Hydrogeochemical characteristics, driving factors, and health risk assessment of karst groundwater in Southwest Hubei Province, China.

In South China, karst groundwater is an important water resource for industrial, agricultural, and drinking purposes. However, karst aquifers are highly vulnerable to pollution, leading to deteriorating karst groundwater quality and posing potential health risks to local residents. In this study, 22 groundwater samples were collected from a karst aquifer in the southwestern part of Hubei Province. The hydrogeochemical characteristics and their controlling factors were examined, and the potential health risks associated with groundwater pollutant concentrations in karst groundwater were assessed. The results showed that the groundwater is slightly alkaline with low chemical oxygen demand values, indicating good water quality. The groundwater facies type was identified as HCO3-Ca at most sample spots, showing low total dissolved solids concentrations. Substantial spatial variations in Na+, CO3 2-, and NO2 - concentrations were found, whereas spatial variations in the K+, Ca2+, Cl-, HCO3 -, and F- concentrations were small. In addition, the dissolution of gypsum deposits and magnesium carbonate sedimentary rocks at sampling sites resulted in groundwater facies types of HCO3•SO4-Ca and HCO3-Ca•Mg, with low total dissolved solids concentrations. The karst groundwater chemistry in the study area was mainly controlled by water-rock interactions, as well as by the dissolution of gypsum deposits and magnesium carbonate sedimentary rocks at specific groundwater sampling sites. The groundwater Cl- concentrations were mainly affected by atmospheric precipitation. NO3 - was mainly derived from atmospheric precipitation, domestic sewage, septic tanks, and industrial activities, whereas SO4 2- was derived from atmospheric precipitation, sulfate rock dissolution, and sulfide mineral oxidation. These results highlight the absence of potential human health risks of NO3 - and F- to infants, children, and adults, as their concentrations are below the corresponding regional background values. In contrast, the potential health risks of Cl- cannot be ignored, particularly for infants. This study offers scientific guidelines for protecting and allocating local groundwater resources.

Comprehensive model development based on Dempster-Shafer evidence theory for pollution source analysis in chemical parks.

Pollution source analysis is an effective method that can help chemical park managers accurately understand the characteristics and contributions of pollution sources in the park. However, as more receptor models are being used in this field, it has become difficult for managers to find the best interpretable and reasonable model among many source analysis models. Here, we present a case study of pollution source analysis in a southern chemical park using the D-S evidence theory approach to combine the source analysis results of different receptor models for comprehensive consideration. Receptor models were used to analyse the pollution sources via positive definite matrix decomposition, principal component analysis-multiple linear regression, and Unmix models. The results demonstrated that source analysis was greatly influenced by the uniqueness of pollutant characteristics and model receptor differences. Furthermore, incomparable analysis results and low fineness were observed. The D-S evidence theory model proposed in this study solved the above-mentioned problem to some extent and successfully extracted the four primary pollution sources in the study area, of which 45.73 % came from the metal processing industry (F1), whose primary pollutants were Cr, Ni, Zn, Cr(VI), and Cu, and 25.12 % came from the electronics manufacturing industry (F2), whose primary pollutants were Pb, Cr(VI), Cu, and Zn. 15.62 % of the contamination came from the production of chemical agents (F3), whose primary pollutant was TEHP, and 13.53 % came from the use of oil-containing auxiliary materials (F4), whose primary pollutant was TPH. The D-S evidence theory model used in this study provides a reference for the management of chemical parks.

Effect of temperature on PTEs deportment and ecological risks of the biochars obtained from sewage sludge.

Sewage sludge-derived biochars (SSBCs) were obtained at temperatures of 300, 500, and 700 °C to investigate the potentially toxic elements (PTEs) behaviors and assess the environmental acceptability for the possible application in the environment. Results indicated that PTEs exhibited diversely in the distribution of chemical speciation, while all elements tended to be immobilized in biochar matrix and the total amount elevated during the pyrolysis. The risk assessment of biochars implied a low degree of environmental risk for the utilization of SSBCs prepared at high temperatures. In addition, higher pyrolysis temperature alleviated the inhibition on the early seedling growth of Triticum aestivum L., with root elongation more sensitive to the biochar addition. PTEs, especially Cr, contributed much to the phytotoxicity of biochars as revealed by the principle component analysis (PCA) and leaner correlation analysis. Findings from this work illustrated that SSBCs prepared at higher temperatures might be more conductive to a wide range of applications with acceptable environmental risk.