha) (8-iso-PGF(2alpha)) in major rat tissues. We also investigated whether increased level of oxidative stress causes a decrease in the mitochondrial membrane potential of peripheral lymphocytes of old rats using the MitoTracker Red fluorochrome. Our results show positive correlations between 8OHdG and 8-iso-PGF(2alpha) for liver, brain and kidney measured by HPLC-UV-ECD (electrochemical detector) and EIA methods, respectively. However, heart tissues show a negative correlation. The mitochondrial membrane potential of old rat lymphocytes records significant decrease compared with the young lymphocytes. Based on our results, we conclude that in ageing studies, specific tissues need to be examined in order to measure the localised DNA damage and lipid peroxidation as different tissues display different extent of oxidative damage. We believe this approach of using combined markers is useful to verify the true efficacy of health intervention studies in animals and humans. In addition, the isoprostane assay can be further developed looking at lipid peroxidation as a potential marker in ageing studies.


Assuntos
Envelhecimento , Dano ao DNA/fisiologia , Peroxidação de Lipídeos/fisiologia , Potenciais da Membrana/fisiologia , Mitocôndrias/metabolismo , Estresse Oxidativo/fisiologia , 8-Hidroxi-2'-Desoxiguanosina , Envelhecimento/genética , Animais , Cromatografia Líquida de Alta Pressão , Desoxiguanosina/análogos & derivados , Desoxiguanosina/análise , Dinoprosta/análogos & derivados , Dinoprosta/análise , Técnicas Imunoenzimáticas , Linfócitos/metabolismo , Masculino , Ratos , Ratos Endogâmicos F344
13.
Artigo em Inglês | MEDLINE | ID: mdl-12625584

RESUMO

A laser scanning vibrometer (LSV) was used for the first time to measure the piezoelectric coefficient of ferroelectric thin films based on the converse piezoelectric effect. The significant advantages of the use of the LSV for this purpose were demonstrated. Several key points were discussed in order to achieve reliable and accurate results.


Assuntos
Materiais Revestidos Biocompatíveis/química , Interferometria/instrumentação , Lasers , Teste de Materiais/instrumentação , Teste de Materiais/métodos , Vibração , Acústica/instrumentação , Cristalografia/instrumentação , Cristalografia/métodos , Desenho de Equipamento , Interferometria/métodos , Chumbo/química , Sensibilidade e Especificidade , Titânio/química , Transdutores , Zircônio/química
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