Microstructure-Based Modeling of Deformation and Damage Behavior of Extruded and Additively Manufactured 316L Stainless Steels.

In this study, we investigated the micromechanical deformation and damage behavior of commercially extruded and additively manufactured 316L stainless steels (AMed SS316L) by combining experimental examinations and crystal plasticity modeling. The AMed alloy was fabricated using the laser powder bed fusion (LPBF) technique with an orthogonal scanning strategy to control the directionality of the as-fabricated material. Optical microscopy and electron backscatter diffraction measurements revealed distinct grain morphologies and crystallographic textures in the two alloys. Uniaxial tensile test results suggested that the LPBFed alloy exhibited an increased yield strength, reduced elongation, and comparable ultimate tensile strength in comparison to those of the extruded alloy. A microstructure-based crystal plasticity model was developed to simulate the micromechanical deformation behavior of the alloys using representative volume elements based on realistic microstructures. A ductile fracture criterion based on the microscopically dissipated plastic energy on a slip system was adopted to predict the microscopic damage accumulation of the alloys during plastic deformation. The developed model could accurately predict the stress-strain behavior and evolution of the crystallographic textures in both the alloys. We reveal that the increased yield strength in the LPBFed alloy, compared to that in the extruded alloy, is attributed to the higher as-manufactured dislocation density and the cellular subgrain structure, resulting in a reduced elongation. The presence of annealing twins and favorable texture in the extruded alloy contributed to its excellent elongation, along with a higher hardening rate owing to twin-dislocation interactions during plastic deformation. Moreover, the grain morphology and defect state (e.g., dislocations and twins) in the initial state can significantly affect strain localization and damage accumulation in alloys.

Half-topological state in magnetic topological insulators.

We predict a novel topological state,half-topological state, in magnetic topological insulators. The topological state is characterized by different topologies of electrons with different spin orientations, i.e., electrons with one spin orientation occupy a nontrivial topological insulating state, while electrons with opposite orientation occupy another insulating state with trivial topology. We demonstrate the occurrence of the half-topological state in magnetic topological insulators by employing a minimal model. The minimal model is a combination of the spinful Haldane and the double-exchange models. The double-exchange processes maintain a spontaneous magnetic ordering, while the next-nearest-neighbor hopping in the Haldane model gives rise to a nontrivial topological insulator. The minimal model is studied by applying the dynamical mean field theory. It is found that the long-range antiferromagnetic ordering drives the system from either topological or topologically trivial antiferromagnetic insulator to the half-topological state, and finally to topologically trivial antiferromagnetic insulator. The equations for the topological phase transitions are also explicitly derived.

Biogeochemical Fe(II) generators as a new strategy for limiting Cd uptake by rice and its implication for agricultural sustainability.

This work has developed a new strategy of biogeochemical Fe(II) generators for activating microbial Fe(II) generation to immobilize Cd in soils through protons scavenging and coprecipitation. A new biochar modified magnetite (FeBC15) has been fabricated through a top-down method, with which microbial respiration can be stimulated in paddy soil. The FeBC15 exhibits a higher adsorption capacity for Cd than pristine magnetite (1.7 times). The results show that the available Cd can be reduced by 14.4% after adding FeBC15 compared to the control. More importantly, FeBC15 particles promote the conversion of MgCl2 - Cd to stable crystalline Fe/Al bound Cd under the incubation period. The enhanced pH and Fe(II) leads to a comparably lower Cd availability in soils than in pristine soils, which are supported by the enhanced relative abundance of Geobacter and Clostridium with the FeBC15 treatment (i.e. up to 7.44-7.68 × 109 copies/g soil). The Diffusive Gradients in Thin-films (DGT) study indicates that FeBC15 can lower the replenish capacity of soils (i.e. KdL values of 0.2-3.6 mL/g) to soil pore waters and limit root absorption. Pot experiments demonstrate that this strategy can alleviate the rice Cd content by 38.4% (< 0.2 mg/kg). This work paves a new pathway for reducing Cd uptake in rice, enabling sustainable remediation of paddy soil.

Effect of Quenching Tempering-Post Weld Heat Treatment on the Microstructure and Mechanical Properties of Laser-Arc Hybrid-Welded Boron Steel.

In the present study, we have investigated the effect of post-welding heat treatment (PWHT) of quenching and tempering (QT) on the microstructure and mechanical properties of welded boron steel joints processed using laser-arc hybrid welding on two commercial filler materials, SM80 (Type-I) and ZH120 (Type-II). The microstructure and mechanical properties of the weld joints were characterized via optical microscopy, Vickers microhardness, and the uniaxial tensile test. The macrostructure of the weld joint was composed of a fusion zone (FZ), heat-affected zone (HAZ), and base metal zone (BMZ). After the QT-PWHT, the QT specimens revealed the V-shape hardness distribution across the weld joint, while the as-welded specimen exhibited the M-shape hardness distribution. As a result, the QT specimens revealed the premature fracture with little reduction in the area at the interface between the HAZ and FZ, while the as-welded specimen exhibited the local necking and rupture in the BMZ. In addition, the Type-II filler material with a greater value of equivalent carbon content was rarely influenced by the tempering, maintaining its hardness in the as-quenched status, while the Type-I filler material showed a gradual decrease in hardness with the tempering time. The results demonstrate that the Type-II weld joint outperformed the Type-I weld joint in terms of the structural integrity of welded parts.

Competition between Kondo and RKKY correlations in the presence of strong randomness.

We propose that competition between Kondo and magnetic correlations results in a novel universality class for heavy fermion quantum criticality in the presence of strong randomness. Starting from an Anderson lattice model with disorder, we derive an effective local field theory in the dynamical mean-field theory approximation, where randomness is introduced into both hybridization and Ruderman-Kittel-Kasuya-Yosida (RKKY) interactions. Performing the saddle-point analysis in the U(1) slave-boson representation, we reveal its phase diagram which shows a quantum phase transition from a spin liquid state to a local Fermi liquid phase. In contrast with the clean limit case of the Anderson lattice model, the effective hybridization given by holon condensation turns out to vanish, resulting from the zero mean value of the hybridization coupling constant. However, we show that the holon density becomes finite when the variance of the hybridization is sufficiently larger than that of the RKKY coupling, giving rise to the Kondo effect. On the other hand, when the variance of the hybridization becomes smaller than that of the RKKY coupling, the Kondo effect disappears, resulting in a fully symmetric paramagnetic state, adiabatically connected to the spin liquid state of the disordered Heisenberg model. We investigate the quantum critical point beyond the mean-field approximation. Introducing quantum corrections fully self-consistently in the non-crossing approximation, we prove that the local charge susceptibility has exactly the same critical exponent as the local spin susceptibility, suggesting an enhanced symmetry at the local quantum critical point. This leads us to propose novel duality between the Kondo singlet phase and the critical local moment state beyond the Landau-Ginzburg-Wilson paradigm. The Landau-Ginzburg-Wilson forbidden duality serves the mechanism of electron fractionalization in critical impurity dynamics, where such fractionalized excitations are identified with topological excitations.

Novel duality in disorder driven local quantum criticality.

We find that competition between random Kondo and random magnetic correlations results in a quantum phase transition from a local Fermi liquid to a spin liquid. The local charge susceptibility turns out to have exactly the same critical exponent as the local spin susceptibility, suggesting a novel duality between the Kondo singlet phase and the critical local moment state beyond the Landau-Ginzburg-Wilson symmetry breaking framework. This leads us to propose an enhanced symmetry at the local quantum critical point, described by an O(4) vector for spin and charge. The symmetry enhancement serves as a mechanism of electron fractionalization in critical impurity dynamics, where such fractionalized excitations are identified with topological excitations.