A new liquid sensor based on a piezoelectric resonator with a radial electric field.

The possibility of development a liquid sensor based on a piezoelectric resonator with radial concentric electrodes is shown. The specified resonator has a large number of resonance peaks corresponding to different vibrational modes. The influence of two types of liquid container with distilled water on the resonance characteristics of these vibrational modes is experimentally investigated. As a result, the optimal type of container and two vibrational modes with frequencies of 0.128 and 0.317 MHz were selected, which retain acceptable Q-factors in the presence of distilled water. The dependences of the resonance frequency and the maximum value of the real part of the electrical impedance of these resonance peaks on the conductivity of the liquid were measured. It has been found that with an increase in the conductivity of the liquid, the resonance frequency of the parallel resonance initially remains practically unchanged, but after reaching a certain value of the conductivity of water, it decreases for both resonances. In this case, the maximum value of the real part of the electrical impedance first decreases, reaches a minimum, and then increases in all cases. It is shown that using these dependences as calibration curves, one can unambiguously determine the conductivity of a liquid in the range of 45-5000 µS/cm.

Evaluation of Elastic Properties and Conductivity of Chitosan Acetate Films in Ammonia and Water Vapors Using Acoustic Resonators.

Novel bio-materials, like chitosan and its derivatives, appeal to finding a new niche in room temperature gas sensors, demonstrating not only a chemoresistive response, but also changes in mechanical impedance due to vapor adsorption. We determined the coefficients of elasticity and viscosity of chitosan acetate films in air, ammonia, and water vapors by acoustic spectroscopy. The measurements were carried out while using a resonator with a longitudinal electric field at the different concentrations of ammonia (100-1600 ppm) and air humidity (20-60%). It was established that, in the presence of ammonia, the longitudinal and shear elastic modules significantly decreased, whereas, in water vapor, they changed slightly. At that, the viscosity of the films increased greatly upon exposure to both vapors. We found that the film's conductivity increased by two and one orders of magnitude, respectively, in ammonia and water vapors. The effect of analyzed vapors on the resonance properties of a piezoelectric resonator with a lateral electric field that was loaded by a chitosan film on its free side was also experimentally studied. In these vapors, the parallel resonance frequency and maximum value of the real part of the electrical impedance decreased, especially in ammonia. The results of a theoretical analysis of the resonance properties of such a sensor in the presence of vapors turned out to be in a good agreement with the experimental data. It has been also found that with a growth in the concentration of the studied vapors, a decrease in the elastic constants, and an increase in the viscosity factor and conductivity lead to reducing the parallel resonance frequency and the maximum value of the real part of the electric impedance of the piezoelectric resonator with a lateral electric field that was loaded with a chitosan film. This leads to an increase in the sensitivity of such a sensor during exposure to these gas vapors.

Liquid sensor based on a piezoelectric lateral electric field-excited resonator.

The influence of viscous and conducting liquid on the characteristics of a piezoelectric lateral electric field-excited resonator based on the X-cut lithium niobate plate has been investigated. It has been found that the contact of a free surface of such resonator with conducting or viscous liquid leads to the substantial variation of its electrical impedance/admittance. The analysis has shown the modulus of electrical impedance or admittance at any frequency near the parallel or series resonance to be a parameter unambiguously associated with the conductivity or the viscosity. This parameter is more sensitive to the variation of the liquid conductivity or viscosity as compared to the widely used for this purpose resonant frequency whose variation area is essentially smaller. By this means the liquid conductivity and viscosity affects unambiguously on the change of electrical impedance and admittance modulus whose measurement at a fixed frequency should present no problem in practice. Consequently, the lateral field excited resonator we have described may be employed as a liquid conductivity and viscosity meter with an appropriate graduation.

Acoustic waves in a structure containing two piezoelectric plates separated by an air (vacuum) gap.

This paper presents experimental results for the characteristics of acoustic waves propagating in a structure containing two parallel piezoelectric plates (I and II) separated by an air gap. Plate I, made of Y-X lithium niobate, contained two interdigital transducers that excited and received an acoustic wave with shear-horizontal polarization. Piezoelectric plate II, made of lithium niobate, was placed above and between the transducers, separated by a fixed gap. For its certain orientation, the amplitude-frequency characteristic showed sharply defined resonant attenuation peaks, which were situated at an equidistant separation from each other. The depth of the peaks was observed to decrease with a wider gap between the plates. It has been stated that these peaks are associated with the resonant reflections of a slot acoustic wave across the width of plate II. Experimentally determined phase velocities and electromechanical coupling coefficient for the slot wave in the structure under study are in a good agreement with theoretical values for various crystallographic orientations of plate II. A comparison between the experimental and theoretical results has allowed us to state two conditions for the slot wave to exist. The structures described may be employed for noncontact excitation of acoustic waves in the plates and for the development of various liquid, gas, and temperature sensors.